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This is the POC checklist for Pokémon Orange Islands version 5.6
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Pre Badge-1(40 Pokemon)
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PokemonHow/Where to obtain
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PikachuOaks lab
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CharizardOaks lab
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TaurosOaks lab
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SquirtleOaks lab
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WartotleEvolve at lvl 16
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BlastoiseEvolve at lvl 36
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MukOaks lab
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KinglerOaks lab
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Bulbasaur Oaks lab
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IvysaurEvolve at lvl 16
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VenasaurEvolve at lvl 32
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MankeyRoute 1
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PrimeapeEvolve at lvl 28
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CaterpieValencia Park
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MetapodEvolve at lvl 7
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ButterfreeEvolve at lvl 10
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WeedleValencia Park
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KakunaEvolve at lvl 7
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BeedrillEvolve at lvl 10
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RattataValencia Park
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ParasValencia Park
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BellsproutValencia Park
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OddishValencia Park
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ParasectValencia Park
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RaticateValencia Park
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GloomValencia Park
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WeepinbellValencia Park
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VictrebellEvolve with leaf stone
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Don't catch metapod and kakuna since they are much easier to evolve
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You get a leaf stone here which can be used to evolve gloom into vileplume or weepinbell to into victreebell
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After defeating those three trainers you will probably have enough money to buy pokeballs and get
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VenonatPokemon Park
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VenomothEvolve at lvl 31
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PidgeyPokemon Park
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PidgeottoEvolve at lvl 18
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PidgeotEvolve at lvl 36
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SpearowPokemon Park
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FearowEvolves at lvl 20
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LaprasTangelo Island
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MagikarpOld rod
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GyradosEvolve magikarp at lvl 20
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TentacoolRoute E(Try to catch at lvl 22)
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TentacruelEvolve at lvl 30
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Don't take a lot of effort to catch every pokémon in a single ball you can return back to Valencia island again in this section
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Pre-Badge 2(89 Pokémon)
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DrowzeeMandarin North
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HypnoEvolve at lvl 26
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MachopSunburst Island
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MachokeEvolve at lvl 28
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MachampEvolve at lvl 40
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MeowthSunburst Island
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PersianEvolve at lvl 28
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TangelaSunburst Island
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ExeggcuteSunburst Island
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GeodudeCrystal cave
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GravellerEvolve at lvl 25
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GolemEvolve at lvl 40
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OnixCrystal cave
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Zubat Crystal cave
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GolbatEvolve at lvl 22
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SlowpokeCrystal cave(Surf)
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SlowbroCrystal cave(Surf)
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Nidoran MalePinkan Island
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Nidoran FemalePinkan Island
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NidroinoPinkan Island
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NidorinaPinkan Island
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NidoqueenEvolve with moon stone(from clefairy)
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ElectrabuzzPinkan Island
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DiglettPinkan Island
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DugtrioEvolve at lvl 26
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RyhornPinkan Island
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RhydonEvolve at lvl 42
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NidokingPinkan Island
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JigglypuffFukuharu Island
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WigglytufgEvolve with moon stone(from clefairy)
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ClefairyBay cave
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ClefableEvolve with moon stone(from clefairy)
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Be sure to get both helix and dome fossil from the island
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VulpixRoute G
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EkansRoute G
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ArbokEvolve at lvl 22
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PsyduckRoute G(surf)
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GolduckRoute G(surf)
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SeelRoute H(surf)
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DewgongRoute H(surf)
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HorseaRoute H(dive)
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SeadraEvolve at lvl 32