Ibarra et al., 2022 supplemental materials.xlsx

	A	B	C	D	E	F	G	H	I	J	K	L	M	N	O	P	Q	R	S
1	Electronic Annex for Ibarra et al. "Triple oxygen isotope systematics of diagenetic recrystallization of diatom opal-A to opal-CT to microquartz in deep sea sediments"
2
3	Table S1. Data from all replicates of standards and samples analyzed over the course of the analyses
4	Laboratory Analysis Number	Method	Session	Date Analyzed	Lab Short ID	δ'18O (VSMOW-SLAP)	δ'17O (VSMOW-SLAP)	δ18O (VSMOW-SLAP)	Δ'17O (λ = 0.528)	Δ'17O Measurement SE		Yanchinila et al. (2020) δ18O (VSMOW)	δ18O Difference	Mean δ18O (VSMOW-SLAP)	δ18O Replicate 1SE	Mean Δ'17O (λ = 0.528)	Δ'17O Replicate 1SE	Depth (m)	Age (Ma)
5	432	bomb	501	7/7/2020	15d	32.084	16.803	32.604	-0.137	0.009		34.15	2.07	32.249	0.847	-0.147	0.012	324.55	5.26
6	488	bomb	502	7/21/2020	15d	32.957	17.269	33.506	-0.132	0.010		34.15	1.19
7	742	bomb	510	11/17/2020	15d	30.176	15.762	30.636	-0.170	0.007		34.15	3.97
8	433	bomb	501	7/7/2020	16d	31.626	16.533	32.131	-0.166	0.008		34.6	2.97	32.520	0.216	-0.150	0.008	325.91	5.28
9	492	bomb	502	7/21/2020	16d	32.034	16.772	32.553	-0.142	0.009		34.6	2.57
10	741	bomb	510	11/17/2020	16d	32.349	16.938	32.878	-0.142	0.009		34.6	2.25
11	431	bomb	501	7/7/2020	9973-1	36.103	18.873	36.763	-0.190	0.008		37.17	1.07	36.771	0.297	-0.179	0.008	185.14	3.18
12	493	bomb	502	7/21/2020	9973-1	36.611	19.166	37.289	-0.164	0.009		37.17	0.56
13	726	bomb	510	11/13/2020	9973-1	35.618	18.624	36.260	-0.182	0.006		37.17	1.55
14
15	360	laser	203	2/10/2020	9948-1	23.280	12.203	23.553	-0.089	0.008		25.02	1.74	24.006	0.453	-0.090	0.001	442.91	7.86
16	393	bomb	501	6/26/2020	9948-1	24.165	12.668	24.459	-0.091	0.008		25.02	0.86
17	364	laser	203	2/10/2020	9994 DL20	21.123	11.068	21.347	-0.084	0.008		24.77	3.65	21.694	0.454	-0.065	0.010	466.36	8.56
18	391	bomb	501	6/26/2020	9994 DL20	22.343	11.738	22.594	-0.059	0.008		24.77	2.43
19	820	laser	510	12/4/2020	9994 DL20	20.920	10.993	21.140	-0.052	0.009		24.77	3.85
20	396	bomb	501	2/8/2020	9995 CL20	23.584	12.339	23.864	-0.113	0.009		26.51	2.93	25.315	1.451	-0.109	0.005	471.21	8.72
21	489	bomb	502	6/26/2020	9995 CL20	26.413	13.842	26.765	-0.104	0.008		26.51	0.10
22
23	351	laser	203	2/7/2020	9900 AL20	17.890	9.365	18.051	-0.081	0.011		19.82	1.93	18.014	0.177	-0.067	0.003	475.14	8.72
24	406	laser	501	7/1/2020	9900 AL20	17.536	9.202	17.690	-0.056	0.009		19.82	2.28
25	821	laser	510	12/4/2020	9900 AL20	18.135	9.512	18.300	-0.063	0.004		19.82	1.69
26	352	laser	203	2/7/2020	9902 AL20	18.044	9.448	18.207	-0.079	0.010		19.64	1.60	17.588	0.619	-0.079	0.000	491.39	9.22
27	438	laser	501	7/8/2020	9902 AL20	16.827	8.805	16.969	-0.079	0.008		19.64	2.81
28	347	laser	203	2/7/2020	9994 AL20	18.044	9.465	18.208	-0.062	0.010		21.93	3.89	18.771	0.563	-0.065	0.003	466.36	8.56
29	405	laser	501	7/1/2020	9994 AL20	19.150	10.042	19.334	-0.069	0.008		21.93	2.78
30
31	464	bomb	502	7/15/2020	9960-2	19.260	10.072	19.446	-0.097	0.007		21.72	2.46	20.087	0.641	-0.101	0.004	10.95	0.23
32	490	bomb	502	7/21/2020	9960-2	20.516	10.728	20.728	-0.104	0.007		21.72	1.20
33	480	bomb	502	7/17/2020	9974-1	28.588	14.977	29.000	-0.117	0.009		30.8	2.21	28.431	0.569	-0.122	0.005	240.31	4.06
34	510	bomb	502	7/24/2020	9974-1	27.482	14.383	27.863	-0.127	0.010		30.8	3.32
35	478	bomb	502	7/17/2020	9975-1	28.076	14.701	28.473	-0.123	0.007		28.97	0.89	27.412	1.062	-0.122	0.001	308.95	5.04
36	511	bomb	502	7/24/2020	9975-1	26.009	13.612	26.350	-0.121	0.009		28.97	2.96
37
38
39
40	Laboratory Analysis Number	Method	Session	Date Analyzed	Sample Short ID	δ'18O (VSMOW-SLAP)	δ'17O (VSMOW-SLAP)	δ18O (VSMOW-SLAP)	Δ'17O (λ = 0.528)	Δ'17O Measurement SE	Mean δ18O (VSMOW-SLAP)	δ18O Replicate 1σ	δ17O Replicate 1σ	Mean Δ'17O (λ = 0.528)	Δ'17O Replicate 1σ	δ18O Known (VSMOW-SLAP)	Δ'17O Known (λ = 0.528)	Reference
41	344	laser	203	2/5/2020	L1	17.637	9.211	17.794	-0.101	0.010	18.143	0.514	0.269	-0.089	0.012	18.070	-0.075	Adjusted from Wostbrock et al. (2020) via standards in Sharp and Wostbrock (2021)
42	345	laser	203	2/5/2020	L1	17.917	9.374	18.079	-0.087	0.010						18.070	-0.075
43	348	laser	203	2/7/2020	L1	17.820	9.323	17.980	-0.086	0.010						18.070	-0.075
44	354	laser	203	2/7/2020	L1	17.691	9.244	17.848	-0.097	0.009						18.070	-0.075
45	361	laser	203	2/10/2020	L1	17.774	9.298	17.933	-0.087	0.011						18.070	-0.075
46	378	laser	501	6/23/2020	L1	17.856	9.343	18.016	-0.085	0.008						18.070	-0.075
47	379	laser	501	6/23/2020	L1	17.685	9.253	17.842	-0.085	0.007						18.070	-0.075
48	387	laser	501	6/25/2020	L1	18.013	9.430	18.177	-0.081	0.008						18.070	-0.075
49	407	laser	501	7/1/2020	L1	17.753	9.274	17.912	-0.100	0.009						18.070	-0.075
50	419	laser	501	7/3/2020	L1	17.708	9.261	17.866	-0.089	0.008						18.070	-0.075
51	446	laser	502	7/10/2020	L1	17.818	9.318	17.978	-0.090	0.008						18.070	-0.075
52	451	laser	502	7/13/2020	L1	17.759	9.318	17.918	-0.059	0.009						18.070	-0.075
53	459	laser	502	7/14/2020	L1	17.488	9.138	17.642	-0.096	0.006						18.070	-0.075
54	481	bomb	502	7/17/2020	L1	18.886	9.903	19.065	-0.069	0.009						18.070	-0.075
55	515	bomb	502	7/24/2020	L1	18.919	9.899	19.100	-0.091	0.008						18.070	-0.075
56	532	laser	502	7/29/2020	L1	17.756	9.283	17.915	-0.093	0.008						18.070	-0.075
57	539	laser	503	7/31/2020	L1	18.119	9.471	18.285	-0.096	0.008						18.070	-0.075
58	554	laser	503	8/4/2020	L1	17.761	9.285	17.920	-0.092	0.008						18.070	-0.075
59	568	bomb	503	8/5/2020	L1	18.717	9.802	18.893	-0.081	0.007						18.070	-0.075
60	589	laser	503	8/10/2020	L1	18.251	9.518	18.419	-0.119	0.005						18.070	-0.075
61	622	bomb	507	9/28/2020	L1	18.136	9.499	18.301	-0.076	0.008						18.070	-0.075
62	640	laser	507	10/1/2020	L1	17.776	9.291	17.935	-0.095	0.011						18.070	-0.075
63	652	bomb	507	10/2/2020	L1	19.382	10.146	19.572	-0.088	0.009						18.070	-0.075
64	665	laser	507	10/6/2020	L1	17.775	9.278	17.934	-0.107	0.005						18.070	-0.075
65	674	bomb	507	10/7/2020	L1	19.576	10.262	19.769	-0.074	0.007						18.070	-0.075
66	705	laser	510	11/10/2020	L1	17.356	9.095	17.507	-0.069	0.007						18.070	-0.075
67	711	laser	510	11/11/2020	L1	17.757	9.285	17.915	-0.091	0.008						18.070	-0.075
68	734	laser	510	11/16/2020	L1	17.710	9.272	17.868	-0.080	0.007						18.070	-0.075
69	747	laser	510	11/17/2020	L1	17.759	9.294	17.918	-0.083	0.009						18.070	-0.075
70	758	laser	510	11/19/2020	L1	17.883	9.343	18.044	-0.099	0.007						18.070	-0.075
71	779	laser	510	11/23/2020	L1	17.755	9.272	17.914	-0.102	0.007						18.070	-0.075
72	792	laser	510	11/24/2020	L1	17.796	9.317	17.955	-0.079	0.008						18.070	-0.075
73	812	laser	510	12/3/2020	L1	17.776	9.294	17.935	-0.091	0.008						18.070	-0.075
74	829	laser	510	12/7/2020	L1	17.768	9.296	17.926	-0.086	0.008						18.070	-0.075
75	845	laser	510	12/10/2020	L1	17.772	9.285	17.930	-0.098	0.008						18.070	-0.075
76
77	358	laser	203	2/8/2020	NBS-28	9.493	4.958	9.538	-0.054	0.009	9.701	0.338	0.179	-0.042	0.012	9.577	-0.050	Sharp and Wostbrock (2021)
78	421	laser	501	7/3/2020	NBS-28	9.768	5.109	9.816	-0.048	0.007						9.577	-0.050
79	441	laser	501	7/8/2020	NBS-28	9.726	5.094	9.773	-0.041	0.008						9.577	-0.050
80	450	laser	502	7/10/2020	NBS-28	10.105	5.296	10.156	-0.039	0.006						9.577	-0.050
81	462	laser	502	7/14/2020	NBS-28	10.258	5.371	10.311	-0.046	0.004						9.577	-0.050
82	501	laser	502	7/23/2020	NBS-28	9.724	5.071	9.771	-0.063	0.008						9.577	-0.050
83	537	laser	503	7/31/2020	NBS-28	9.693	5.080	9.740	-0.038	0.008						9.577	-0.050
84	586	laser	503	8/10/2020	NBS-28	8.997	4.705	9.038	-0.045	0.009						9.577	-0.050
85	610	laser	507	9/25/2020	NBS-28	9.417	4.916	9.462	-0.056	0.008						9.577	-0.050
86	613	laser	507	9/25/2020	NBS-28	9.305	4.854	9.349	-0.059	0.008						9.577	-0.050
87	620	bomb	507	9/28/2020	NBS-28	10.293	5.398	10.346	-0.036	0.008						9.577	-0.050
88	624	bomb	507	9/28/2020	NBS-28	10.092	5.292	10.143	-0.037	0.003						9.577	-0.050
89	637	laser	507	9/30/2020	NBS-28	9.497	4.974	9.542	-0.040	0.003						9.577	-0.050
90	695	laser	510	11/9/2020	NBS-28	9.493	4.970	9.539	-0.042	0.008						9.577	-0.050
91	699	laser	510	11/10/2020	NBS-28	9.881	5.173	9.930	-0.044	0.009						9.577	-0.050
92	737	laser	510	11/16/2020	NBS-28	9.541	5.010	9.587	-0.028	0.008						9.577	-0.050
93	765	laser	510	11/19/2020	NBS-28	9.353	4.881	9.397	-0.058	0.010						9.577	-0.050
94	769	laser	510	11/20/2020	NBS-28	9.495	4.989	9.541	-0.025	0.007						9.577	-0.050
95	791	laser	510	11/24/2020	NBS-28	9.451	4.956	9.496	-0.034	0.010						9.577	-0.050
96	808	laser	510	12/1/2020	NBS-28	9.500	5.002	9.545	-0.014	0.003						9.577	-0.050
97
98	772	bomb	510	11/20/2020	PS Diatom	39.415	20.598	40.202	-0.213	0.003	41.540	1.630	0.830	-0.179	0.020	42.800		Chapligin et al. (2011)
99	649	bomb	507	10/2/2020	PS Diatom	38.902	20.391	39.669	-0.149	0.009		0.576	0.294		0.007	42.800
100	672	bomb	507	10/7/2020	PS Diatom	40.869	21.395	41.716	-0.184	0.009						42.800