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QuerypriorityNameSearch NotesJCBnotesASIDLnoteslink
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How many solubility measurements have been done for nitromethane as solvent?doneJCB/StephCsearched for all organics on Reaxydid not complete - too many hitsthis solvent noted as having suspect AD values - Andy thanks for the suggestion but I think there is something wrong with Reaxys so I'm waiting to hear back from the librarian firstCould limit to those compounds with known Abraham descriptors: http://lxsrv7.oru.edu/~alang/abrahamdescriptors/http://onschallenge.wikispaces.com/AbrahamSolventsModel001c
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How many solubility measurements have been done for nitromethane as solvent?done - add to solsumJCB/StephCsearched for all carboxylic acids on Reaxys7 hits, mostly fatty acids - addition of values to solsum pendingthis solvent noted as having suspect AD valuesCould limit to those compounds with known Abraham descriptors: http://lxsrv7.oru.edu/~alang/abrahamdescriptors/http://onschallenge.wikispaces.com/AbrahamSolventsModel001c
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How many solubility measurements have been done for carbon disulfide as solvent?1this solvent noted as having suspect AD valuesCould limit to those compounds with known Abraham descriptors: http://lxsrv7.oru.edu/~alang/abrahamdescriptors/http://onschallenge.wikispaces.com/AbrahamSolventsModel001c
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How many solubility measurements have been done for N-formylmorpholine as solvent?1this solvent noted as having suspect AD valuesCould limit to those compounds with known Abraham descriptors: http://lxsrv7.oru.edu/~alang/abrahamdescriptors/http://onschallenge.wikispaces.com/AbrahamSolventsModel001c
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Has anyone reported the oxidation of 4-chlorobenzaldehyde while trying to make an imine with aniline or another aromatic amine?doneJCBsearched Reaxys for the target imine as a product got 13 results, with several in ethanol - the main difference with Evan's reaction seems to be they used lower concentration in ethanol and equimolar (Evan had a large excess of the amine)trying to discover mechanism for Evan's finding of oxidation instead of imine formationhttp://showme.physics.drexel.edu/onsc/reactionattempts/advancedsearch.php?compound=&solvent=&reactiontype=oxidation&researcher=Evan+Curtin
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Has anyone reported the oxidation of 4-chlorobenzaldehyde while trying to make an imine with aniline or another aromatic amine?doneMarkSearched Reaxys for reactions with 4-chloro-benzaldehyde with an aniline starting material substructure search337 reaction, three types of reactions only contained these two reactants and nothing else, these were reductive aminations, amides synthysis by oxidative amidation, and. catalytic preparations of amides.trying to discover mechanism for Evan's finding of oxidation instead of imine formationhttp://showme.physics.drexel.edu/onsc/reactionattempts/advancedsearch.php?compound=&solvent=&reactiontype=oxidation&researcher=Evan+Curtin
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Has anyone reported the oxidation of 4-chlorobenzaldehyde while using ethanol as a reactant?doneMarkSearched Reaxys for reactions with 4-chloro-benzaldehyde with an ethanol starting material substructure search50 sources, none had 4-chlorobenzoic acid as a product, in almost every single case the ethanol reacted with the aldehyde to an acetal. In none did it oxidize into an acid.trying to discover mechanism for Evan's finding of oxidation instead of imine formationhttp://showme.physics.drexel.edu/onsc/reactionattempts/advancedsearch.php?compound=&solvent=&reactiontype=oxidation&researcher=Evan+Curtin
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How many solubility reports for any organic compound in ethylene glycol?doneValentinesearched for acetic acid substructureone hit - a methoxyimino acid - temperature study
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How many solubility reports for any organic compound in diethylene glycol?doneValentinesearched for acetic acid substructureno hits
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How many solubility reports for any organic compound in glyme?
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How many solubility reports for any organic compound in ethylene glycol?doneValentinesearched for benzene substructure3 compounds
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