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DateName of PresenterMechanism ProblemPlease present all experiments performed since your last presentationNote, the first person listed is responsible for the mechanism. The second person is in charge of compiling the lit slides (P)
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Package Pickup
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11/10/2025
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11/5/2025Max Practice (Wed)Sumanth
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11/3/2025Sumanth practiceMax
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10/29/2025Tan Practice (Wed)Yuhang
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10/20/2025Zhencheng PracticeEdwin
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10/14/2025EdwinTanZD
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YuhangTN
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EA
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YZSynthesis, Structures, and Properties of Polybenzo[n]spirenes with Carbon-Based Polyspiroconjugation
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MMCopper-Catalyzed Asymmetric C−H Sulfilimination of Arenes via HAT-Primed C−S Radical−Radical Coupling https://doi.org/10.1021/jacs.5c15479
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SGSynthesis of Bicyclo[2.2.1]Heptanes via Pyridine-Boronyl Radical-
Catalyzed [2π + 2σ] Cycloaddition. https://doi.org/10.1021/acs.joc.5c01474
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10/6/2025SumanthZhenchengZD
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MaxTN
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EAhttps://pubs.acs.org/doi/pdf/10.1021/jacs.5c13001?ref=article_openPDF. Overriding Norrish Type II to Access Cyclopropanols
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YZAsymmetric Hydrogenation of Triazolo[1,5‑a]‑, Imidazo[1,2‑a]‑, and Pyrazolo[1,5‑a]pyridines
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MMLigand-Controlled Alkylation–Heck–C(sp3)–H Annulation Cascade for a Divergent Synthesis of Cyclobutane- and Cyclopropane-Containing Heterocycles https://pubs.acs.org/doi/10.1021/jacs.5c11047
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SG
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9/29/2025YuhangSumanthZD
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TanTNB(C6F5)3-Catalyzed Coupling of N-Alkyl Arylamines and Alkenes for the Synthesis of Tetrahydroquinolines
https://pubs.acs.org/doi/10.1021/acs.orglett.5c03023
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EADivergent Transformations of Cobaltacyclobutenes Generated from [2 + 2]-Cycloadditions of Vinylidenes and Alkynes. https://pubs.acs.org/doi/10.1021/acscatal.5c04303
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YZ
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MMSynthesis of Fused Polycyclic 1,4-Benzodiazepines via a Metal-Free Cascade Cyclization of 2-Acylbenzoic Acids with N-(o-Aminobenzyl)-indoles. https://doi.org/10.1021/acs.joc.5c01615
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SG
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9/22/2025EdwinMaxZD
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ZhenchengTN
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EA
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YZCatalyst-Controlled Switchable Mono-/Di-C−H Arylation of Aromatic Amides with Arylsilanes
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MMRegio- and Chemoselective Synthesis of Spiro Cyclobutane-Isobenzofuranimines via Cascade Oxycyclization and [2 + 2] Cycloaddition of o-Alkynolbenzamides. https://doi.org/10.1021/acs.joc.4c03092
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9/15/2025MaxYuhangZDConstruction of Complex Bisether-Bridged Medium-Sized Cyclic Compounds from o-(1-(Acyloxy)propargyl)benzaldehydes under Base and Acid Catalysis https://pubs.acs.org/doi/10.1021/acs.joc.9b01677
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SumanthTNA C-to-B Atom Swap on Coumarins and Dibenzolactones
https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202509674
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EAhttps://pubs.acs.org/doi/10.1021/acscatal.5c04509. Systematic Synthesis of Chiral CAACs with Three Independent Stereogenic Centers for Enantioselective Copper-Catalyzed Conjugate Borylation of Michael Acceptors
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YZPhotocatalytic Arene C−H Amination with Aromatic N‑Heterocyclic Radicals
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MM
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SGCobalt(0)-Catalyzed Isomerization of Allylamines Promoted by
Monodentate Benzofuran Phosphines. https://doi.org/10.1021/jacs.5c09017
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9/8/2025TanEdwinZD
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YuhangTNDevelopment of a Vinylated Cyclic Allene: A Fleeting Strained Diene for the Diels–Alder Reaction
https://onlinelibrary.wiley.com/doi/10.1002/ange.202510319
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EASynthesis of Highly Substituted Alkenes from Terminal Alkynes. https://pubs.acs.org/doi/10.1021/jacs.5c11173
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YZEnantioselective Rhodium-Catalyzed Cycloisomerization of 1,5-Bis(allenes) to Access 1,2-cis-Ethynyl- and Vinyl-Substituted Five-Membered (Hetero)Cycles
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MMEnantio- and Diastereoselective Synthesis of Tricyclic Lactones Bearing Three Quaternary Stereocenters https://doi.org/10.1021/acs.joc.5c01607
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SGSynthesis of CF3‑Substituted N‑Heterocyclic Compounds Based on
C−H Activation-Initiated Formal [2 + 3] Annulation Featuring with a
Latent Nucleophilic Site. https://doi.org/10.1021/acs.joc.4c00508
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9/1ZhenchengTanZD
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EdwinTN
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EAC(sp3)H/N(sp2) Cross-Coupling Reaction for the Synthesis of Tertiary Arylamines via Fluxional SOX·Pd(II) Catalysis. https://pubs.acs.org/doi/10.1021/jacs.5c08883
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MMRh(III)-Catalyzed Mild Synthesis of Isoquinoline Derivatives from N-Chloroimines and Alkenes https://doi.org/10.1021/acs.joc.5c01362
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SGPalladium-Catalyzed Decarboxylative Cross-Coupling of 2,4-Dienoic
Acids and Aryl Halides: Access to Fluorescence Active (E,E)‑1,4-
Diarylbutadienes. https://pubs.acs.org/action/showCitFormats?doi=10.1021/acs.joc.5c00782&ref=pdf
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6/2/2025Summer School Planning and Prep
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5/26/20251-on-1 meetingsYuhang
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5/19/2025MaxEdwinZD
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YuhangTNRadical Arylboration of Unactivated Alkenes via Visible-LightCatalysis
https://pubs.acs.org/doi/epdf/10.1021/acs.orglett.5c01297?ref=article_openPDF
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YZModular Synthesis of 2,3,4,6-Tetrasubstituted Thieno[2,3-c]furans Based on Formal [3+2] Cycloaddition Utilizing [1,2]-Phospha Brook Rearrangement / Brønsted Base-Mediated Cyclization Strategy
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MM
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5/12/2025EdwinTanZD
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ZhenchengTNZr-Catalyzed Assembly of 1,1,1-Triborylalkanes from Alkenes and HBpin
https://pubs.acs.org/doi/10.1021/jacs.5c05144
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MM