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Chemistry�(HOLT Chapter 4)

Atoms and the Periodic Table

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Day One Notes

Atoms

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Chemistry:

  • The study of composition, structure and properties of matter and changes that happen to matter

Matter:

  • Anything that has mass and occupies space
  • Solid, Liquid, Gas, or plasma

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Elements Contain a Single Kind of Atom

Atom:

  • Atoms make up the matter around you
  • Substances are created as a result of the combination of many atoms
  • Atoms are very small

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Subatomic particles � (parts of the atom):

1. Proton = (+) Charge

2. Electron = (-) Charge

    • Neutron = neutral (no) charge

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Atomic Nucleus

Nucleus:

  • The center of the atom
  • Contains the protons and the neutrons
  • Contains most of the atom’s mass

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Atomic Nucleus

Proton

  • Positive charge (+)
  • Protons are nearly 2000 times more massive as the electron
  • Found in nucleus

Neutron:

  • Found in the nucleus
  • No charge
  • Approximately same mass as proton

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Outside the Atomic Nucleus

Electrons

  • Surround the nucleus
  • Move around the nucleus
  • Are very small
  • Negative charge
  • Outside the nucleus of an atom is mostly empty space

Valence Electrons

  • The electrons in the outermost energy level (shell)
  • Most shells full at 8 electrons

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Elements

  • Any material that is made up of only one type of atom is classified as an element.

Ex. Pure gold (Au) contains only gold atoms

Ex. Nitrogen (N) gas = only nitrogen atoms

  • All of the elements are listed in a chart called the Periodic Table of Elements
  • Approx 100 elements
  • 90 found in nature
  • The rest have been created in a laboratory

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Atomic Symbol

  • Each element is designated by its atomic symbol
  • Name comes from the letters of the element’s name.
  • 1st letter of the element is always CAPITALIZED
  • 2nd letter (if there is one) always lower case
    • Ex: C = Carbon,

Cl = Chlorine

    • Ex: Co = Cobalt…

…Different from CO = Carbon + Oxygen

Sometimes the name originates from the Latin name

  • Ex: Gold = Au for the Latin name aurum

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Atomic Number

Atomic number: number of protons in the nucleus

    • This DEFINES the element
    • If an atom is neutral, the number of protons is equal to the number of electrons
    • Q: If an oxygen atom has 8 electrons it will also have ____ Protons.

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Mass Number

Mass Number:

  • Is the total number of protons and neutrons in the nucleus
  • Found by rounding off the atomic mass
  • This is how isotopes are identified

Helium:

Mass number 4

Atomic number -2

number of neutrons 2

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Isotopes: atoms of the same element, with the same number of protons but different number of neutrons

    • They have different mass numbers

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Practice

If the atomic number is 9,

  • What is the element name?
  • How many protons does it have?
  • How many electrons does it have?

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  • How many protons does platinum have?
  • How many electrons does lead have?
  • How many neutrons does mercury have?
  • What similarities do these three elements have?�

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End Day 1

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Day 2 notes

Types of Elements

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Early Versions of the Periodic Table

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Early Versions of the Periodic Table

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Dmitri Mendeleev

  • Dmitri Mendeleev developed the periodic table in 1869

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1. He grouped elements with similar chemical and physical properties together

2. He arranged the elements in increasing atomic mass.

3. He predicted the properties of elements not yet discovered.

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Mendeleev’s Periodic Table

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Periodic Table

  • Today’s periodic table, the elements are arranged in increasing atomic number so elements with similar properties fall in the same group.

Note: Ar and K are ordered according to atomic number, not atomic mass

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Periodic Law

  • Periodic Law: When elements are arranged in increasing atomic numbers, there is a repeating (periodic) pattern to the properties.

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Metals

  • Elements that are shiny, opaque
  • Good conductors of electricity and heat
  • malleable = can be bent without breaking
  • Ductile = can be drawn into wires
  • Most are solid at room temperature

*Mercury (Hg) is liquid at room temperature

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Nonmetals

  • On the right side of the periodic table
  • Very poor conductors of electricity and heat
  • Transparent
  • Not malleable nor ductile
  • Are brittle and shatter
  • Some are solid, liquid and gas

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Metalloids (Semiconductors)

  • Six elements only
  • Found between metals and nonmetals in the periodic table
  • Have both metal and nonmetal characteristics
  • B; Si; Ge; As; Sb;Te

(Important for electronics/microchips)

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Group (Family)

  • Vertical column
  • 18 groups total
  • Describes properties of their elements

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Period

  • A Period is a horizontal row
  • 7 periods on the table.
  • A Periodic trend of atom size.
  • Atoms get smaller from left to right on the periodic table.
  • Atoms get larger as you go down a group/family.

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End Day 2 notes

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Day 3 notes

Period Table Groups

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Alkali Metals

  • Group 1 (except Hydrogen)
  • Have one valence electron
  • Tend to lose one electron in reactions
  • React violently
  • Soft & shiny
  • Ex: Sodium (Na)

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Alkaline-Earth Metals

  • Group Two
  • Have two valence electrons
  • Tend to lose two electrons in reactions
    • Ex: Calcium (Ca) in bones.

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Transition Metals

  • Groups 3-12
  • Less reactive
  • Ex: Gold (Au)

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Inner-Transition Metals

The two rows at the bottom of the table.

-Lanthanides (top row)

-Actinides (bottom row)

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Inner Transition Metal

  • The inner transition metals are placed at the bottom only to save space.

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Halogens

  • Group 17.
  • Have 7 valence electrons
  • Tend to gain one electron in reactions
    • Ex: Chlorine

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Noble Gases

  • Group 18
  • Have a full valence shell with 8 electrons
  • Un-reactive/stable

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End Day 3 Notes

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Day 4 Notes

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Chemical and Physical Properties

Substance – matter that has uniform and unchanging composition

      • Ex. Pure water has the same lack of taste, color, boiling point, density, etc. It is always made up of hydrogen and oxygen
      • Ex. Sodium Chloride (Table Salt) is the same throughout made up of Sodium Chlorine (NaCl)

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Physical Property

  • Physical Property - can be observed or measured without changing the identity of the substance.
    • Ex. Observing and measuring the boiling point, density, color

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Physical States of Matter

  • Solid- definite shape and volume, particles tightly packed in fixed positions and can only vibrate.
  • Liquid- definite volume, indefinite shape, particles can flow past each other-fluid.
  • Gas- indefinite shape and volume. Particles move more rapidly with lots of space between them. Particles take up the volume and shape of the container.
  • Plasma – indefinite shape and volume; consists of positive and negatively charged particles at extremely high temperatures

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Illustration of 3 states of matter

Difference between gas and vapor

    • vapor is a gaseous state of a substance that is a solid or liquid at room temperature
      • Ex. Steam

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Chemical Properties

  • Chemical Properties- a substance’s ability to change to form new substances or ability not to.
    • Ex. Iron
      • Iron rusts when it reacts with oxygen in the air
      • Iron does not react with nitrogen gas in the air

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Physical Change

  • Physical Change – a type of change that alters the physical properties of a substance but does not change its composition.
    • Examples
      • Crumpled Aluminum Foil
      • Cutting Paper
      • Breaking a crystal
      • Boiling Water

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Chemical Change

Chemical Change – a process involving one or more substances changing into new substances (aka: a chemical reaction)

  • Some indicators of a chemical change:
    • Changing color (such as metal rusting)
    • Releasing/Absorbing heat (such as burning wood)
    • Producing light (fireflies)
    • Rotting
      • Note: energy is always involved in physical and chemical changes

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Chemical Change

Chemical Reaction - the process in which atoms of one or more substances are rearranged to form a new substance.

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End Day 4 Notes

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Day 5 Notes

  • Periodic Trends

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Atomic Radii

  • Atomic Radii – ½ the distance between the nuclei of 2 of the same atoms bonded together.

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Atomic Radii

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Atomic Radius Trend

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Electronegativity

  • Electronegativity is a measure of the attraction of an atom for the electrons in a chemical bond.

  • The higher the electronegativity of an atom, the greater its attraction for bonding electrons.

  • Example: Chlorine has higher electronegativity than sodium and will take an electron from sodium.

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Elctronegativity Trend

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Ionization Energy

ionization energy is the energy required to completely remove an electron from an atom or ion.

  • The closer and more tightly bound an electron is to the nucleus, the more difficult it will be to remove, and the higher its ionization energy will be.

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Ionization energy Trend

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