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The Arizona STEM Acceleration Project

GROWING CRYSTALS PART 1:

Actualizing the Formation of Crystalline Solid

Sugar Crystal Growing

Sodium tetraborate Crystal Growing

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Growing Crystals Part 1: Actualizing the Formation of Crystalline Solid

A 9th-12th grade STEM lesson

Maria Theresa A. Gonzaga

3/26/2023

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Notes for teachers

Context:

  • This lesson can be taught from 9th grade to 12th grade (depending on the depth of lesson)

  • This lesson takes place in a Laboratory Room for one or more hours.

  • Students may work in small groups of 3-4.

  • An emphasis on creating your desired crystals structure based on bonding and forces of attraction.

  • Modification for creative design and activities are welcome and encouraged.

  • Lesson 2

List of Materials

Sucrose (Table sugar) Sodium tetraborate (Borax)

Food dye

Apparatus or Equipment:

500 mL Beaker Hot Plate Digital Thermometer

Stirring Rod Gloves Heat-resistant gloves

Beaker Tongs Weighing scale

For Molding:

Pipe cleaners/chenille stems Skewer/Suspender String

Alternative Materials:

String/ molder cups small bowl Popsicle stirrer

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Arizona Science Standards

Arizona ELA Standards

Essential HS.P1U1.2

Develop and use models for the transfer or sharing of electrons to predict the formation of ions, molecules, and compounds in both natural and synthetic processes.

Plus HS+C.P1U1.4

Develop and use models to predict and explain forces within and between molecules.

Plus HS+C.P1U1.5

Plan and carry out investigations to test predictions of the outcomes of various reactions, based on patterns of physical and chemical properties.

Core Science Idea

P1: All matter in the Universe is made of very small particles.

9-10.W.7

Conduct short as well as more sustained research projects to answer a question (including a self‐generated question) or solve a problem; narrow or broaden the inquiry when appropriate; synthesize multiple sources on the subject, demonstrating understanding of the subject under investigation.

9-10.W.1

Write arguments to support claims in an analysis of substantive topics or texts, using valid reasoning and relevant and sufficient evidence.

a. Introduce precise claim(s), distinguish the claim(s) from alternate or

opposing claims, and create an organization that establishes clear

relationships among claim(s), counterclaims, reasons, and evidence.

b. Develop claim(s) and counterclaims fairly, supplying evidence for

each while pointing out the strengths and limitations of both in a

manner that anticipates the audience’s knowledge level and

concerns.

e. Provide a concluding statement or section that follows from and

supports the argument presented.

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Arizona Science Standards

Cross-Cutting Concepts

Systems and System Models:

● Let the students create a well-defined system to focus on.

● Allow the students to design models (e.g., physical, mathematical, computer models) that can be used to simulate systems and interactions—including energy, matter, and information flows—within and between systems at different scales.

  • Let the students develop plans for their actions or sets of instructions to help them develop the concept that exemplify understanding and usage.

Patterns:

● Let the student identify different patterns to be observed at each of the scales at which a system is studied and can provide evidence for causality in explanations of phenomena.

● Empirical evidence is needed to identify patterns.

Stability and Change:

● Much of science deals with constructing explanations of how things change and how they remain stable.

Arizona Science Standards

Science and Engineering Practices

Asking Questions and Defining Problems:

● Provide questions that arise from careful observation of phenomena, models, theory, or unexpected results.

● Provide questions that require relevant empirical evidence to answer.

● Provide questions that determine relationships, trends and factors affecting the change including quantitative and qualitative relationships.

Developing and Using Models:

● Let the students use diversified or explicit models that best represent and support an understanding of phenomena.

● Let the students develop, revise, and use models to predict and support explanations of relationships between systems or between components of a system.

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Objective(s):

At the end of the 70-minutes lesson the students are expected to:

  1. Describe the different types of crystals and their properties: ionic, metallic, covalent and molecular.
  2. Classify crystals according to the forces of attraction.
  3. Relate the properties of different types of solids to the bonding or interactions among particles in these solids.
  4. Design and create your desired crystalline formation using sugar and sodium tetraborate.

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Agenda (Day 1 and Day 2 Lesson)

Day 1 (50-60 minutes)

  • Engage: Investigate a phenomena, “Why do gems can be crystals yet crystals cannot be gems? What makes the two differ? What is a crystalline solid? (15-20 minutes)

  • Explore: Conduct investigation on the different types of crystals and their properties: ionic, covalent and molecular. (30-35 minutes)

  • Evaluate: Students will be assessed according to the following:

Experimental design: Students understanding how to design their own desired crystals and distinguish factors that influence the formation of crystalline solids

Day 2 (50-60 minutes)

  • Explain: Present and Discuss how forces of attraction between the component atoms, molecules, or ions affects the formation of crystals (15 minutes)

  • Elaborate: Extend to the students' conceptual understanding of the types of crystals formation through application or practice in new settings. Elaborate the characteristics or traits of crystals

  • Evaluate: Students will be assessed according to the following:

Poster Presentations: Students will demonstrate their understanding of how forces of attraction and measuring the amount of impurities of the substance influence the formation of crystals .

Peer Evaluations: Incorporates student-centered instruction encouraging peer teaching through Open House - Display, Present and React.

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Vocabulary:

Crystalline solids: a solid containing an internal pattern of molecules that is regular, repeated, and geometrically arranged.

Molecule: the smallest physical unit of a substance that can exist independently. A molecule is made up one or more atoms held together by chemical forces.

Supersaturated solution: a solution that has been heated in order to dissolve more material than would be possible at room temperature.

Forces of Attraction: refers any particular force that draws two objects or particles towards each other.

Chemical Bonding: the attraction between two or more atoms that allows them to be able to form a stable chemical compound.

Crystallization: the process by which solid forms, where the atoms or molecules are highly organized into a structure known as a crystal

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Driving Question:

“Why can gems be crystals yet crystals cannot be gems? What makes the two differ?

Gems

Crystals

Using sample gemstones and crystals, sort and identify which is a crystal and a gemstone. Observe and compare the properties of the gems and crystals. Write your answers to the table provided.

DAY 1 (70 MINUTES)

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What is a Crystalline Solid?

  • Crystalline substances are described through the types of particles in them and the types of chemical bonding that take place between the particles.

  • There are four types of crystals:

(a) ionic

(b) molecular

(c) metallic

(d) covalent network

(c ) metallic crystal: metal ions and delocalised electrons (d) covalent networks: network held together

11.7: Structures of Crystalline Solids - Chemistry LibreTexts

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Your type of Crystal Structure!

Ionic crystals

  • a crystal structure consists of alternating positively-charged cations and negatively-charged anions.
  • Ions may either be monatomic or polyatomic.
  • Form from a combination of Group 1 or 2 metals and Group 16 or 17 nonmetals or nonmetallic polyatomic ions.

Metallic crystal

  • Consist of metal cations surrounded by a "sea" of mobile valence electrons.
  • These electrons, also referred to as delocalized electrons, do not belong to any one atom, but are capable of moving through the entire crystal.

Covalent network crystals

  • A crystal consists of atoms at the lattice points of the crystal, with each atom being covalently bonded to its nearest neighbor atoms.
  • A three-dimensional and contains a very large number of atoms.
  • Network solids include diamond, quartz, many metalloids, and oxides of transition metals and metalloids.

Molecular crystals

  • Consist of molecules at the lattice points of the crystal, held together by relatively weak intermolecular forces.
  • The intermolecular forces may be:

Dispersion forces - nonpolar crystals

Dipole-dipole forces- polar crystals

Hydrogen bonds - molecules held together

  • When one of the noble gases is cooled and solidified, the lattice points are individual atoms rather than molecules.
  • In all cases, the intermolecular forces holding the particles together are far weaker than either ionic or covalent bonds.

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Let’s investigate!

In the conduct of the experiment, be guided with the following:

  • What type of crystal is formed from a sugar solution?

  • What type of crystal is formed from a disodium tetraborate solution?

  • Which crystals grow faster? Why?

  • How are the two crystals similar and if not, how it differ with the other?

  • Are properties observed the same? Why and why not?

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Hands-on Activity: Let’s grow crystals!

Materials for the Activity:

  • Group students into 5 with 2-4 members, according to their strength. They will perform the activity for 25-30 minutes.

  • Students will work in small groups to design and create desired crystalline formation using sugar and sodium tetraborate. Demonstrate how things will be done.

  • Students will do the OPEN HOUSE. Give every student 3 post-it cards with emoticons that will be used to express their opinion regarding each group exhibit. The group will DISPLAY, PRESENT in 2 minutes the results and let everyone REACT through the post-it cards.

  • Students are encourage for a debate understanding properties of a crystals solution based on research, data collection and communication of results through presentation.

List of Materials

Sucrose (Table sugar) Disodium tetraborate (Borax)

Food dye

Apparatus or Equipment:

500 mL Beaker Hot Plate Digital Thermometer

Stirring Rod Gloves Heat-resistant gloves

Beaker Tongs Weighing scale

For Molding:

Pipe cleaners/chenille stems Skewer/Suspender String

Alternative Materials:

String/ molder cups small bowl Popsicle stirrer

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Hands- on Instructions

Let’s Grow Crystals!

Step 1. Make a saturated solution

Make a saturated sugar solution. Put 200 mL water EXACTLY to heat for 5-7 minutes but not in a boiling point.

Step 2. Heating the solution

In the beaker, ADD 2 cups or 400 mL of sugar to the heated and stir for at least 3-5 minutes or until sugar dissolves.

Step 3. Cooling the solution

TAKE IT OUT from the hot plate and let it cool for 2-3 minutes. This creates a saturated solution, meaning no more solute can dissolve in the water.

Step 4.

Place the cooled beaker back again in a pot to heat or until boil for 3 minutes. Add and stir 1 and half cups or 260 mL of sugar GRADUALLY to the solution.

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Activity Instructions:

Step 5.

Put to boil for 5 more minutes and continue stirring until you see THAT ALL OF IT dissolve in the solution.

LET IT COOL AND TRANSFER TO THE CUP.

Step 6. Grow a Crystal

Tie the string or molder to the suspender or holder and leave it inside the solution. Pour a little of the saturated solution into a cup or dish. Allow it to sit in an undisturbed location for several hours or overnight.

Place the jar in a location where it won't be disturbed. You can set a coffee filter or paper towel over the top of the container, but allow air circulation so that the liquid can evaporate.

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Assessment Day 1:

Experimental design: Students understanding how to design their own desired crystals and distinguish factors that influence the formation of crystalline solids

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Laboratory Worksheet:

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Intro: What are the attractive forces that influence the bonding?

Watch the video about intermolecular forces and intramolecular forces to fully understand how crystalline solids are affected by bonding or particle interactions.

Relate the properties of different types of solids to the bonding or interactions among particles in these solids.

https://www.youtube.com/watch?v=XbDeEdr7OQI

DAY 2 (60-70 minutes)

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Poster Presentation:

From your the role assigned for each member of the group, Presenter will discuss and explain your understanding of how forces of attraction and measuring the amount of impurities of the substance influence the formation of crystals .

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Assessment

Peer Evaluations: Incorporates student-centered instruction encouraging peer teaching through Open House - Display, Present and React.

OPEN HOUSE:

Display their work, present the process and outcome and reacts through post-it cards.

Liked emoji means they understand the process.

Heart emoji means they understand and explain the process on their own language.

Question mark means they need more help and have to write specific questions

towards their concern to help them more understand it.

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Differentiation

Students will be in regular groupings but they will have a peer teaching and will have a modified rubric for assessment.

Remediation

Extension/Enrichment

  • Allow the students to redo or do more trials with different measurement of solution to get several results and desired crystals.

  • Do a separate experiment or activity on recognizing and categorizing crystal properties like melting point, electrical conductivity and hardness

ELL students may use internet and be in group that composed of bilingual members.

Labeled activity is used for them to understand terms.

Write arguments based on the emoji attached to the displays to support claims in an analysis of substantive topic using valid reasoning and relevant and sufficient evidence.

a. Introduce precise claim(s), distinguish the claim(s) from alternate or opposing claims, and create an organization that establishes clear relationships among claim(s), counterclaims, reasons, and evidence (CER)