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Sustainable Science:

Bioplastics from Food Waste

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Traditional plastics

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  • Synthetic: They are made from nonrenewable resources like fossil fuels
  • Ubiquitous: They are everywhere in our daily lives, from product packaging to construction materials.
  • Low Production Cost: They are cost-effective to produce, which has led to their widespread use.
  • Versatile: Traditional plastics can be molded into a wide variety of shapes, making them suitable for countless uses.
  • Durable: They are known for their long-lasting properties, which is both a benefit and a challenge from an environmental standpoint.
  • Global consumption: They are among the most commonly used materials globally.

Traditional plastics

What are they?

Traditional Plastics: What are they?

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  • All plastics are polymers. Monomers + monomers polymers with heat & catalysts.
  • Common monomers:
    • Small alkenes C=H (ethylene, propylene) & methanol from natural gas
    • Benzene and related chemicals from oil.

Traditional plastics

How are they made?

Traditional Plastics: What are they?

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  • Example 1: PE. Commonly used in bottles, bags, pipes, etc.
  • The degree of polymerization n is 700 - 1800.

  • Ethylene derives from natural gas products or the cracking process of oil.
  • PE is extremely chemically inert and takes centuries in nature to break down. Even then, decomposition products are either microplastics or dangerous species like formaldehyde, aerosol, radicals.

Traditional plastics

How are they made?

Traditional Plastics: What are they?

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  • Example 2: polyvinyl alcohol (PVA) - the thin film in Tide pods.
  • Precursors: vinyl acetate & methanol, which derives from ethylene and methanol, all petroleum-based chemicals. Contains 600 - 2400 monomers.
  • Dissolves quickly in water because of the -OH group.

Traditional plastics

How are they made?

Traditional Plastics: What are they?

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  • Example 2: polyvinyl alcohol (PVA) - the thin film in Tide pods.
  • Breakdown mechanism: enzymatic attack at random points along the polymer chain, breaking it into acetic acid. Then acetic acid is metabolized by microbes in the citric acid cycle.
  • It’s biodegradability is still questionable. The OECD label ‘readily biodegradable’ requires this test: a compound only needs to be 60% converted into CO2 in 28 days in laboratory conditions.
  • However, the test did not account for
    1. Remaining 40% material.
    2. Consuming speed of in the sewage vs lab conditions.
    3. Timeline: usually, wastewater remain in treatment plants for less than 28 days.

Traditional plastics

How do they decompose?

Traditional Plastics: What are they?

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Traditional plastics

Annual production of plastics worldwide from 1050 to 2021

(in million metric ton)

Traditional Plastics: What are they?

Source: Statista

Population growth trend

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Traditional plastics

Usage

Traditional Plastics: What are they?

Source: https://www.bakerinstitute.org/

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Traditional Plastics: What are they?

  • Waste Generation: The widespread use of traditional plastics results in significant waste generation, especially in single-use items like packaging and disposable utensils.
  • Non-Biodegradability: Most traditional plastics do not biodegrade naturally. They persist in the environment for hundreds of years, contributing to litter and pollution.
  • Microplastics: Over time, larger plastic items break down into tiny particles known as microplastics. These microplastics infiltrate our ecosystems, harming wildlife and potentially entering the human food chain.
  • Resource Depletion: The production of traditional plastics relies heavily on fossil fuels, contributing to the depletion of non-renewable resources.
  • Greenhouse Gas Emissions: The manufacturing and disposal of plastics generate greenhouse gas emissions, contributing to climate change.

Traditional plastics

& their environmental impact

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Traditional plastics

Traditional Plastics: What are they?

Source: Visual Capitalist

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Bioplastics & Biobased materials

Bioplastics: What are they?

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Biobased materials are

  • Renewable: They rely on materials that can be naturally replenished, reducing the strain on non-renewable resources.
  • Sustainable: Biobased materials are designed to be sustainable and environmentally friendly.

Bioplastics are:

  • Subgroup of biobased materials: They are a category of plastics made from organic, renewable materials, typically derived from plants like corn, potatoes, or sugarcane.
  • Biodegradable: Some bioplastics are biodegradable, meaning they can naturally break down into non-toxic substances at the end of their life cycle, reducing waste and pollution.

Bioplastics & Biobased materials

What are they?

Bio Plastics: What are they?

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Two types of bioplastics are now produced in large quantities.

  • PLA: Polylactide acid. Made from dextrose (sugar molecule) from corn starch, cassava or sugarcane.
  • PHA: polyhydroxyalkanoate. A wide variety of chemicals made from microorganisms.

Their physical properties are very similar to traditional plastics.

  • PLA ≈ polyethylene (films, packing and bottles), polystyrene (Styrofoam) or polypropylene (auto parts & textiles).
  • PHA ≈ polyethylene (bottles), and a lot of other plastics.

Bioplastics & Biobased materials

What are they?

Bio Plastics: What are they?

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  • Corn → dextrose → lactate through glycolysis
  • Lactate goes through dehydration, then polymerization to become polylactic acid.

Bioplastics & Biobased materials

How are they made?

Bio Plastics: What are they?

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  • PHA: made by microorganisms. The microorganisms, kept in carbon-rich but nutrient-deprived conditions, produce PHA as carbon reserves.
  • Structures similar to that of traditional plastics.

Bioplastics & Biobased materials

How are they made?

Bio Plastics: What are they?

General structure of PHAs.

Polycarbonate - traditional plastic

Polybutylene succinate - traditional plastic

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  • Reduced Waste: Bioplastics & biobased materials are designed to break down more easily, reducing the accumulation of plastic waste in landfills, oceans, and ecosystems.
  • Reduced Carbon Footprint: Their production generally emits fewer greenhouse gases compared to traditional plastics, contributing to a reduced carbon footprint.
  • Renewability: Unlike traditional plastics, which rely heavily on fossil fuels, biobased materials use renewable resources. This makes them more sustainable and reduces our dependence on finite resources.

  • Diverse Applications: Biobased materials are used in a wide range of applications, including packaging, textiles, construction, and even automotive components.

Bioplastics & Biobased materials

What are the benefits?

Bio Plastics: What are they?

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  • Diverse Applications:
    • PLA is FDA approved for food-contact material.
    • PHA and PLA are both biocompatible & biodegradable, so they are used in the medical fields for implants, wound covers, scar rejuvenation treatment, etc.
    • PLA has good tensile strength & impact characteristics; its applications in the automotive industry are car interior, safety helmets, front panels, ceiling.
    • PLA has low moisture absorption and high UV resistance, so it is also used in textile, eg., sportswear
    • PHA is also used in drug delivery

Bioplastics & Biobased materials

What are the benefits?

Bio Plastics: What are they?

Suntory Beverage & Food Limited will introduce the world’s first PET beverage bottle caps using 30% plant-based products in Japan. https://www.suntory.com/softdrink/news/pr/article/SBF0380.html

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Kenley McAdams, from bioMASON, applies a feeding to the bacteria Photo courtesy of James O’Rourke

BioMason - Biomanufactured Bricks

Biobased Materials Examples

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www.amino.bio

Prometheus Materials - Biocomposite Masonry Blocks

Biobased Materials Examples

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www.amino.bio

Ohmie - 3D-Printed Lamp

Bioplastic Examples

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Bioplastic Examples

Ohmie - 3D-Printed Orange Peel Lamp

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www.amino.bio

Agar Bottle Student Project

Bioplastic Examples

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Agar Bottle Project - Redefining Sustainable Packaging

Bioplastic Examples

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www.amino.bio

Agar Raincoat Project - Innovating Sustainable Fashion

Bioplastic Examples

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www.amino.bio

Electronic waste

Bioplastic Examples

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www.amino.bio

Bioplastic Examples

Biodesign Challenge - Sustainable Electronics Casings

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www.amino.bio

Biodesign Challenge - Sustainable Electronics Casings

Bioplastic Examples

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Chitosan - Harnessing Crustacean Shells for Sustainability

Bioplastic Examples

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www.amino.bio

Chitosan - Harnessing Crustacean Shells for Sustainability

Bioplastic Examples

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A Note on Food Waste

  • Minimizing Food Waste: Approximately one-third of the food produced globally goes to waste, contributing to food insecurity and environmental problems.
  • Resource Efficiency: When we reuse food waste, we reduce the strain on agricultural resources, energy, and water used to produce the food.
  • Reducing Landfills: Food waste in landfills generates methane, a potent greenhouse gas. Reusing food waste prevents its decomposition in landfills.

Food and Agricultural Waste

A Global Challenge

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Discussion

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Why do you think traditional plastics are a significant environmental concern, and how do they impact our daily lives?

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What are the key benefits of using bioplastics, and how can they help address the environmental issues caused by traditional plastics?

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Why is reusing food waste an essential practice, and how can it contribute to a more sustainable lifestyle?

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Glossary

Bioplastic

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  • Biodegradable: The property of a material to naturally break down into non-toxic substances when it reaches the end of its life cycle, reducing waste and pollution.
  • Biobased Materials: Materials derived from renewable and naturally occurring resources, such as plants and microorganisms. They are more environmentally friendly and sustainable compared to materials based on fossil fuels.
  • Greenhouse Gas Emissions: The release of gases like carbon dioxide into the atmosphere, contributing to the greenhouse effect and climate change.
  • Microplastics: Tiny plastic particles that result from the breakdown of larger plastic items and infiltrate ecosystems, potentially harming wildlife and entering the food chain.
  • Renewable Resources: Resources that can be naturally replenished, such as plant-based materials, as opposed to finite resources like fossil fuels.
  • Sustainability: The practice of using resources in a way that meets current needs without compromising the ability of future generations to meet their needs.
  • Traditional Plastics: Synthetic materials made from polymers that are derived from non-renewable resources, primarily fossil fuels, and have a range of environmental challenges.
  • Bioplastics: A subset of biobased materials that are derived from organic sources like corn, sugarcane, and potato starch. They are designed to be more environmentally friendly and sustainable, with applications in various industries.

Bioplastic Lesson Glossary

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Sustainable Science:

Making bioplastic

from food waste

Experiment

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SAFETY

  • Gloves and goggles can be worn
  • Acetic acid (vinegar) has a strong smell!
  • Microwaved liquids can be hot when taken out.

Safety

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Gather your supplies and prepare your space.

    • Clear your workspace
    • Read through the instructions
    • Gather all the ingredients listed in the instructions
    • Put on your gloves and googles if you have them/want

Bioplastic Lesson Experiment

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  1. Prepare your molds - Oil & identify them:
    • On the thinner mold write “Chitosan”
    • On the larger mold write the name of your food waste
    • Pour a small amount of oil inside each mold and use it to coat the entire inside of the mold. This will act as a mold release.

Bioplastic Lesson Experiment

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Chitosan Bioplastic

  1. Add 25 mL of water to your beaker
  2. Add the tube of glycerol (10 mL) , and one packet of gelatin (1 g) to your beaker
  3. Microwave until it boils
  4. Add the Chitosan powder (3 g).
  5. Mix and once the liquid is smooth, pour it into the “Chitosan” mold.

Bioplastic Lesson Experiment

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Own Food Waste Bioplastic

  • Add the all the acetic acid (50 mL) to your beaker
  • Add a packet of pectin (1.25 g), and a packet of gelatin (1 g) to your beaker
  • Microwave until it boils
  • Add 3 tablespoon of crushed food waste (if you are feeling experimental, add 2, 4 or 5!)
  • Mix and once the liquid is smooth, pour it into the other mold.

Leave the bioplastics to dry 24 - 72 hours.

Bioplastic Lesson Experiment

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Discussion & Reflection

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What environmental benefits can you identify in the process we just conducted?

How does the biodegradability of bioplastics differ from traditional plastics, and why is it important?

Discussion: Environmental Impact

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What challenges or difficulties did you encounter while making bioplastics from food waste?

How might these challenges be addressed in a real-world scenario?

Discussion: Challenges

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Now that we've created bioplastics, can you think of potential applications in everyday life and industries where bioplastics could be beneficial?

How might using bioplastics in these applications impact the environment?

Discussion: Potential Application

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What actions can you take to reduce your use of traditional plastics?

How can you implement the concept of reusing food waste at home or in your community?

Can you think of any products or materials in your daily life that could be replaced with bioplastics for a more sustainable option?

Reflection

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Conclusion

@aminobiolab