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CSIR- 800 Project

LEAKAGE REPAIR IN BUILDING WITH BIO-BASED SEALANT

Submitted to

on

by

Aakriti: 10CC22A01002

Nighot Nikhil Sanjay: 32EE22A01002

Avinash Kumar Yadav: 20EE22A01003

Jyoti Ahlawat: 10CC20A01002

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Problem

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Objective

  • To prevent leaks in houses/buildings that are 10 to 15 years old by applying soy-based sealants
  • Apply these sealants to various surfaces within older homes to seal gaps and cracks that may have developed over time.
  • Minimize reliance on petroleum-based products and chemicals by adopting renewable alternatives like soy-based sealants.
  • Encourage the use of materials derived from renewable resources, such as soybean oil, to reduce environmental impact and promote a circular economy.
  • Option for sealants with low or no volatile organic compounds (VOCs) to improve indoor air quality by reducing emissions of harmful chemicals.
  • Ensure that sealants used in residential or commercial spaces are non-toxic and safe for occupants, minimizing health risks associated with exposure to harmful substances.

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Commercially available sealants in the market

There are various commercially available sealants designed to address water leakage in concrete, wood, and masonry houses. Some common types include

Silicone Sealants

    • Effective for sealing gaps and cracks in various building materials.
    • Offers good adhesion and flexibility.

Polyurethane Sealants

    • Suitable for both interior and exterior use.
    • Provides a durable and flexible seal.

Acrylic Sealants

    • Versatile and easy to apply.
    • Ideal for sealing joints and gaps in wood and masonry

Butyl Rubber Sealants

    • Excellent for sealing joints that may experience movement.
    • Good adhesion to a variety of surfaces.

Elastomeric Sealants

    • Highly flexible and able to accommodate movement.
    • Effective for sealing gaps in concrete and masonry.

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Downsides of commercially available sealants from the market

  • Production and disposal contribute to pollution, harming soil and water sources.
  • Durability may be short-lived due to weather or UV exposure, requiring frequent reapplication.

  • Specialized sealants can be expensive, and regular maintenance adds to long-term expenses.
  • Handling toxic sealants requires precautions and proper ventilation.
  • Some sealants are flammable or react dangerously under specific conditions.
  • Chemical sealants contribute to pollution and resource depletion, lacking eco-friendly features

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Eco-friendly Solution

Homemade Soy-based Sealant

Ingredients and Materials Needed:

  • Refined soybean oil / Mustard oil (1 cup)
  • White vinegar (1 tablespoon)
  • Citrus essential oil (optional for fragrance)
  • Glass container for mixing
  • Stirring utensil
  • Storage container with an airtight lid

Reaction involved:

Vinegar, which contains acetic acid (CH3COOH), may facilitate emulsification of soybean oil with other ingredients.

CH3COOH + Soybean oil → Emulsification Reaction

Vinegar may help in mixing or blending soybean oil with other components, aiding in the formation of a homogeneous mixture for the sealant.

Steps:

Prepare the Ingredients

Mixing the ingredient

Stir and Blend

Storage

Application

Drying and Curing

Process:

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Mechanism of Soy-based Sealant

  1. Oxidation of Unsaturated Fatty Acids:
    • Soybean oil contains unsaturated fatty acids, such as linoleic acid or oleic acid, with double bonds.
    • CH2=CHCH2CH=CH−(Unsaturated fatty acid)+O2)→Oxidation Reaction
    • The double bonds undergo oxidation upon exposure to air (Oxygen), initiating a chain reaction.

  • Formation of Peroxides and Hydroperoxides:
    • Oxygen reacts with the double bonds, forming peroxides and hydroperoxides.
    • RCH=CHR′+O2RCH(OO)−CHR′(Peroxides/Hydroperoxides)
    • These intermediate products contribute to the curing process by initiating subsequent reactions.

  • Polymerization and Cross-Linking:
    • Peroxides and hydroperoxides promote polymerization and cross-linking reactions between molecules.
    • n×RCH(OO)−CHR′→Polymerization/Cross-Linking
    • Polymer chains form, linking molecules together and creating a three-dimensional network.

4. Curing and Solidification:

    • Polymerization and cross-linking continue, leading to the solidification or curing of the sealant.
    • Polymer chains→Cured Solid Film
    • The polymer chains intertwine and form a solid film, providing the desired properties of the cured soy-based sealant.

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Properties of Soy-based Sealant

Applications

  • Wood: Soy-based sealants can protect wooden surfaces, such as decks or fences, from water damage, rot, and decay.
  • Concrete and Masonry: Soy-based sealants are used to waterproof concrete surfaces, preventing water penetration and reinforcing durability.
  • Traditional Building Materials: These sealants can be applied to various traditional materials like adobe, thatch, or natural fibers, helping to protect them from moisture and weather-related deterioration.
  • Formation of Protective Barrier: The cured soy-based sealant forms a durable, flexible, and cohesive barrier on the treated surface.
  • Hydrophobic Barrier: The hydrophobic nature of the soy-based sealant's film prevents water from penetrating the surface. It causes water to bead up and roll off the treated area.
  • Water Repellency: Due to the hydrophobic properties of the sealant, water molecules are unable to permeate the sealed surface, thereby providing protection against water intrusion.
  • Resistance to Water Damage: The created barrier effectively shields the surface from moisture, preventing water-related damage such as swelling, rotting, or degradation.

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Merits of Soy-based Sealant

  • Derived from renewable soybean oil, reducing reliance on non-renewable resources.
  • Biodegrades naturally, minimizing environmental impact during disposal.

  • Contains fewer volatile organic compounds, improving indoor air quality.

  • Excellent at preventing water infiltration and protecting surfaces from moisture-related damage.

  • Suitable for various surfaces like wood, concrete, metals, and plastics.

  • Forms durable protective layers with strong adhesion, resisting degradation over time.

  • Can offer cost advantages in maintenance and lifecycle expenses.
  • Lower toxicity compared to conventional chemical sealants, posing fewer health risks.

  • Encourages the use of agricultural products like soybean oil, supporting renewable resource utilization.

  • Contributes to the development of eco-friendly technologies and sustainable construction practices.

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Impact on Society

Environmental impact:

    • Reduced environmental footprint compared to petroleum-based sealants.
    • Decreased reliance on fossil fuels.
    • Soy is a renewable resource, promoting sustainability.
    • Soy-based sealants are generally biodegradable, reducing long-term environmental impact.

Health Benefits:

    • Lower toxicity levels compared to some conventional sealants.
    • Improved indoor air quality for workers and occupants.

Economic Advantages:

    • Supports local economies through small-scale production.
    • Cost-effective, making it a competitive option.

Job Creation:

    • Expands employment opportunities in soybean cultivation, processing, and sealant manufacturing

Community Awareness and Education:

    • Promotes awareness among communities about the benefits of using soy-based sealants, fostering a culture of sustainability.

Local Production:

    • Provides opportunities for local businesses and entrepreneurs.
    • Reduces transportation-related environmental impacts.

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Thank you

Leakage repair in building with Bio-based sealant