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Rutherford's scattering experiment

A beam of alpha particles are directed at a very thin gold foil

Most of the alpha particles passed right through.

A few (+) alpha particles were deflected by the positive nucleus.

A tiny number of particles reflected back from the nucleus.

B01) Atomic Structure

Atoms, elements and compounds

Atom

The smallest part of an element that can exist

Have a radius of around 0.1 nanometres and have no charge (0).

Element

Contains only one type of atom

Around 100 different elements each one is represented by a symbol e.g. O, Na, Br.

Compound

Two or more elements chemically combined

Compounds can only be separated into elements by chemical reactions.

Method

Description

Example

Filtration

Separating an insoluble solid from a liquid

To get sand from a mixture of sand, salt and water.

Crystallisation

To separate a solid from a solution

To obtain pure crystals of sodium chloride from salt water.

Simple distillation

To separate a solvent from a solution

To get pure water from salt water.

Fractional distillation

Separating a mixture of liquids each with different boiling points

To separate the different compounds in crude oil.

Chromatography

Separating substances that move at different rates through a medium

To separate out the dyes in food colouring.

Mixtures

Two or more elements or compounds not chemically combined together

Can be separated by physical processes.

The development of the model of the atom

Pre 1900

Tiny solid spheres that could not be divided

Before the discovery of the electron, John Dalton said the solid sphere made up the different elements.

1897 ‘plum pudding’

A ball of positive charge with negative electrons embedded in it

JJ Thompson ‘s experiments showed that showed that an atom must contain small negative charges (discovery of electrons).

1909 nuclear model

Positively charge nucleus at the centre surrounded negative electrons

Ernest Rutherford's alpha particle scattering experiment showed that the mass was concentrated at the centre of the atom.

1913

Bohr model

Electrons

orbit the nucleus at specific distances

Niels Bohr proposed that electrons orbited in fixed shells; this was supported by experimental observations.

James Chadwick

Provided the evidence to

show the existence of neutrons within the nucleus

Chemical equations

Show chemical reactions - need reactant(s) and product(s) energy always involves and energy change

Law of conservation of mass states the total mass of products = the total mass of reactants.

Word equations

Uses words to show reaction

reactants 🡪 products

magnesium + oxygen 🡪 magnesium oxide

Does not show what is happening to the atoms or the number of atoms.

Symbol equations

Uses symbols to show reaction

reactants 🡪 products

2Mg + O2 🡪 2MgO

Shows the number of atoms and molecules in the reaction, these need to be balanced.

Relative electrical charges of subatomic particles

Name of Particle

Relative Charge

Relative Mass

Proton

+1

1

Neutron

0

1

Electron

-1

Very small

7

Li

3

Mass number

The sum of the protons and neutrons in the nucleus

Atomic number

The number of protons in the atom

Number of electrons = number of protons

Relative atomic mass

Isotopes

Atoms of the same element with the same number of protons and different numbers of neutrons

35Cl (75%) and 37Cl (25%)

Relative abundance =

(% isotope 1 x mass isotope 1) + (% isotope 2 x mass isotope 2) ÷ 100

e.g. (25 x 37) + (75x 35) ÷ 100 = 35.5

Central nucleus

Contains protons and neutrons

Electron shells

Contains electrons

Electronic structures

Electronic shell

Max number of electrons

1

2

2

8

3

8

4

2