1 of 49

Fire Inspection and�Code Enforcement

8th Edition�Inspector II

Chapter 10 — Hazardous Materials

2 of 49

�Learning Objective 1

Describe an inspector's role in process controls.

10–1

3 of 49

Know requirements for hazardous manufacturing processes.

10–2

Regularly use two or more hazardous materials

If materials are not used properly, they may rapidly decompose and result in a fire or explosion

Model fire codes require systems be properly designed by a competent design professional

(Cont.)

Courtesy of Scott Stookey, International Code Council, Washington D.C.

4 of 49

Know requirements for hazardous manufacturing processes.

10–3

IFC and NFPA® 400 require that hazardous materials follow a proper path during the manufacturing processes

Codes also require that the process must not exceed the temperature or pressure limits established by the designer

Inspectors may require a Technical Report and Opinion, prepared by an authorized person, to clarify the process or its potential hazards

5 of 49

REVIEW QUESTION

What can an inspector require to clarify processes?

10–4

6 of 49

�Learning Objective 2

Identify an inspector's responsibility after an unauthorized discharge.

10–5

7 of 49

Unauthorized discharge is a release of a hazardous material that does not conform to codes and regulations.

10–6

As defined by IFC and NFPA® 400

    • Work to prevent additional incidents
    • To this end, a stop-use order may be issued
    • In some cases, the hazardous material will need to be removed from the system

Inspector’s responsibility

    • Should consider the required steps so that repairs or improvements can be safely accomplished without creating another incident

Plan of action

8 of 49

REVIEW QUESTION

What can an inspector do in response to an unauthorized discharge?

10–7

9 of 49

�Learning Objective 3

Describe requirements for piping, valves, and fittings that convey hazardous materials.

10–8

10 of 49

IFC and NFPA® 400 have extensive requirements for piping systems design, erection, and testing.

10–9

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Components of piping systems that convey hazardous materials from cylinders and tanks to a point of use

Piping systems are required to be constructed of materials with adequate strength and durability and are chemically compatible with the material being conveyed

Model fire codes require hazardous materials piping systems be constructed to ASME B31.3

Verify that the installation matches the approved plans

11 of 49

Know when codes prescribe the installation of an excess flow control valve or other means of flow control.

10–10

Courtesy of Scott Stookey, International Code Council, Washington D.C.

In piping systems conveying flammable, pyrophoric, toxic, and corrosive liquids and gases

Excess flow control valves are designed to stop the flow at a predetermined setting or if the pipe is severed

Selected based on the pipe diameter and the material being conveyed

Key inspection issue for excess flow control valves is pipe diameter changes

12 of 49

REVIEW QUESTION

List some of the requirements for piping, valves, and fittings used to convey hazardous materials.

10–11

13 of 49

�Learning Objective 4

Recognize the classification system and requirements for hazardous and high-hazard occupancies.

10–12

14 of 49

Hazardous occupancies represent some of the most challenging building uses.

10–13

If the amount of hazardous materials in a building exceed the MAQ, IBC and NFPA® 400 require compliance with applicable Hazardous or High-Hazard occupancy classification

Design and construction are based on the classification of hazardous materials that are stored or used

Classifications change when materials change

Hazardous occupancies are assigned to one or more of four different categories, based on the physical or health hazards

Generally, the lower the occupancy number, the greater the hazard the building presents

15 of 49

Understand Group H-1/High Hazard Level 1 occupancy classifications.

10–14

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Assigned to occupancies that present a detonation hazard

Assigned to buildings that store explosives, blasting agents, or other hazardous materials

Represent the highest level hazard of all physical hazardous materials

16 of 49

Understand Group H-2/High Hazard Level 2 occupancy classifications.

10–15

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Store materials that present a deflagration hazard

Present a risk from accelerated burning of the material

Include storage of flammable gases, pressurized flammable or combustible liquids, pyrophorics, higher-reactivity oxidizers, organic peroxides

17 of 49

Understand Group H-3/High Hazard Level 3 occupancy classifications.

10–16

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Store or use hazardous materials that readily support combustion or present other physical hazards

Includes unpressurized flammable and combustible liquids, lower reactivity oxidizers and organic peroxides, flammable solids, oxidizing gases

18 of 49

Understand Group H-4/High Hazard Level 4 occupancy classifications.

10–17

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Designed for the storage of health hazard materials; for corrosives, and toxic and highly toxic materials exceeding the MAQ

19 of 49

NOTE

The IBC and NFPA® 400 require a dual hazardous occupancy classification in buildings where the MAQ for physical and health hazard materials are exceeded.

10–18

20 of 49

An explosion can result in either a detonation or deflagration.

10–19

    • Heat producing reaction characterized by a shock wave in the material
    • Reaction zone progresses through the material at a rate greater than the speed of sound
    • Principal heating mechanism is one of shock compression

Detonation

    • Heat-producing reaction occurs when a flammable gas, vapor or combustible dust is rapidly oxidized
    • Reaction zone progresses through the unburned material at a rate less than the speed of sound

Deflagration

21 of 49

Some industries designate explosive materials as either primary or secondary explosives.

10–20

Courtesy of Scott Stookey, International Code Council, Washington D.C.

    • Very sensitive materials that can be easily detonated and produce a fast pressure wave
    • Commonly used in detonators, which are devices used for initiating a detonation

Primary explosives

    • Will detonate when initiated by a shock wave created by a detonator
    • Normally will not detonate when heated or ignited

Secondary explosives

22 of 49

Some industries designate explosive materials as either primary or secondary explosives.

10–21

(Cont.)

23 of 49

Some industries designate explosive materials as either primary or secondary explosives.

10–22

24 of 49

Hazardous occupancies have requirements common to the four occupancy classes.

10–23

    • Not permitted in mixed occupancy buildings
    • Require a separate, stand-alone building without a basement

Group H-1/High Hazard Level 1 occupancies

    • Require an automatic sprinkler system complying with NFPA® 13
    • Must also comply with the sprinkler requirements in the particular NFPA® hazardous material standard

Sprinklers

    • Removes vapors or gases released

Continuous mechanical ventilation

    • When a Hazardous/High Hazard occupancy is located in a mixed occupancy building

Fire-resistive separation

(Cont.)

25 of 49

Hazardous occupancies have requirements common to the four occupancy classes.

10–24

    • Additional seismic safety features and special inspections are required for Group H occupancies based on the physical or health hazard classification of the stored materials

IBC

    • Group H/High-Hazard Level occupancies are more restrictive when compared to the other occupancies

Means of egress

    • Required in hazardous occupancies regardless of occupant load

Panic hardware

    • Reduced
    • Exit access travel distances cannot be increased by installing an automatic sprinkler system

Common path of egress travel distances

26 of 49

REVIEW QUESTION

Describe the classification categories for hazardous and high-hazard occupancies.

10–25

27 of 49

Codes prescribe specific administrative and engineering controls in Group H/High-Hazard occupancies.

10–26

Secondary containment

Mechanical ventilation systems

Automatic sprinkler protection

28 of 49

Hazardous occupancies storing liquid or solids require spill control or secondary containment.

10–27

Hazardous occupancies storing liquid or solids

Required to contain an accidental spill and keep it within the occupancy

Secondary containment is prescribed when the outdoor MAQ is exceeded and iin all cases of exterior flammable and combustible liquid storage

Not required for compressed or liquefied compressed gases

29 of 49

Using the floor surface of the hazardous occupancy will satisfy the requirements for spill control.

10–28

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Permissible if the container volume is less than 55 gallons (220 L) of liquids or 550 pounds (275 kg) of solids

IFC and NFPA® 400 require that the floor be liquid tight by using concrete or asphalt construction

Containment pallets can also satisfy the requirement for spill control

30 of 49

Model fire codes require secondary containment for liquids and solids.

10–29

Liquids

    • When the container volume is greater than 55 gallons (220 L) or the aggregate volume is greater than 1,000 gallons (4 000 L)

Solids

    • When the individual container weight is greater than 550 pounds (275 kg) or the aggregate weight of hazardous materials is more than 10,000 pounds (5 000 kg)

31 of 49

Model fire codes offer several compliance options for secondary containment.

10–30

In all cases the design must provide a liquid-tight method of containing the spill from the largest container

Portable tank or stationary AST

Designs may utilize raised curbs or foundations constructed with a depression with sufficient depth to contain the contents

(Cont.)

Courtesy of Scott Stookey, International Code Council, Washington D.C.

32 of 49

Model fire codes offer several compliance options for secondary containment.

10–31

Another compliance option is a drainage system that captures a spill and drains it to an outdoor containment basin or a storage tank

Key consideration in the design of a drainage system is it must not allow the mixing of incompatible hazardous materials

Courtesy of Scott Stookey, International Code Council, Washington D.C.

33 of 49

Model fire codes require monitoring of a secondary containment or drainage system.

10–32

Visual surveys

Electronic monitoring

34 of 49

Know collection requirements for indoor secondary drainage systems.

10–33

Designed to collect the volume of the largest container or tank plus the discharge from an operating automatic sprinkler system

Model fire codes require that the system be capable of containing a minimum of 20 minutes of sprinkler water flow over the design area of the automatic sprinkler system or the area of hazardous occupancy, whichever is smaller

35 of 49

Know collection requirements for outdoor secondary containment systems.

10–34

Courtesy of Scott Stookey, International Code Council, Washington D.C.

With the exception of flammable and combustible liquids, model fire codes require secondary containment of hazardous materials outdoor storage when the outdoor MAQ is exceeded

Design for hazardous materials must contain the volume of the largest container or storage tank and contain the volume of rainfall produced in a 24-hour/25 year storm

36 of 49

REVIEW QUESTION

What is the purpose of spill control and secondary containment?

10–35

37 of 49

Know why Group H/High Hazard occupancies must have mechanical ventilation systems.

10–36

    • Fumes
    • Vapors
    • Gases created by a container
    • Piping
    • Valve or component leak

Systems provide adequate air movement to exhaust

Mechanical ventilation is not required for flammable solids

38 of 49

Become familiar with the design requirements for mechanical exhaust systems.

10–37

Designed and constructed in accordance with the IMC or NFPA® 91

Must provide enough air at a sufficient velocity to capture gases or vapors

    • Materials with a vapor density greater than one require ventilation openings within 12 inches (300 mm) of the floor
    • Lighter-than-air vapors or gases require ventilation openings within 12 inches (300 mm) of the highest point of the room

Design issue is the vapor density of the stored materials

(Cont.)

39 of 49

Become familiar with the design requirements for mechanical exhaust systems.

10–38

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Mechanical ventilation systems in hazardous occupancies are designed to provide a minimum air flow rate of one cubic foot per minute per square foot (cubic meter per minute per square meter) over the area of occupancy or space

40 of 49

The selection of the duct and fan air foils (blades) is another consideration for inspectors.

10–39

Nonmetallic ducts may be required for corrosive materials

Materials like glass-fiber reinforced plastic or chlorinated PVC are acceptable but must be constructed of materials with limited flame spread and smoke production characteristics

Duct materials may be required to be listed for specific applications

In most cases the duct and air foils are of noncombustible construction

41 of 49

Know how to determine the adequacy of emergency vents in stationary tanks.

10–40

Courtesy of Scott Stookey, International Code Council, �Washington D.C.

    • Requires the nameplate on all shop-fabricated ASTs to indicate the required emergency vent flow

UL 142

    • Compare rate posted on the nameplate to the flow rate on the emergency vent

Verify size

    • Requires all emergency vents to be permanently marked with their design flow rate
    • When the flow rate on the vent equals or exceeds the rate on the nameplate, it complies
    • When the flow rate on the vent is less than the value on nameplate, it does not

NFPA® 30

42 of 49

REVIEW QUESTION

List some of the requirements for mechanical ventilation systems.

10–41

43 of 49

Group H/High-Hazard occupancies require automatic sprinkler protection.

10–42

May be required throughout the building or only within the hazardous occupancy

Model fire codes generally do not dictate the type of sprinkler system, only that it must comply with NFPA® 13 requirements

    • Flammable and combustible liquids
    • Compressed gases that are classified as pyrophoric, flammable or oxidizers
    • Solid and liquid oxidizers and organic peroxides

NFPA® 13 requires specialized automatic sprinkler designs be installed for certain classes of physical hazard materials

(Cont.)

44 of 49

Group H/High-Hazard occupancies require automatic sprinkler protection.

10–43

Courtesy of Scott Stookey, International Code Council, Washington D.C.

Of all the physical hazards, flammable and combustible liquids present the most variables in the design of an automatic sprinkler system

One method of satisfying the NFPA® 30 sprinkler design requirements is installing in-rack sprinklers with a horizontal barrier

45 of 49

REVIEW QUESTION

List some of the requirements for automatic sprinkler systems in hazardous occupancies.

10–44

46 of 49

�Summary

  • During the course of an inspection, an inspector may encounter materials that may individually or in combination pose a risk or hazard.

#–45

(Cont.)

47 of 49

�Summary

  • It is essential for an inspector to recognize these potential hazards and have them removed, modify the way hazardous materials are stored, or provide for measures that reduce risks to acceptable levels.

#–46

(Cont.)

48 of 49

�Summary

  • The inspector must also be familiar with the maximum allowable quantities of hazardous materials that are permitted based on occupancy type and the materials themselves.

#–47

(Cont.)

49 of 49

�Summary

  • Hazardous and High-hazard occupancies require special attention because of the materials involved and potential for a catastrophic event.

#–48