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Sample Throughput Optimization for

Thermal Desorption Spectroscopy

Ethan Greene, Jamie Lee, Saul Rios, Leo Serbinov, Vedanth Talla, Brayden Wong

Department of Mechanical and Aerospace Engineering at University of California San Diego

Sponsored by PISCES Lab

Scan this QR code to visit the team website! Includes CAD, videos, reports, and project management

Final Design

  • Tests 8 samples in 1 work day
  • Divided into two sections divided by a gate valve:
    • Sample Loading Chamber
    • Sample Testing Chamber
  • Grabber moves samples within system
  • Three actuators
    • Sample Transporter: Provides linear motion and opening and closing of the grabber
    • Storage Actuator: Provides vertical motion for a sample storage elevator
    • Thermocouple Actuator: Moves thermocouple wire on and off of the sample

Overview

This project, as sponsored by the PISCES Lab within UC San Diego’s Center for Energy Research, focuses on the development of a sample loading system for a thermal desorption spectroscopy (TDS) system. TDS occurs at ultra high vacuum pressures (1.33*10-7 Pa) and at samples are heated to 1100 ℃.

Primary Objective: Increase the throughput of samples tested each workday by developing a sample loading system that can exchange samples in vacuum conditions.

Functional Requirements

  • Ability to test at least 5 samples in one day
  • Chamber remains at vacuum pressures during sample exchange and testing
  • All materials are resistant to outgassing
  • Thermocouple is in contact with sample during testing

Hardware Testing

Testing Performance

  • System was tested with acrylic models in place of quartz pieces and a temporary, shorter sample transporter due to long lead times
  • Grabber is effectively able to move linearly and open and close using the sample transporter
    • Temporary sample transporter had weak magnetic coupling making it difficult to extend grabber at times
  • Sample loading process takes ~15 minutes
    • With TDS testing taking 1 hour per sample, the system is able to test 8 samples within a 10 hour period
    • Increases sample throughput by a factor of 8

Components

Sample Holder

  • Fused Quartz
  • Allows for sample faces to remain

untouched by grabber

  • Can be manufactured for different

sample sizes

    • Adjust hole size or shape

Grabber

  • 304 Stainless Steel
  • Forklift design
  • Attaches to 2 DOF actuator
    • Linear movement
    • Rotational DOF: opens and

closes grabber

Elevator

  • 304 Stainless Steel
  • Modular Design
  • 8 sample holder slots

Sample Pedestal

  • Fused Quartz
  • Holds sample holder in place during

TDS testing

  • Located in sample testing chamber

Thermocouple Attachment

  • 304 Stainless Steel
  • Grabs onto thermocouple wire
  • Attached to thermocouple actuator
    • Allows for thermocouple wire to

move on and off of sample

Sample Testing Chamber

  • Fused Quartz & Borosilicate

Glass

  • Where TDS testing occurs

Future Improvements

  • Fully autonomous sample loading process
    • Utilize motorized actuators
  • Thicker thermocouple wire
    • Increased rigidity, easier to manipulate

Impact on Society

  • Research from the TDS system is conducted as part of a multinational project: ITER
    • ITER is developing the world’s largest Tokamak
    • PISCES analyzes wall materials of Tokamaks to improve the material performance and longevity
  • ITER aims to produce the world’s first nuclear fusion power producing energy system
    • Reduce reliance on carbon energy
    • Mitigate climate change

Acknowledgements

  • PISCES Lab at UC San Diego
  • Simon Moore and George Tynan
  • Professor Jerry Tustaniwskyj
  • Thomas Chalfant and Chris Cassidy

References

[1] “Making it work.” ITER, 13 December 2024, http://www.iter.org/fusion-energy/making-it-work.

Gate Valve

Sample Testing Chamber

Sample Loading Chamber

Storage Actuator

Sample Transporter

Figure 1: CAD Assembly of Sample Loading System

Sample Exchange System

Figure 9: CAD of Grabber and Sample Storage Unit

Thermocouple Actuator

Figure 3: CAD of Grabber

Figure 2: CAD of Sample Holder

Figure 5: CAD of Sample Pedestal

Figure 6: CAD of Thermocouple Attachment

Figure 4: CAD of Sample Elevator

Figure 10: CAD of Grabber and Sample Pedestal

Figure 15: ITER’s Tokamak [1]

Figure 7: Render of Sample Testing Chamber

Thermal Analysis

  • Testing chamber is made from quartz to withstand 1100 ℃ temperatures
    • Must transition to glass to connect to CF Flanges, glass has a lower temperature range. Must transition materials 0.126 m from heater.

Figure 8: Ansys Thermal Analysis of Sample Testing Chamber

Figure 11: Final Assembly

Figure 13: Stainless Steel Grabber

Figure 14: Acrylic Models of the Sample Holders and Sample Pedestal

Figure 12: Final Elevator