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TEMPERATURE, HEAT, AND PHASE CHANGES

Vincent van Gogh

Landscape with Wheat Sheaves and Rising Sun

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PHASE CHANGES

  • Phase changes occurs when enough energy is added to a substance (endothermic process) or released by the substance (exothermic process) that the intermolecular forces change enough to form a new phase.

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PHASE CHANGES

Solid → Liquid → Gas

Endothermic

Weaker Intermolecular Forces

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PHASE CHANGES

Gas → Liquid → Solid

Exothermic

Stronger Intermolecular Forces

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PHASE CHANGES

States Changing

Phase Change Name

Endothermic or Exothermic

Solid → Liquid

Melting

Endothermic

Liquid → Solid

Freezing

Exothermic

Liquid → Gas

Vaporization

Endothermic

Gas → Liquid

Condensing

Exothermic

Solid → Gas

Sublimating

Endothermic

Gas → Solid

Deposition

Exothermic

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HEATING CURVE

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HEATING CURVE

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TEMPERATURE DEPENDS ON PARTICLE MOVEMENT!

  • All matter is made up of atoms that are moving (have kinetic energy)…even solid objects have atoms that are vibrating.
  • The motion from the atoms gives the object energy.
    • Solid = vibrate (jiggle) but do not move from place to place.
    • Liquid = vibrate but can slide past each other.
    • Gas = vibrate and move independently at high speeds.

Solid

Liquid

Gas

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TEMPERATURE

  • Temperature: The measure of the average kinetic energy of all the particles in the object
  • KE = ½ mv2
  • TK = TC + 273

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HOW DOES A THERMOMETER WORK?

A thermometer can measure temperature because the liquid inside expands (rises) when heated or contracts (lowers) when cooled by a linear amount.

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THERMAL EXPANSION

  • All gases, liquids, and most solids (water is the exception) expand when their temperature increases.

  • This is why bridges are built in short segments with small breaks to allow for expansion.

Expansion joints such as this one are used in bridges to accommodate thermal expansion.

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THERMAL ENERGY

If each of the objects to the right is the same temperature, which has more thermal energy?

the total kinetic energy of particles in an object.

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LET’S TALK ABOUT TEMPERATURE

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TOUCH THE TWO OBJECTS�STYROFOAM BLOCK VS. METAL BLOCK

  • Which has the higher temperature?
  • How do you know?
  • What does that mean?
  • What about the temperature of the room? Both objects are in this room.
  • Let’s measure the temperature of the two objects with an infrared thermometer...
  • Whoa! Why do the two object feel different but are the same temperature?

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ICE ON THE TWO OBJECTS

  • If ice is placed on both of the objects, what will happen?
  • Let’s try!
  • Whoa...what happened and why?

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WHY DID THE METAL FEEL COLDER THAN THE STYROFOAM?

  • The metal transferred heat faster than the Styrofoam.
  • Why would this make the metal feel colder (a lower temperature?)

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ENERGY FLOWS FROM WARMER TO COOLER OBJECTS (ALWAYS!)

  • Heat: the flow of energy from a substance at a higher temperature to a substance at a lower temperature.

Example: Placing a cold spoon in hot water

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MEASURING HEAT

What are the units of heat?

  • calorie (cal): The amount of energy needed to raise the temperature of 1 gram of water by 1oC
  • Joule (J): the SI unit of energy

  • 1.00 calorie= 4.18 J

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SOME SUBSTANCES CHANGE TEMPERATURE MORE EASILY THAN OTHERS.

Specific Heat:

the amount of energy required to raise the temperature of 1 gram of a substance by 1oC

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SOME SUBSTANCES CHANGE TEMPERATURE MORE EASILY THAN OTHERS.

  • Substances with a lower specific heat require less energy to change their temperature.
  • Substances with a higher specific heat require more energy to change their temperature.

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WHY DID THE METAL FEEL COLDER THAN THE STYROFOAM?

  • The metal had a lower specific heat than the styrofoam so the metal transferred heat faster than the styrofoam.
  • Why would this make it feel colder (a lower temperature?)