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Starter: Ionic Equations

1) 2Al + 6HNO3 🡪 2Al(NO3)3 + 3H2

2) Sr + H2SO4 🡪 SrSO4 + H2

Challenge:

3) NaCl(aq) +AgNO3​(aq) →NaNO3​(aq) + AgCl(s)

4) 2NaCl(aq) + CuSO4(aq) 🡪 Na2SO4 (aq) + CuCl2 (s)

CHALLENGE HINT:

Only aqueous ionic compounds can be broken down into their ions. Solids (precipitates) do not break down into ions and have a neutral charge.

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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1) 2Al (s) + 6HNO3 🡪 2Al(NO3)3 + 3H2

2Al + 6H+ + 6NO3- 🡪 2Al3+ + 6NO3- + 3H2

2Al + 6H+ 🡪 2Al3+ + 3H2

Al loses 3 electrons

H gains 1 electron

Oxidation

Reduction

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

3 of 16

2) Sr + H2SO4 🡪 SrSO4 + H2

Sr + 2H+ + SO42- 🡪 Sr2+ + SO42- + H2

Sr + 2H+ 🡪 Sr2+ + H2

Sr loses 2 electrons

H gains 1 electron

Oxidation

Reduction

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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3) NaCl(aq) +AgNO3​(aq) →NaNO3​(aq) + AgCl(s)

Na+ + Cl- + Ag+ + NO3- 🡪 Na+ + NO3- + AgCl

Cl- + Ag+ 🡪 AgCl

Cl- loses 1 electron

Ag gains 1 electron

Oxidation

Reduction

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

5 of 16

4) 2NaCl(aq) + CuSO4(aq) 🡪 Na2SO4 (aq) + CuCl2 (s)

2Na+ + 2Cl- + Cu2+ + SO42- 🡪 2Na+ + SO42- + CuCl2

2Cl- + Cu2+ 🡪 CuCl2

Cl loses 1 electron

Cu gains 2 electrons

Oxidation

Reduction

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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Electrolysis - Recap

+

+

-

P

A

N

I

C

OSITIVE

NODE

EGATIVE

S

ATHODE

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

7 of 16

Molten Ionic Compounds

A molten compound has been melted.

This means the ions are free to move.

E.g.

Molten Lead bromide

Pb2+

Pb2+

Pb2+

Pb2+

Br-

Br-

Br-

Br-

Br-

Br-

Br-

Br-

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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Molten Ionic Compounds

E.g.

Molten Cobalt (II) chloride

Co2+

Cl-

Co2+

Co2+

Co2+

Cl-

Cl-

Cl-

Cl-

Cl-

Cl-

Anode – Chlorine gas

Cathode –

Cobalt solid

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

9 of 16

Learning Check – Molten Ionic Compounds

Each of the molten compounds below are electrolysed.

State what ions are present in each compound.

Describe what would be given off at the anode and cathode.

  • Magnesium oxide
  • Zinc (II) fluoride
  • Silver chloride
  • Iron (III) oxide
  • Potassium bromide
  • Sodium chloride
  • Potassium selenide
  • Magnesium telluride
  • Lithium nitride
  • Beryllium phosphide

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

10 of 16

Compound

Ions

Anode

Cathode

Magnesium oxide

Zinc (II) fluoride

Silver chloride

Iron (III) oxide

Potassium bromide

Sodium chloride

Potassium selenide

Magnesium telluride

Lithium nitride

Beryllium phosphide

Mg2+

O2-

Zn2+

F-

Ag+

Cl-

Fe3+

O2-

K+

Br-

Na+

Cl-

K+

Se2-

Mg2+

Te2-

Li+

N3-

Be2+

P3-

Oxygen (gas)

Magnesium (solid)

Fluorine (gas)

Zinc (solid)

Chlorine (gas)

Silver (solid)

Oxygen (gas)

Iron (solid)

Bromine (gas)

Potassium (solid)

Chlorine (gas)

Sodium (solid)

Selenium (solid)

Potassium (solid)

Tellurium (solid)

Magnesium (solid)

Nitrogen (gas)

Lithium (solid)

Phosphorus (solid)

Beryllium (solid)

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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Aqueous Compounds

An aqueous solution is found where a ionic compound has been dissolved in water.

The ions are free to move BUT there are more ions to consider.

Water molecules ionise to form hydrogen ions and hydroxide ions.

H2O H+ + OH-

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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Co2+

Cl-

H+

OH-

Co2+

Co2+

OH-

OH-

Cl-

Cl-

H+

H+

H+

Positive Ions –

Co2+

H+

Negative Ions –

Cl-

OH-

Rule 1

The more reactive ion will remain in the solution, the less reactive ion will move.

Rule 2

If a halide ion is present in solution, the halogen will be produced at the anode.

What is the pH of the remaining solution?

E.g.

Aqueous Cobalt (II) chloride

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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E.g.

Aqueous Copper sulphate

Cu2+

OH-

SO42-

H+

H+

H+

H+

Cu2+

Cu2+

Cu2+

OH-

OH-

SO42-

SO42-

OH-

Positive Ions –

Cu2+

H+

Negative Ions –

SO42-

OH-

Describe what will be seen at the anode and the cathode.

Copper (Solid) at the Cathode

Oxygen (gas) at the Anode

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

14 of 16

Learning Check – Aqueous Ionic Compounds

State what ions are present in each compound.

Describe what would be given off at the anode and cathode.

  • Copper chloride
  • Sodium chloride
  • Silver bromide
  • Iron (II) sulphate
  • Manganese nitrate
  • Barium fluoride
  • Lead carbonate
  • Chromium (III) sulphate
  • Silver fluoride
  • Magnesium carbonate

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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Compound

Ions

Anode

Cathode

Copper chloride

Sodium chloride

Silver bromide

Iron (II) sulphate

Manganese (II) nitrate

Barium fluoride

Copper carbonate

Chromium (III) sulphate

Silver fluoride

Magnesium carbonate

Cu2+ H+

Cl- OH-

Na+ H+

Cl- OH-

Ag+ H+

Br- OH-

Fe2+ H+

SO42- OH-

Mn2+ H+

NO3- OH-

Ba2+ H+

F- OH-

Cu2+ H+

CO32- OH-

Cr3+ H+

SO42- OH-

Ag+ H+

F- OH-

Mg2+ H+

CO32- OH

Chlorine (gas)

Copper (solid)

Chlorine (gas)

Hydrogen (gas)

Bromine (gas)

Hydrogen (gas)

Oxygen (gas)

Hydrogen (gas)

Oxygen (gas)

Hydrogen (gas)

Fluorine (gas)

Hydrogen (gas)

Oxygen (gas)

Copper (solid)

Oxygen (gas)

Hydrogen (gas)

Fluorine (gas)

Silver (solid)

Oxygen (gas)

Hydrogen (gas)

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.

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Exam Questions

Complete the exam question on Electrolysis.

Choose the difficulty of questions that you need to start with.

Starter

Activity 1

Learning Check

Activity 2

Learning Check

Activity 3

Learning Check

Activity 4

Learning Check

Electrolysis

Wednesday, 11 December 2019

Grade 8

Explain why different gases are released at the electrodes in aqueous solutions.

Grade 8

Explain why electrolysis can only occur when an ionic compound is molten or aqueous.

Grade 6

Describe electrolysis in terms of movement of ions.

HOT Question:

Explain why different molecules are released from the anode and cathode depending on the solution.