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Replacing the Whole Barrel: �An Overview of Sustainable and Renewable�Biofuels and the Emerging Bioeconomy��For Parul University Presentation�January 9, 2024��Joanne Ivancic, Executive Director for Advanced Biofuels USA

Advanced Biofuels USA

www.AdvancedBiofuelsUSA.org

+1 301-644-1395

WhatsApp 301-524-6841

Copyright 2023 Advanced Biofuels USA

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Advanced Biofuels: A Truly Sustainable Renewable Future

Advocates for the adoption of advanced biofuels as an

        • energy security,
        • military flexibility,
        • economic development
        • climate change mitigation
        • pollution control

solution.

Advanced Biofuels USA

501(c)3 Nonprofit Educational Organization

Founded April 2008

Frederick, MD

Website:

www.AdvancedBiofuelsUSA.org

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Advanced Biofuels USA Home Page www.AdvancedBiofuelsUSA.org

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Before we start:��What do you think of when you hear �“bioenergy”?

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Does it include energy for transportation?

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What do you think of when you hear biofuel”?

  • Corn-based Ethanol?
  • Biodiesel from used cooking oil, canola/rapeseed?
  • Ethanol from sugar cane, cassava, sugar beets?
  • Renewable jet fuel?

Your answer might depend on where you live.

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What Are Sustainable Renewable Fuels?

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What are they?

What are they used for?

How are they made?

Why are they important?

Jobs/Careers throughout

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What Are Sustainable Renewable Fuels?

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What are they?

What are they used for?

How are they made?

Why are they important?

Jobs/Careers throughout

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What Are Sustainable Renewable Fuels?

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What are they?

What are they used for?

How are they made?

Why are they important?

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Some Considerations:� -Low-cost feedstock� -Low nutrient inputs� -Don’t harm environment� -Conversion processes are energy and water efficient� -Equal or better performance than fossil fuels

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What Are Sustainable Renewable Fuels?

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Ethanol is a biofuel, �not the only biofuel. ��Biodiesel�Renewable Diesel�Sustainable Aviation Fuel (SAF)�Bio-isobutanol�Renewable Natural Gas�rDME, Bio-CNG, Bio-LNG, Bio-PNG�Drop-in hydrocarbons�Marine/Maritime Fuel and more

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What Are Sustainable Renewable Fuels?

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Corn-based ethanol, sugarcane ethanol(nearly 200 proof moonshine or 100% ethanol) ��One of the few currently commercially available biofuels you can buy for vehicles today. Blends of 10%, 15%, 30%, 85% ��Replaces MTBE, provides octane.

  • And the ethanol molecule is part of many other things too.

      • Wine
      • Beer
      • Whiskey/Whisky

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“First Generation” Biofuel

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What Are Sustainable Renewable Fuels??

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What are they?

What are they used for?

How are they made?

Why are they important?

 

 

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The Citröen Rosalie

Ford Model T

What Are Sustainable Renewable Fuels Used For?Yesterday: Early Automobiles

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What Are Sustainable Renewable Fuels Used For?Today

  • Fueling Cars, Trucks, Trains, Equipment
    • Replace MTBE
    • Octane
    • Ultra Low Sulfur
  • Fueling Aircraft

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If you have a flex fuel vehicle (FFV), you can use gasoline with blends up to 85% ethanol.

Look for the logo, check your owner’s manual or look at the info on the driver’s side door.

What Are Sustainable Renewable Fuels Used For?Today Flex Fuel Vehicles

If you have a diesel engine, you might see a decal that indicates it was built to use up to 20% biodiesel, B20

Or, you can retrofit older cars to use E85

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What Are Sustainable Renewable Fuels Used For?�Today

Sustainable Aviation Fuel (SAF)

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What Are Sustainable Renewable Fuels Used For?Today

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Fueling Trains with Biodiesel and Renewable Diesel

From Diesel Technology Forum: LA’s Metrolink and Bay Area’s Capitol Corridor Commuter Rail Service Both Invest in New Advanced Diesel Engines Powered with 100% Renewable Diesel

18 new trains for regional passenger rail services in Groningen and Friesland, the Netherlands will be powered by biodiesel.

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What Are Sustainable Renewable Fuels Used For?Today

Fueling Buses with Renewable Natural Gas (RNG)

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Buses with Biodiesel, Renewable Diesel and Hydrogen

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What Are Renewable Fuels Used For?�Today

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What Are Renewable Fuels Used For?�Today

Fueling Trucks with Renewable Natural Gas, Biodiesel and Renewable Diesel

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What Are Sustainable Renewable Fuels Used For?�Today

Heating oil

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What Are Renewable Fuels Used For?�Today

Ethanol Cook Stoves

Project Gaia:

Nigeria

Ethiopia

Haiti

Brazil

Tanzania

KOKO’s “ATM” Dispensers

Kenya

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What Are Sustainable Renewable Fuels Used For?�Today

  • Military Aviation Fuels

  • Military Marine Fuels

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What Are Sustainable Renewable Fuels Used For?Today

  • Maritime/Marine Fuels

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What Are Sustainable Renewable Fuels Used For?�Today

  • Green Racing: Indy 500 used 100% renewable in 2023

  • Le Mans used 100% biofuels starting in 2023

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  • Formula 1

Plans for 100% sustainable, renewable by 2026

(Formulas 2,3,4 also use renewables)

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What Are Renewable Fuels Used For? Today

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What Will Sustainable Renewable Fuels Be Used For?� Tomorrow

Fuels for high performance vehicles, E85 retrofit

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Hydrogen or Ethanol for Fuel Cells

E30 Sweet Spot

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What Will Sustainable Renewable Fuels Used For?�Tomorrow

  • Optimized Flex-Fuel Vehicles (FFV)
    • E85
    • E30

  • Drop-In Petroleum Fuel Replacements
    • The Rest of the Gallon
    • 100% Sustainable Aviation Fuel

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Ford Escape Hybrid E85

Toyota’s 100% ethanol plug in hybrid prototype introduced in India, August 2023

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What Will Sustainable Renewable Fuels Be Used For? Tomorrow

Rocket Fuel

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Missile Fuel: DARPA High Density JP-10 (BR-1)

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What Are Sustainable Renewable Fuels?

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How are they made?

Feedstock

Logistics

Technology

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Agriculture�Forestry�Aquaculture The Foundations�of the Bioeconomy Along with Waste Managementfor the Circular Economy

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Carbon Cycle

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Examples of Potential Feedstocks or Energy Crops

  • Sugars, Starches
  • Oil Seed Crops
  • Algae
  • Agave
  • Corn stover
  • Corn cobs
  • Energy cane
  • Sorghum
  • Forestry waste
  • Municipal waste
  • Sawdust
  • Chicken manure
  • Agricultural residues
  • Grasses such as
    • Switchgrass
    • Miscanthus
  • Sugar beets
  • Coffee grounds
  • Jatropha
  • Camelina
  • Paper/pulp mill waste
  • Industrial waste gases
  • Cashew apple
  • Thin Air
  • Halophytes

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  • Food/Animal Processing Residues
  • Water
  • Captured Carbon Dioxide

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Examples of crops/plants which are used for production of biofuels

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Soybeans, Corn, Rice, Wheat

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Examples of potential crops/plants which can be used for production of biofuels

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AGRICULTURAL RESIDUES

Corn Stover, Corn Cobs

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Examples of potential crops/plants which can be used for production of biofuels

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Grain Sorghum

Milo

Forage Sorghum

Sweet Sorghum

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Examples of potential crops/plants which can be used for production of biofuels

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Sunflower or

Jerusalem Artichoke

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Examples of potential crops/plants which can be used for production of biofuels

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Canola/Rapeseed

Carinata

Camelina

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Examples of potential crops/plants which can be used for production of biofuels

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Arundo or Giant Reed

And many others

Miscanthus

Grasses

Phragmites

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Examples of potential crops/plants which can be used for production of biofuels

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Switchgrass

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Examples of potential crops/plants which can be used for production of biofuels

Energy Tobacco

Tyton Bioenergy Systems

Ready to Harvest, Danville, VA

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Examples of potential crops/plants which can be used for production of biofuels

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Sugar Cane

Sugar Cane Bagasse

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Examples of potential crops/plants which can be used for production of biofuels

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Sugar Beet/Sugar Beet Pulp

Energy Beets

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Examples of potential crops/plants which can be used for production of biofuels

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Cassava

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Examples of potential crops/plants which can be used for production of biofuels

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Jatropha

Moringa

Pongamia

Castor Bean

Jojoba

Croton

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Examples of potential crops/plants which can be used for production of biofuels

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Cashew Apple

Agave

Cactus,

Nopales

Date Palm Pits/Seeds, Waste

Sisal Bole

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Examples of potential crops/plants which can be used for production of biofuels

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Kenaf

Hemp and Cannabis Residues

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Examples of potential crops/plants which can be used for production of biofuels

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Nut Shells

Cotton Seed and Hulls

Rice Hulls, Husk

Rice or Wheat Straw

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Examples of potential crops/plants which can be used for production of biofuels

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Woody Biomass

Forest Waste and Residues

Sawdust

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Examples of potential crops/plants which can be used for production of biofuels

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Short Rotation Coppice Willow

Poplar

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Examples of potential feedstock which can be used for production of biofuels

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Duckweed/Lemna

Algae

Cyanobacteria

Seaweed

Kelp

Duckweed/Lemna

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Examples of potential feedstock which can be used for production of renewable fuels

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Sorted Municipal Solid Waste or Food Waste

Flue Gas

Brewers and Distillers Waste

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Used Cooking Oils

Fats

Grease

Examples of potential feedstock which can be used for production of biofuels

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Landfill Gas or Biogas from Animal or Food Processing Waste

Examples of potential feedstock which can be used for production of biofuels

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Renewable Fuels and Chemicals, �Not Just Bio-Based -- Recycling Carbon

  • Flue Gas/Industrial Waste Gas
  • Recycled Plastic, Tires
  • Municipal Waste
  • Carbon Capture and Reuse

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LanzaTech

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Water for Renewable Hydrogen

Examples of potential feedstock which can be used for production of renewable fuels

Renewable Hydrogen plus Carbon Dioxide to Methanol or Methane

Power to Fuel

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Not Just Renewable Fuels --�Co-Products!

  • Animal Feed
  • Agricultural and Forest Residues
  • Agricultural Co-Products
  • Food Processing Co-Products
  • Animal Manure/Waste (dairy cows, swine, poultry)
  • Brewery/Vineyard/Whisky
  • Biochar, Fertilizer
  • Carbon dioxide for dry ice, beverages and medical uses

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Celtic Renewables

Raisinor/U.C.V.A Distillery

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Feedstock Sustainability Criteria

Edible oil crops

Edible Sugars

1st gen-crop based

Advanced and waste

waste and residue lipids

purposely grown energy plants

Agricultural residues

Oil trees on degraded land

Rotational Cover Crops

Oil cover crops

Cellulosic Cover Crops

Forestry Residues

Wood Processing Waste

Municipal solid waste

Recycled Carbon

Non-biomass based

Reusable plastic waste

Industrial waste gas

CO2 from direct air capture (DAC)

CO2 from point source capture (CCS)

Other (e.g. gas from steel production)

Focus of analysis

Palm

Soybean

Other (incl. sunflower, rapeseed/canola)

Sugar Cane

Maize

Other

Used cooking oil (industrial or private sources)

Animal waste fat (tallow)

Other (incl. tall oil, technical corn oil, fish oil, POME, PFAD)

Jatropha, pongamia

Camelina, carineta, pennycress

Miscanthus, switchgrass, reed canary grass

Rice Straw

Sugarcane bagasse

Other (incl. corn stover, cereal residues)

Feedstock type

Feedstock Category

Feedstock

Substantial GHG savings potential

No fundamental sustainability concerns

Satisfied

Potentially Satisfied

Not Satisfied

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A Few Types of Jobs Available in Renewable Fuels Feedstock Development and Production

  • Agronomists
  • Farmers
  • Farm workers
  • Farm equipment designers
  • Biologists
  • Biologists specializing in genetic research
  • Biologists specializing in plant cells
  • Chemists
  • Chemical engineers
  • Researchers into bioenergy crop development
  • Agriculture/horticulture experts

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  • Freight railroad operators, engineers, loaders, unloaders
  • Equipment operators, technicians
  • Farm product purchasers/traders
  • Agricultural and Forestry Supervisors
  • Agriculture Economists
  • Agricultural Inspectors
  • Computer Software Engineers
  • Commodity Traders
  • Others?

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What Are Sustainable Renewable Fuels?

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How are they made?

Feedstock

Logistics

Technology

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Logistics: Harvest, Storage, Transport

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Logistics: Harvest, Storage, Transport

 

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Logistics: Harvest, Storage, Transport

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Logistics: Harvest, Storage, Transport

Storage of co-product, carbon dioxide (CO2), for carbon sequestration

Graphic from Rocky Mountain Coal Mining Institute

http://www.rmcmi.org/education/carbon-capture-storage#.X-zZi9hKhPY

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What Are Sustainable Renewable Fuels?

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How are they made?

Feedstock

Logistics

Technology

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Recycling Carbon Why is the sustainable renewable fuel industry concerned about capturing CO2 and CH4? Consider this reason:�

  • Microbes and yeast used in fermentation and anaerobic digestion use about 40-45% of the biomass put into reactors for their respiration. When finished with producing the enzymes and other chemicals used for fermentation and anaerobic digestion, the “bugs” exhale the CO2 and CH4 back into the atmosphere.
  • For renewable fuels to produce zero percent greenhouse gases, the CO2 must be reused or sequestered.

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Processes

  • Fermentation
  • Transesterification
  • Enzymatic Hydrolysis
  • Enzymatic Catalysis
  • Photosynthesis
  • Anaerobic Digestion

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Biochemical

Thermochemical/Catalysis

  • Gasification
  • Plasma arc gasification
  • Pyrolysis
  • Thermochemical conversion of sugars
  • Electrolysis
  • Hydrothermal Liquefaction (HTL)

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Overcoming the �Technical Roadblocks to Low-Cost Advanced Biofuel Production

-- Make all components of biomass available for biofuel and co-product production (Use the appropriate parts of specific plants)

-- Improve the efficiency of biomass to biofuel conversion (Do it faster, cheaper, sustainably)

-- Minimize the cost of biomass transportation (Move more for less)

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Why aren’t we there yet?� Biomass Recalcitrance

  • Lignin

(“You can make anything you want from lignin except money”)

  • Cellulose
  • Hemicellulose
  • Pectin

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Making Plant Biomass �Available for Biofuel Production �Biomass Recalcitrance

  • Cellulose, hemicellulose, pectin, & lignin intertwine to create complex cell wall matrices
  • This complex structure protects plants and trees from disease, moves nutrients, and provides for growth
  • These complex structures also restrict access to the “simple sugar” components
  • Current technologies to break up biomass: acid, ammonia, steam, or pressure, enzymatic hydrolysiscost intensive

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Making Plant Biomass �Available for Biofuel Production �Sugar Availability in Plant Cell Walls

  • Tree and grass cell walls have an additional component, lignin.

This is the “woody” material that gives trees great tensile strength

  • Cellulose, hemicellulose, and pectin are composed of monosaccharides strung together, they are called polysaccharides

  • Lignin is composed of polysaccharides and alcohols

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Making Plant Biomass �Available for Biofuel Production �Overcoming Biomass Recalcitrance

Researchers are pursuing at least four different approaches to overcome biomass recalcitrance

  1. 1. Reverse engineer plant cell wall genetics to discover enzymes that will “deconstruct” cell wall matrices
  2. 2. Adapt microbial “deconstruction” enzymes to dissolve cell walls

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Making Plant Biomass �Available for Biofuel Production �Overcoming Biomass Recalcitrance

  1. 3. Breed plants and trees with cell wall structures more amenable to enzyme solubility

  1. 4. Reduce costs and energy requirements of conversion processes

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Making Plant Biomass �Available for Biofuel Production �Overcoming Biomass Recalcitrance

Discover enzymes that will “deconstruct” cell wall matrices

Examples: Leaf Cutter Ants, Termites, Horse or Panda Feces, sea hare slugs.

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Praj 2nd Generation Ethanol and Bioplastics Work

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Virent’s BioForming Platform

Recent announcement of working with Cargill to use dextrose from corn ethanol production as feedstock

https://advancedbiofuelsusa.info/cargill-virent-collaborate-on-biobased-fuels-and-chemicals/

 

 

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Clariant ferments straw/stover/grasses/bagasse via enzymes and microorganisms to multiple products

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Anaerobic Digester

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Fermentation and Anaerobic Digestion as Integral Parts of Gevo’s

Net Zero 1 Biorefinery System

Anaerobic Digestion

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Anaerobic Digestion

Hydrogen (Bio-Hydrogen), E-Fuels

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Hydrogen (Bio-Hydrogen), E-Fuels: Cautions and Comparisons

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Recycling Carbon

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Synhelion uses RED II-certified CO2 and methane from biowaste as a carbon source to ensure clean production.

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Process Path: Biomass-to-Fuels and Products

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Graphic by Zina Deretsky, National Science Foundation

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Recycling Carbon

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Recycling Carbon

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Anaerobic Digestion

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Bright Renewables CO2 liquefaction plant is a prefab compact containerized technology

The facility consists of eight collector containers, with an annual capture capacity of 500 tons each. Iceland location; Swiss company

Co-product and/or Feedstock:

Carbon Capture and Storage or Use

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Water for Renewable Hydrogen via Electrolysis

Examples of potential feedstock which can be used for production of renewable fuels

Renewable Hydrogen plus Captured Carbon Dioxide to Methanol

Power to Fuel

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A Few Types of Jobs Available in Advanced Biofuels Production

  • Biologists
  • Biologists specializing in genetic research
  • Biologists specializing in plant cells
  • Chemists
  • Chemical engineers
  • Mechanical Engineers
  • Systems engineers
  • Research assistants
  • Lab technicians
  • Industrial engineers

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  • Industrial architects
  • Construction workers, Managers
  • Truck drivers
  • Plant operations managers
  • Equipment operators, technicians
  • Computer Software Engineers
  • Refinery Equipment Manufacturers
  • Welders
  • Boilermakers
  • Pipe Fitters
  • Others?

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What Are Sustainable Renewable Fuels?

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How are they made?

What are they used for?

Why are they important?

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What We Have

Why Replacing Fossil Fuel Is Important

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What We Could Have

Why Replacing Fossil Fuel Is Important

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Windmills and solar

can produce electricity

but cannot power jet airplanes.

Why Replacing Fossil Fuel Is Important

Virtually no oil is used to produce electricity in the US.

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Before oil runs out, it becomes more difficult and dangerous to extract.

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Why Replacing Fossil Fuel Is Important

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Before oil runs out, it becomes more difficult and dangerous to extract.

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Why Replacing Fossil Fuel Is Important

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Waste Management,

Landfill Management

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Why Replacing Fossil Fuel Is Important

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Solutions to Problems

  • Reduce carbon footprints
  • Erosion control
  • Waste water treatment
  • Remediation of contaminated soil
  • Nutrient management
  • Carbon sequestration
  • Alternative to carcinogens / Air Quality
  • Overflowing landfill relief/plastic recycling
  • Burning agricultural waste in fields
  • Grease (fatbergs) in sewers
  • Contaminated black market used cooking oil

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Why Replacing Fossil Fuel is Important

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Zero Emissions Vehicle…?

GHG Emissions

GHG Emissions

Nuclear

Coal Mining

Natural Gas Fracking

Power Plant

Solar

Wind

Hydro

Rare Earth Metal Mining

Batteries

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Zero Emissions Vehicle…?

GHG Emissions

GHG Emissions

Nuclear

Coal Mining

Natural Gas Fracking

Power Plant

Solar

Wind

Hydro

Rare Earth Metal Mining

Batteries

34%

20%

36%

0.33%

2.9%

1.35%

Captured methane: 0.3%

Solid Waste: 0.5%

Wood/Biomass: 0.17%

2019

Frederick, Maryland

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A Few Types of Jobs in Communicating Importance of Advanced Biofuels

  • Public Relations
  • Economic Development
  • Marketing/Sales
  • Elected Official
  • Federal Agency Staff
  • State Agency Staff
  • County/Local Administrative Staff
  • Journalists
  • Writers
  • Photographers
  • Broadcast Media Professionals

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  • Teachers
  • Teaching Assistants
  • Nonprofit Organization Staff
  • Advocates
  • Lawyers
  • Office Administrative Staff
  • Book Publishers
  • Event Organizers
  • Fundraisers
  • Celebrities
  • Others?

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Barriers and Challenges�Not as easy as we hoped!

TECHNICAL CHALLENGES, Biomass Recalcitrance, Enzyme Recycling, …

FINANCING “New” & “Never Been Done Before” Technologies …

POLICY ISSUES / CONTROVERSIES: Feedstock Cost Reductions, Efficient Land Use, Sustainability

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��

Advocates for the adoption of sustainable, renewable fuels as

  • energy security,
  • military flexibility,
  • economic development
  • climate change mitigation
  • pollution control

solutions.

Advanced Biofuels USA

501(c)3 Nonprofit

Educational Organization

Founded April 2008

Website:

www.AdvancedBiofuelsUSA.org

Frederick, MD

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��

Advanced Biofuels USA

501(c)3 Nonprofit

Educational Organization

Founded April 2008

Website:

www.AdvancedBiofuelsUSA.org

Frederick, MD

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Advanced Biofuels

for a

Truly Sustainable

Renewable

Future