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LOSS PREVENTION & COMPLIANCE | HSE TRAINING PROGRAM

The Globally Harmonized System (GHS),

HAZCOM & HAZMAT

Classification, Labeling, Communication, and Safe Management of Hazardous Materials

Prepared for: [Name Here]�Presented by: HSE Engineer�Reference Framework: UN GHS · GSO 2654 · SASO · OSHA 29 CFR 1910.1200 · NFPA · Aramco EHS Policies

Company Confidential — For Internal Training Use Only

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COURSE ROADMAP

Agenda & Learning Objectives

1

Understand GHS

Purpose, scope, and structure of the UN Globally Harmonized System of Classification and Labelling of Chemicals.

2

Apply Classification & Labeling

Interpret hazard classes, pictograms, signal words, and Safety Data Sheets (SDS).

3

Master HAZCOM Requirements

Elements of a compliant Hazard Communication program and workforce right-to-know.

4

Manage HAZMAT Safely

Identification, storage, segregation, transport, and emergency response for hazardous materials.

5

Apply the Aramco Framework

Align daily practice with Aramco EHS policy and Saudi/GCC regulatory obligations.

6

Strengthen LP&C Oversight

Use audit, inspection, and verification tools to drive compliance in the field.

Introduction

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INTRODUCTION

Why Hazard Communication Matters

Chemical incidents remain a leading cause of process safety events, occupational illness, and environmental non-conformance across the energy and petrochemical sector.

Unlabeled or mislabeled containers are a recurring root cause in incident investigations worldwide.

Inconsistent hazard communication across contractors, suppliers, and facilities increases exposure risk.

Regulators (SASO, GSO, OSHA) require documented classification, labeling, and training — not optional guidance.

A single uncontrolled hazardous material release can trigger safety, environmental, legal, and reputational consequences.

GHS 10

The UN GHS is now in its 10th revised edition, adopted or transposed by 80+ countries and jurisdictions.

1 System

One classification, one label, one SDS format — across the entire hydrocarbon and chemical supply chain.

Introduction

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SECTION 1 · GHS FUNDAMENTALS

What Is the GHS?

A Common Global Language for Chemical Hazards

The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is a United Nations framework — published in the "Purple Book" — that standardizes how chemical hazards are identified, classified, and communicated worldwide.

Developed under the UN Economic and Social Council (UN ECOSOC) Sub-Committee of Experts.

Harmonizes hazard classification criteria, pictograms, signal words, and hazard/precautionary statements.

Covers physical, health, and environmental hazards for substances and mixtures.

Adopted nationally through local regulation — e.g., US OSHA HazCom 2012, GCC GSO 2654, EU CLP.

CORE OBJECTIVES

Protect People

Ensure workers understand chemical risks before exposure occurs.

Enable Trade

Reduce duplicate testing/classification across borders.

Reduce Confusion

Replace multiple national systems with one framework.

Support Emergency Response

Give first responders consistent, reliable hazard data.

GHS Fundamentals

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SECTION 1 · GHS FUNDAMENTALS

History & Global Adoption

1992

Rio Earth Summit calls for a globally harmonized chemical classification system (Agenda 21).

2003

First edition of the UN GHS ("Purple Book") published by UNECE.

2012

US OSHA aligns the Hazard Communication Standard (HCS) with GHS — 29 CFR 1910.1200.

2021

GCC Standardization Organization issues GSO 2654:2021, adopting GHS across all six GCC states.

2023

UN GHS Revision 10 published — latest classification and labeling criteria.

Today

Saudi Arabia (SASO/GSO) and Aramco align internal EHS requirements to current GHS revisions.

Reference: United Nations, "Globally Harmonized System of Classification and Labelling of Chemicals (GHS)," Rev. 10 (2023), ST/SG/AC.10/30/Rev.10.

GHS Fundamentals

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SECTION 1 · GHS FUNDAMENTALS

Regulatory Framework — International & Regional

Authority

Key Instrument

Scope

Relevance

United Nations

UN GHS (Purple Book), Rev. 10

Global

Foundational classification & labeling criteria adopted by reference worldwide.

United States (OSHA)

29 CFR 1910.1200 — HazCom 2012

National

Aligns US Hazard Communication Standard with GHS; SDS & label requirements.

GCC (GSO)

GSO 2654:2021 — GHS in GCC Countries

Regional (GCC)

Regional technical regulation harmonizing GHS across all six GCC member states.

Saudi Arabia (SASO)

National Technical Regulations & Conformity Rules

Kingdom of Saudi Arabia

Enforces GSO/GHS technical regulations for chemicals placed on the Saudi market.

UN / IMO / ICAO

UN Model Regulations (Orange Book), IMDG, ADR

Transport

Governs classification & labeling of hazardous materials in transport.

NFPA / ANSI (USA)

NFPA 704, NFPA 30, ANSI Z400.1

Industry Practice

Facility hazard rating, flammable liquids storage, and SDS authoring format.

GHS Fundamentals

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SECTION 1 · GHS FUNDAMENTALS

The Aramco EHS Compliance Framework

Saudi Aramco integrates GHS, HAZCOM, and HAZMAT requirements into its enterprise EHS management system, aligning corporate policy with Kingdom regulation and global good practice.

1

Corporate EHS Policy

Aramco EHS Policy sets mandatory expectations for hazard identification, chemical safety, and process safety management across all business lines.

2

Engineering & Operating Standards

Aramco General Instructions (GIs), Engineering Procedures (SAEPs), and Engineering Standards (SAESs) translate policy into facility-level requirements for chemical handling, labeling, and storage.

3

National & Regional Regulation

Alignment with Saudi Arabia's SASO/GSO technical regulations (including GSO 2654 GHS) and Kingdom environmental and civil defense requirements.

4

International Reference Standards

UN GHS, OSHA HazCom, NFPA, and ANSI provide globally recognized technical benchmarks incorporated into Aramco practice.

Loss Prevention & Compliance teams verify this chain of compliance through audits, inspections, and management-of-change reviews.

GHS Fundamentals

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SECTION 2 · CLASSIFICATION & LABELING

GHS Hazard Classification Overview

Physical Hazards

Explosives, flammable gases/liquids/solids, oxidizers, gases under pressure, corrosive to metals, self-reactive substances.

Health Hazards

Acute toxicity, skin corrosion/irritation, respiratory/skin sensitization, carcinogenicity, reproductive toxicity, aspiration hazard.

Environmental Hazards

Hazardous to the aquatic environment (acute and chronic), hazardous to the ozone layer.

More than 25 distinct hazard classes are defined across these three categories, most with numerical sub-categories (e.g., Category 1 = most severe). Classification determines which pictogram, signal word, and hazard statement must appear on the label and SDS.

Classification & Labeling

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SECTION 2 · CLASSIFICATION & LABELING

GHS Label Elements

1

Product Identifier

Chemical name/identity consistent with the SDS.

2

Pictogram(s)

Red-bordered diamond symbols denoting hazard type.

3

Signal Word

"Danger" (more severe) or "Warning" (less severe).

4

Hazard Statement(s)

Standardized phrase describing the nature and degree of hazard (e.g., "Causes severe skin burns").

5

Precautionary Statement(s)

Recommended measures to minimize/prevent adverse effects — prevention, response, storage, disposal.

6

Supplier Identification

Name, address, and telephone number of the manufacturer/supplier.

Classification & Labeling

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SECTION 2 · CLASSIFICATION & LABELING

The Nine GHS Pictograms

GHS01

Explosives

GHS02

Flammables

GHS03

Oxidizers

GHS04

Gases Under Pressure

GHS05

Corrosives

GHS06

Acute Toxicity

GHS07

Irritant / Sensitizer

GHS08

Health Hazard (CMR)

GHS09

Aquatic / Environmental

Classification & Labeling

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SECTION 2 · CLASSIFICATION & LABELING

Safety Data Sheets (SDS) — 16-Section Format

Every hazardous chemical must be accompanied by an SDS in the standardized 16-section GHS format (ANSI Z400.1 / ISO 11014 aligned):

1. Identification

2. Hazard(s) identification

3. Composition/ingredients

4. First-aid measures

5. Fire-fighting measures

6. Accidental release measures

7. Handling and storage

8. Exposure controls / PPE

9. Physical & chemical properties

10. Stability and reactivity

11. Toxicological information

12. Ecological information

13. Disposal considerations

14. Transport information

15. Regulatory information

16. Other information

Highlighted sections (2, 4, 6, 8) are the most frequently referenced during field operations and emergency response.

Classification & Labeling

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SECTION 3 · HAZARD COMMUNICATION (HAZCOM)

What Is HAZCOM?

Hazard Communication (HAZCOM) is the regulatory and operational framework that ensures hazard information generated under GHS actually reaches the people who need it — most notably formalized in OSHA's Hazard Communication Standard, 29 CFR 1910.1200 ("HazCom 2012").

Hazard Classification

Chemical manufacturers and importers classify hazards of chemicals they produce or import.

Labels

Containers of hazardous chemicals must be labeled with pictograms, signal words, and hazard statements.

Safety Data Sheets

A 16-section SDS must be readily accessible to employees for every hazardous chemical.

Written Program & Training

Employers maintain a written HAZCOM program and train employees before initial assignment.

Hazard Communication (HAZCOM)

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SECTION 3 · HAZARD COMMUNICATION (HAZCOM)

HAZCOM Program Elements — Field Implementation

1

Chemical Inventory

Maintain an up-to-date master list of hazardous chemicals present at each facility or work site.

2

SDS Management

Collect, verify, and make current SDSs accessible to all shifts — physically or via approved digital systems.

3

Labeling Verification

Confirm primary and secondary (workplace) container labels meet GHS format before use.

4

Employee Training

Deliver GHS/HAZCOM training at onboarding, on new chemical introduction, and at periodic refresh intervals.

5

Contractor Coordination

Communicate site-specific chemical hazards to contractors per multi-employer worksite provisions.

6

Audit & Verification

Loss Prevention & Compliance validate program adequacy through scheduled and unannounced audits.

Hazard Communication (HAZCOM)

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SECTION 3 · HAZARD COMMUNICATION (HAZCOM)

Employee Rights & Responsibilities

The "Right to Know"

Access to SDSs for every hazardous chemical they may be exposed to.

Training on hazards, protective measures, and label/SDS content in a language and format they understand.

Access to their own chemical exposure and medical monitoring records.

The ability to raise hazard communication concerns without fear of reprisal.

Employee Responsibilities

Read and follow container labels and SDS instructions before use.

Use required PPE and engineering controls as specified for the chemical.

Never remove, deface, or bypass hazard labels on containers.

Report damaged labels, missing SDSs, or unlabeled containers immediately.

Hazard Communication (HAZCOM)

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SECTION 4 · HAZARDOUS MATERIALS (HAZMAT)

What Is HAZMAT?

A Hazardous Material (HAZMAT) is any substance or material capable of posing an unreasonable risk to health, safety, property, or the environment when improperly handled, stored, or transported.

HAZMAT MANAGEMENT DRAWS ON:

GHS classification — what the hazard is (health/physical/environmental).

UN Transport of Dangerous Goods (Orange Book) — how it may be moved.

NFPA 704 — facility-level fire/hazard rating for emergency responders.

Local civil defense & environmental regulation — permits, storage limits, disposal.

COMMON HAZMAT CATEGORIES

Flammable & Combustible Liquids

Compressed & Liquefied Gases

Corrosive Chemicals (Acids/Bases)

Toxic & Reactive Substances

Oxidizers & Organic Peroxides

Radioactive Materials (NORM)

Hazardous Materials (HAZMAT)

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SECTION 4 · HAZARDOUS MATERIALS (HAZMAT)

HAZMAT Management Lifecycle

1

Identify & Classify

Determine hazard class per GHS/SDS before procurement or use.

2

Label & Document

Apply compliant labels; ensure SDS accessibility at point of use.

3

Store & Segregate

Store per compatibility groups, quantity limits, and NFPA 704 ratings.

4

Handle Safely

Apply engineering controls, PPE, and safe work permits during use.

5

Transport Compliantly

Follow UN packaging, marking, and placarding requirements.

6

Dispose / Neutralize

Treat, neutralize, or dispose via licensed hazardous-waste channels.

Hazardous Materials (HAZMAT)

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SECTION 4 · HAZARDOUS MATERIALS (HAZMAT)

Storage & Segregation — NFPA 704

3

2

0

W

Red (Top):

Flammability

Blue (Left):

Health Hazard

Yellow (Right):

Instability / Reactivity

White (Bottom):

Special Hazard (e.g., W = reacts with water)

KEY SEGREGATION PRINCIPLES

Segregate incompatible classes (e.g., oxidizers away from flammables/organics) per SDS Section 7 & 10 guidance.

Store flammable liquids in approved, ventilated cabinets/rooms consistent with NFPA 30 quantity limits.

Maintain spill containment (bunding) sized for the largest container plus rainfall allowance where applicable.

Post NFPA 704 placards and GHS labels at storage area entrances and on bulk tanks/containers.

Restrict access to designated, trained personnel; maintain inventory reconciliation logs.

Locate emergency eyewash/shower stations and spill kits within immediate reach of storage areas.

Hazardous Materials (HAZMAT)

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SECTION 4 · HAZARDOUS MATERIALS (HAZMAT)

Emergency Response & Spill Procedures

1

Recognize

Identify the release using placards, labels, SDS, and NFPA 704 ratings before approaching.

2

Notify

Activate site emergency response per Aramco emergency notification procedures; alert Loss Prevention.

3

Isolate & Evacuate

Establish exclusion zones and evacuate non-essential personnel upwind/uphill of the release.

4

Respond (if trained)

Only HAZMAT-trained responders (per NFPA 472 competencies) attempt containment or mitigation.

5

Decontaminate

Decontaminate personnel and equipment before returning to normal operating areas.

6

Investigate & Report

Document the incident, conduct root-cause investigation, and report per Aramco incident procedures.

Hazardous Materials (HAZMAT)

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SECTION 5 · ASSURANCE

The Role of Loss Prevention & Compliance

LP&C teams provide independent verification that GHS, HAZCOM, and HAZMAT controls are effectively implemented — not just documented.

Compliance Audits

Periodic audits against GHS/HAZCOM/HAZMAT requirements and Aramco EHS standards.

Field Inspections

Verify labeling, SDS availability, storage segregation, and PPE use at the point of work.

Non-Conformance Management

Log findings, assign corrective actions, and track closure to prevent recurrence.

Standards Interpretation

Advise operations on applying evolving GHS revisions and Kingdom regulatory changes.

Incident Investigation Support

Contribute hazard-communication expertise to root-cause analysis of chemical incidents.

Training & Awareness

Partner with HSE to reinforce GHS/HAZCOM competency across the workforce and contractors.

Assurance

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CLOSING

Key Takeaways & References

Key Takeaways

GHS provides one global language for chemical hazard classification and communication.

HAZCOM turns that language into enforceable programs: labels, SDSs, training, and documentation.

HAZMAT management extends hazard communication into storage, transport, and emergency response.

Aramco compliance rests on aligning corporate policy with SASO/GSO and international standards.

Loss Prevention & Compliance are the assurance layer that makes the system real in the field.

Standards & References

• UN GHS (Purple Book), Rev. 10, 2023

• OSHA 29 CFR 1910.1200 — HazCom 2012

• GSO 2654:2021 — GHS in GCC Countries

• SASO National Technical Regulations

• NFPA 704 · NFPA 30 · NFPA 472

• ANSI Z400.1 / Z129.1 (SDS & labeling)

• UN Model Regulations on Transport of Dangerous Goods

• Saudi Aramco EHS Policy & General Instructions

Questions & Discussion

Thank you — Loss Prevention & Compliance | HSE Department