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Acid Base�in PICU�

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ACID - BASE

KISS

  1. THERE IS NEVER OVERCOMPENSATION (when you know pH, you have 1/3 of the answer

  • pH < 7.35 is always an acidosis

  • pH > 7.45 is always an alkalosis

  • Know the rules for estimating appropriate PaC02 ↔ HCO3

  • Use ∆ gap and (rarely) ∆ gap/ ∆ gap

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Step approach to acid base problems

1. pH?

Alkalosis : pH > 7.45

PaCO2 < 35 mm Hg ? : Respiratory

[HCO3] > 26 mM ? Metabolic

Acidosis: pH < 7.35

PaCO2 > 45 mmHg? : Respiratory

[HCO3] < 22 mM/L? : Metabolic

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Step approach to acid base problems

2. If Respiratory

is it acute or chronic: ? (HCO3/PaCO2)

3. If Metabolic

what is anion gap? > 20, then I ۫ metabolic acidosis

Is respiratory compensation (fall in PaCO2/HCO3) as predicted ?

4. What is excess AG ( ∆ Gap or gap-gap)

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ACID – BASE�20:1 rule

Metabolic (kidney)

pH = __________________

Ventilation (lung)

HCO3 20

pH = ___________ = ________

0.03 x PaC02 1

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ACID – BASE�balance between compensated HCO3 and PaCO2 is nearly 20:1

pH = 6.1+ log HCO3 / 0.03 PaC02

normal HC03 = ~ 24

normal PaC02 = ~ 40

(PaC02) 40 x 0.03 = 1.2

24/1.2 = 20

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ACID – BASE�

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Predicted change in pH

Acute Respiratory Acidosis 0.08 x [PaCO2-40÷10]

Chronic Respiratory Acidosis 0.03 x [PaCO2- 40÷10]

Acute Respiratory Alkalosis 0.08 x [40 - PaCO2÷10]

Chronic Respiratory Alkalosis 0.03 x [40-PaCO2÷10]

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ACID – BASE�balance between compensated HCO3 and PaCO2 is nearly 20:1

Cherniak, RM, Pulmonary Function Testing, WB Saunders Co., ed 2,1992

PaC02 40

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ACID – BASE�Metabolic Acidosis�balance between compensated HCO3 and PaCO2 is nearly 20:1

Cherniak, RM, Pulmonary Function Testing, WB Saunders Co., ed 2,1992

PaCO2 falls by 1 -1.5 mm Hg times the fall in [HCO3]

pH

PaC02 20

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Metabolic Acidosis

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ACID – BASE�Metabolic Alkalosis�balance between compensated HCO3 and PaCO2 is nearly 20:1

Cherniak, RM, Pulmonary Function Testing, WB Saunders Co., ed 2,1992

PaC02 should rise by 0.25 – 1.0 mm Hg times the rise in [HCO3]

PaC02 ~45

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Metabolic Alkalosis

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ACID – BASE� Respiratory Acidosis �balance between compensated HCO3 and PaCO2 is nearly 20:1

Cherniak, RM, Pulmonary Function Testing, WB Saunders Co., ed 2,1992

ACUTE

[HCO3] by 1 mM for each 10 mm Hg In PaCO2

CHRONIC

[HCO3] by 4 mM for each 10 mm Hg in PaCO2

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Respiratory Acidosis

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ACID – BASE� Respiratory Alkalosis�balance between compensated HCO3 and PaCO2 is nearly 20:1

Cherniak, RM, Pulmonary Function Testing, WB Saunders Co., ed 2,1992

ACUTE

↓ [HCO3] by 1 - 3 mM for each 10 mm Hg ↓ In PaCO2, but usually to no lower than ~ 18 mM/L

CHRONIC

↓ [HCO3] of 2-5 for each 10 mm Hg ↓ In PaCO2, but not to less than 14

PaC02 20

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Respiratory Alkalosis

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Step approach to acid base problems

1. pH?

Alkalosis : pH > 7.45

PaCO2 < 35 mm Hg ? : Respiratory

[HCO3] > 26 mM ? Metabolic

Acidosis: pH < 7.35

PaCO2 > 45 mmHg? : Respiratory

[HCO3] < 22 mM/L? : Metabolic

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Step approach to acid base problems

2. If Respiratory

is it acute or chronic: ? (HCO3/PaCO2)

3. If Metabolic

what is anion gap? > 20, then I ۫ metabolic acidosis

Is respiratory compensation (fall in PaCO2/HCO3) as predicted ?

4. What is excess AG ( ∆ Gap or gap-gap)

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Step approach to acid base problems

  1. What is excess AG ( ∆ Gap or gap-gap)

∆ gap = [calculated AG – nl AG (~12)] +measured HC03

if ∆ gap > nl Serum HCO3 (30), there is underlying metabolic alkalosis

if ∆ gap less than normal [HC03] (23), there is an underlying metabolic, non anion gap, acidosis

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< 15 mM/L

> 20 mM/L

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Metabolic Alkalosis�acid loss

    • GI
      • loss gastric secretions
      • chloride losing diarrhea
    • Renal
      • diuretics
      • mineralacocorticoid excess
      • low chloride intake
      • hypercalcemia
    • Sweat-
      • CF

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Metabolic Alkalosis

Retention of bicarbonate

    • massive transfusions
    • administration of bicarb
    • milk-alkali

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Metabolic Alkalosis�Diagnosis:�Urinary Chloride

Chloride Responsive

Urinary Cl < 10

Vomiting

NG loss

Post hypercapnea

Prolonged diuretic

Chloride Resistant

Urine Cl : 10 – 15

Mineralocorticoid excess

Cushing’s

Licorice

Severe K depletion

Bartter’s

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Treatment of alkalosis

Generally due to diuretics

    • distal nephron Na-H exchange in presence of high aldosterone levels
    • causes HCO3- reabsorption and urine Cl- loss

Replace Cl- to enhance renal HCO3- clearance

    • either NaCl or KCL
    • cut diuretics

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Treatment of alkalosis

Saline administration

Renal retention of NaCl in distal tubules

Allows secretion of HCO3-

fall in urine pH with treatment

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Treatment of alkalosis

Arginine Hydrochloride

Ammonium Chloride- beware in liver failure- metabolized to NH3

HCl 0.1-.2N - need central catheter

calculated doses

acid required in mEq/kg=

0.2 L/kg X [103-Cl-] or

0.5 L/kg X [HCO3- - 24]

give 1/2 dose over 3 hours then reassess

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Metabolic acidosis

  • NaHCO3 ?? Yes or No

  • Mechanical ventilation, rapid change in PaCO2 causing cerebral edema

  • Anion Gap, limitations

  • Δ gap, and its cousins

  • Strong Ion difference

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Sodium Bicarbonate for Acidosis�or not!!!!!!!!!!!!!!!!!

The data supporting treatment of pH alone does NOT EXIST …………………. pause ………………..icons fall,

ACLS : no data

In two RCT’s no difference between volume replacement and NaHCO3 therapy in improvement in global hemodynamics or response to catecholamines

Mathieu D, et al. Effects of bicarbonate therapy on hemodynamics and tissue oygenation in patients with Lactic Acidosis: a prospective controlled clinical study. Crit Care Med 19:1352,1991

Cooper DJ, et al. Bicarbonate does not improve hemodynamics in critically ill patients who have lactic acidosis. A prospective controlled clinical study. Ann Int Med 112:492, 1990.

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Sodium Bicarbonate for Acidosis�or not!!!!!!!!!!!!!!!!!

Negative side effects of NaHCO3:

  • Can increase production of lactate
  • Paradoxic acidemia (closed space)
  • Fails to improve intracellular pH
  • Na load, osmolar load
  • Transient decrease in BP and elevation in ICP with rapid infusion
  • Drops ionized calcium

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Sodium Bicarbonate for Acidosis�or not!!!!!!!!!!!!!!!!!

Recommended treatment if choose to use HCO3:

HCO3 defecit = 0.3 x BW in Kg x [HCO3 exp - HCO3 obs}

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Metabolic Acidoisis and Mechanical Ventilation: Hyperventilation in DKA �Tasker RC, etal. Hyperventilation in severe diabetic ketoacidosis Pediatr Crit Care Med 2005; 6 405-411.

pH CSF determines CBF

[HCO3] csf changes slowly over hours

PCO2 changes quickly across BBB

In DKA low [HCO3] csf and compensatory hyperventilation lowers PaCO2, and maintains a relatively increased pH csf

IF DKA patient intubated +/or given HCO3, and goal is normal PaCO2, then Pcsf CO2 ↑ rapidly, pH csf ↓ and brain may become hyperemic

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ACID – BASE� Hyperventilation in DKA �Tasker RC, etal. Hyperventilation in severe diabetic ketoacidosis Pediatr Crit Care Med 2005; 6 405-411.

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ACID – BASE�∆ Gap, ∆ / ∆, SID

Anion Gap (AG)

= Na – (Cl + HCO3)

= 12 ± 2 mEq/L

∆ Gap

= [calculated AG – Normal AG (12 mM)] + measured serum [HCO3]

∆ Gap > 30 there is underlying metabolic alkalosis

∆ Gap < 23 there is a non anion gap acidosis

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ACID – BASE�∆ Gap, ∆ / ∆, SID

Anion Gap (AG)

situations to know to avoid false interpretation

Profound metabolic alkalosis (elevated gap due to HCO3) pH > 7.5

Hypoalbuminemia (<3.0)

Excess or Deficit in Plasma Water (use SID)

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Anion gap acidosis

Renal Failure

Lactic Acidosis

Ketoacidosis (DKA, starvation, alcohol)

Rhabdomyolysis

Ingestions

ASA, methanol, ethylene glycol, paraldehyde, toluene

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Non gap acidosis

Acid Administration- hydrochloric acid administration, HAL

HCO3- losses

GI

Renal- RTA (proximal type 2), ketoacidosis

Impaired Renal Acid Excretion

RTA Type 1

with elevated K (Type 4 RTA)

Renal insufficiency

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Non gap acidosis

RTA

Distal RTA, Type 1

urine pH > 6, mild to moderate acidosis

Proximal RTA, Type 2

urine pH > 6, only mild acidosis

Type 4, (Hyperkalemic)

primary aldosterone deficiency, psuedohypoaldosteronism

Iatrogenic RTA

ampho B, aminoglycosides

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Non gap acidosis�RTA?

RTA ?

Urinary anion gap

[uNa +uK ] –[-uCl]

if Na + K is less than Cl, there is another cation, eg NH4, normal distal tubular acidification

If Na + K is greater than Cl, it suggests absence of possibility of distal RTA

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ACID – BASE�∆ Gap, ∆ / ∆, SID

Anion Gap (AG) and albumin

AG affected by negative charges on proteins, esp albumin

AG falls 2.5 mEq/L for every 1 g dL ↓ in [albumin]

Note :SID accounts for albumin, PO4

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ACID – BASE�metabolic acidosis �∆ / ∆,

∆ / ∆ (∆ anion gap / ∆ HCO3)

In Lactic Acidosis ∆ / ∆ usually 1.6: 1, why?

HL + NaHCO3 → NaL + H2CO3 → CO2 + H2O

looks like AG/HCO3 should be 1:1

But

lactate remains in ECF, whereas H + is 50% buffered by bone and cells (takes several hours)

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ACID – BASE�metabolic acidosis �∆ Gap, ∆ / ∆

∆ / ∆ (∆ anion gap / ∆ HCO3)

In Ketoacidosis 1:1 why?

urinary losses of ketoacids as Na and K salts of β Hydroxy buterate and aceto acetate

Lowers AG without affecting the [HCO3]

while in LA, urinary acid loss minimal (renal failure and tubular re uptake of lactate)

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ACID – BASE�metabolic acidosis �∆ Gap, ∆ / ∆,

∆ / ∆ (∆ anion gap / ∆ HCO3)

In DKA :AG ~ GFR

IF hypovolemic early on → low GFR

AG is high and ∆ / ∆ > 1.6/1 (looks like LA)

but,

when Volume and GFR restored

lose keto acids in urine and ∆ / ∆ is < 1 and AG near nl

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ACID – BASE�metabolic acidosis �∆ Gap, ∆ / ∆

∆ / ∆ (∆ anion gap / ∆ HCO3)

D Lactic Acidosis

Patient on multiple antibiotics post jejuno ileal bypass surgery;

ataxic, slurred speech.

Na 137, Cl 102, HCO3 13, LA 2, pH 7.22

AG = 22 ; ∆ Gap =23

∆ / ∆ (∆ anion gap / ∆ HCO3) = 10-12/ 10-12 = (~1)

????

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ACID – BASE�metabolic acidosis , ∆ Gap, ∆ / ∆

∆ / ∆ (∆ anion gap / ∆ HCO3)

D-lactic acidosis

short gut, CHO feeds, antibiotics, jejunal bypass

overgrowth of Gram + eg Lactobacillus

CNS symptoms: confusion, ataxia, slurred speech (drunk)

Episodic metabolic acidosis, AG is increased but

Increase in AG less than predicted (ie ∆ / ∆ low)

nl Lactate, no ketones,

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Blood Gases and Temperature�For the hypothermia range that we are using, the distinction is probably not clinically significant.�The implications of knowing which standard is being used...

the "alpha stat" standard (i.e. all ABG's measured at 37C)

"pH stat" standard (i.e. ABG's corrected for pt temp).

As the body is cooled:

total CO2 stores are constant, more CO2 is dissolved into the blood causing "alkalosis" (increased HCO3, decreased pCO2).

alpha stat standard,

No change in management

although the patient may be "alkalotic", the measured pH will be normal.

pH stat standard

decrease the minute ventilation on the ventilator and allow the pCO2 to rise to regain "normal" pH. As the patient is rewarmed, need to remember to increase the minute ventilation since he/she would become acidotic without any changes.

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Blood Gases and Temperature�

Which standard ?

Since humans are mammals (non hibernating) intuitively, could manage hypothermia in a pH stat manner

As cooling occurs "alkalosis" actually preserves the normal H+/OH- ratio, so at say 25C, a 7.4 pH is actually "physiologically acidotic" and the net result is that enzyme function may be impaired. It is believed that this "acidosis“ especially intra cell, is deleterious

So the alpha stat approach provides better cellular protection during deep hypothermic circ arrest.

ABG's ( U of M) are being reported by the alpha stat standard, so no special changes in patient management is needed.

ABGs ( U of M) are reported as PaO2 or PaCO2 measurements at 37 C. Temperature correction can be requested.

PaO2 decreases 7% per degree C lower than 37 C and PaCO2 decreases 4% per degree C lower than 37 C.

For temps > 37 C, opposite happens - PaO2 increases 7% per degree C greater than 37 C and PaCO2 increases 4% per degree C higher than 37 C.

So: appreciate that a PaCO2 of 35 (at 37C) is approximately 28 (at 32C).

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ACID – BASEmetabolic acidosis �SID

TWO DIAGNOSTIC SYSTEMS: based on assumptions or are calculated ( SBE)

1. PLASMA HC03 AND AG

2. BASE EXCESS/DEFECIT

NEITHER ACCOUNTS FOR NON HCO3 BUFFERS: ALBUMIN AND PHOSPHORUS, changes in water

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ACID – BASE�metabolic acidosis �SID

MAIN NON-HCO3 BUFFERS ARE

PLASMA PROTEIN(ALBUMIN)

INORGANIC PHOSPHORUS

Fencl, V Am J Resp Crit Care Med 2000. 162:2246-51

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SID calculations:

SID = [HCO3] +[ALB]+[Pi]

XA= ( [Na]+[K]+[Ca]+[Mg])-[Cl]-SID

CORRECTED CL =

WATER EXCESS/DEFECIT = ABNL Na

[Cl] corrected = [Cl] obs x [Na] nl/[Na]obs

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Close enough for jazz calculation

SID =

[HCO3]+ .28x[Alb]gms/dl+1.8 x [Pi]mmol/l

Usually 38 - 42

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ACID – BASE�metabolic acidosis �SID

HYPOALBUMINEMIA

ALB IS A WEAK ACID

In traditional analysis:

IN THE HCO3 or AG SYSTEM:

EFFECTS HCO3 ESTIMATE IN AG ESTIMATE

IN THE BE APPROACH

NO DISTINCTION BETWEEN A DEFICIT OR EXCESS OF NON VOLATILE Acid

HYPOALBUMINEMIA HAS AN ALKALIZING EFFECT

(deficit of weak acid)

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ACID – BASE�metabolic acidosis �SID

HYPOALBUMINEMIA HAS AN ALKALIZING EFFECT

(deficit of weak acid)

AG affected by negative charges on proteins, esp albumin

AG falls 2.5 mEq/L for every 1 g dL ↓ in [albumin]

Note :SID accounts for albumin, PO4

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SID in practice

The strong ion gap predicts mortality in children following cardiopulmonary bypass

Durard,A, Tibby SM, Skellet S et al. Pediatr Crit Care Med 2005; 6:281-285.

Raised Strong Ion Gap > 3 mEq/L correlated with 4 / 5 deaths

SIG was superior to serum Lactate as a predictor

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Defining Acidosis in postoperative cardiac patients using Stewart’s method of strong ion difference�Murray DM, Olhsson V, Fraser JI. Pediatr Crit Care Med 2004; 5:240-245.

SID=[HCO3] +[Alb]+[Pi]

Tissue Acids ([Na]+[K]+[Ca]+[Mg]) – [Cl]-SID

Unmeasured acids (UMA) given by:

TA=UMA+Lactate

AG corr = AG + .25 x [44-Alb obs]

Cl corr = Cl obs x [Na] nl/[Na] obs

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Defining Acidosis in postoperative cardiac patients using Stewart’s method of strong ion difference�Murray DM, Olhsson V, Fraser JI. Pediatr Crit Care Med 2004; 5:240-245.

150 samples; 44 pts; age: 3.5 months

25/44 CPB

TA in 60/150 samples

due to:

↑ UMA in 44/60(73%)

↑ LA in 6/60

↑ UMA and LA in 10/60

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Defining Acidosis in postoperative cardiac patients using Stewart’s method of strong ion difference�Murray DM, Olhsson V, Fraser JI. Pediatr Crit Care Med 2004; 5:240-245.

Hyperchloremia in 19/150

BD gave an apparent acidosis in 44/150, but in 21/44 TA was nl (<5 mEq)

BD was normal in 106, but 14/106 had ↑ in TA

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Defining Acidosis in postoperative cardiac patients using Stewart’s method of strong ion difference�Murray DM, Olhsson V, Fraser JI. Pediatr Crit Care Med 2004; 5:240-245.

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NOTE

Units for albumin’

Phos,

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18: COPD, CHF; low albumin is cause of Met Alkalosis. Traditional method reports a high HCO3 and BE of +9. but, SID, Na, Cl, and XA are nl.

This is simply a hypoalbuminemic metabolic alkalosis.

59: MSOF; SID is ⭣ by ~ 20. this is caused by both plasma H20 ⭡ , ⭡ Cl(corrected), and by ⭡ in XA.

The low albumin mitigates the SID acidosis. BE only detects ½ of change in SID. Note AG is low nl, but abnormal amount of anion showed by high XA. The acidemia is mitigated by the hypocapnea as one would predict.

Fencl, V Am J Resp Crit Care Med 2000. 162:2246-51

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18: COPD, CHF; low albumin is cause of Met Alkalosis. Traditional method reports a high HCO3 and BE of +9. but, SID, Na, Cl, and XA are nl.

This is simply a hypoalbuminemic metabolic alkalosis.

59: MSOF; SID is ⭣ by ~ 20. this is caused by both plasma H20 ⭡ , ⭡ Cl(corrected), and by ⭡ in XA.

The low albumin mitigates the SID acidosis. BE only detects ½ of change in SID. Note AG is low nl, but abnormal amount of anion showed by high XA. The acidemia is mitigated by the hypocapnea as one would predict.

Fencl, V Am J Resp Crit Care Med 2000. 162:2246-51

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63: Post Cardiac Arrest. There is a ⭣ SID of ~ 10, which results from high XA and low plasma water, which offset. The resultant low SID acidosis is hidden by the alkalinization secondary to the ⭣ albumin. BE misses the high XA acidosis and interprets this as a mild metabolic alkalosis. The HC03 is high end of nl, and AG misses the high abnormal anions. No Cl excess is present even though the Cl observed would suggest it.

The alkalosis is from low PaC02

81: ARDS and Sepsis; SID is reduced by ~12, owing to plasma water excess and very high XA and Pi. These are mitigated by the alkalosis from ⭣Cl, and low albumin thus the [HC03] is only slightly low. AG observed is ⭡, and Base deficit is only – 4. The severity of the acidosis is underestimated by traditional methods

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Blood Gases

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Blood Gases

Alveolar-arterial gradient

PAO2 – PaO2

(Pb – PH2O) x FiO2 – PaCO2/R

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Blood gases

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Shunt vs V/Q

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Ventilation ~ PaCO2

PaCO2 = .863 x CO2 Production

Rate (tidal volume – dead space)

VCO2 is a constant

Estimating in a close enough for jazz world:

Unless Vd increases, if RR or Vt increase, PaCO2

Falls arithmetically and proportionally

and vice versa