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UNIT II : PRIMARY TREATMENT

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Process Flow Sheet-I

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Process Flow Sheet-II

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Process Flow Sheet-III

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Unit operation Efficiencies

Type of treatment

Purification effected

process or unit employed

%BOD removal

%Solids removal

%bacterial removal

Preliminary Treatment

removal of floating materials

Coarse/fine screens

5-10%

2-20%

10-20%

removal of heavy settleable inorganics

Grit chamber or detritus tank

10-20%

20-40%

10-20%

removal of fats & grease

Skimming tank

20-30%

20-40%

10-20%

Primary Treatment

removal of suspended settleable organic solids

sedimentation tank

30-35%

60-65%

25-75%

septic tank

20-30%

40-60%

25-75%

Imhoff tank

30-40%

60-65%

25-75%

Secondary treatment

removal of fine suspended non-settleable solids and colloids including dissolved organic matter

chemical flocculation and sedimentation (seldom used)

50-85%

70-90%

40-80%

Intermittent sand filter with sedimentation (seldom used)

90-95%

85-95%

95-98%

Low rate trickling filter w/sedimentation

90-95%

70-92%

90-95%

high rate trickling filter w/sedimentation

65-95%

65-92%

80-95%

activated sludge treatment w/sedimentation

75-95%

85-90%

90-98%

oxidation pond

85-90%

85-90%

90-98%

Tertiary treatment

removal of pathogens and very fine dissolved organics

chlorination

100.00%

100.00%

100.00%

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WWTP: Basic Design Considerations

  1. Influent characteristics and strength
  2. Effluent Quality
  3. Design Loading
  4. Design parameters

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Design Considerations

Influent Strength and characteristics

(Taught in Unit-I)

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Design Considerations: Effluent Quality

  • Based upon ultimate disposal/reuse
  • Basis for selection of treatment process, unit operations and their design
    • Efficiency of treatment
    • Disinfection vs no-disinfection

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Design Considerations: Design Loading

  1. Hydraulic Loading
    1. In terms of volumes
  2. Mass Loading
    • In terms of mass of BOD or SS

  • Average, Maximum, Minimum loading???
  • Daily, Monthly, yearly??
  • Dry weather runoff (no stormwater runoff) or wet weather runoff (stormwater in rainy season)??

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Design loading (contd..)

  • Hydraulic loading: pump, pipes and hydraulically limited equipment design
  • Mass loading: aeration, sludge digestion equipment

  • Peak flow factor= Max flow/avg flow = 1.5 – 3.0
  • Minimum flow factor= Min flow/avg flow = 0.1 – 0.3

  • Check for max., min and average conditions. Units may be shut off during minimum flow. Scouring to be avoided during min. flow.
  • Max design: capacity underutilization, Min design: process overloading

  • Design multiple units

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Design Considerations: Design Parameters

  • Typically published criteria/standards (govn. Bodies-CPHEEO, India) for unit process design.
  • Obtained from research and laboratory scale model studies and field operational experience

  • Hydraulic criteria (flow Rates and detention time)
    • Sedimentation tank: weir loading rate, overflow rate, hydraulic detention time
  • Mass loading criteria:
    • Mass of BOD per volume of aeration tank
  • Geometric ratio (L:B:H)
    • Dead pockets/ Hydraulic short-circuiting due to incorrect L:B ratio
    • Inefficient hydraulic performance due to improper L:H ratio.

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Typical Design Loading criteria

Flow Measurement

Peak hourly flow

Bar Screen

Peak hourly flow

Pump

Peak hourly flow/Min. hourly flow

Grit Chamber

Max. monthly flow/ Peak hourly flow

Primary Settling

Max monthly flow

Biological Treatment

Max monthly BOD loading/peak hourly BOD loading (Check)

Final settling

Max monthly flow

Disinfection

Peak hourly flow

Sludge Thickening

Max daily sludge flow/max. solids loading (check)

Sludge digestion

Max monthly volatile solids load/max monthly sludge flow (check)

Sludge dewatering

Max sludge flow/max solids loading (Check)

Land application

Max nutrient loading (sludge)/max hydraulic loading (water)

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Principles of Reactor design

  • Reactors: The units or vessels that hold wastewater for treatment by chemical or biological process.

  • Basin/tank: units used for separation of solids from liquids by settling or floatation.

  • Reactors or tanks are generally rectangular or circular.

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Chemical/Biological Reactions

  • Homogeneous reaction: all reactants have same phase (solid, liquid or gas)
  • Heterogeneous reaction: reactants have more than one phase (e.g., reactions at interphases)
  • Reaction orders: 0, 1st and 2nd
  • Biological processes: Heterogeneous and 1st order
  • Biological reaction rate doubles for 10°C temperature rise.

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Reactor sizing

  • L:B and L:H for reactors or diameter of reactors
  • Influent and effluent conduits
  • Inlet and outlet chambers
  • Distribution and collection boxes
  • Hopper bottom sludge pockets
  • Scum removal mechanism
  • Surface/diffuse aeration system
  • Mixers/mechanical equipments
  • Pumps, etc.

Actual/Net reactor size also includes provisions for appurtenances- inlet/outlet, channels, sludge collection, etc.

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Types of reactors

  • Batch reactor
  • Plug-flow reactor (PFR)
  • Continuous-flow stirred tank reactor (CSTR)
  • Arbitrary flow reactor (AFR)
  • Fluidized bed reactor (FBR)
  • Packed bed reactor (PBR)
  • Sequencing batch reactor (SBR)

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Reactors: Batch reactor

  • Flow neither enters nor leaves the reactor during detention time, e.g. BOD bottle… L:B ~1
  • Assumptions: 1st order kinetics (BOD) and uniform reactant concentration throughout the reactor. Homogeneous reactions (reactants have same phase)
  • Application: bench-scale lab studies and sludge digestion.

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Reactors: Plug-flow reactor

  • FIFO (First-in-first-out) principle
  • Particles exit in the same order in which they entered.
  • No Longitudinal mixing. Each “plug” moves independently.
  • Reactions along the length, reactant concentration decreases and product’s increases.
  • Long and narrow reactors of large length and small width
  • May be made serpentine.
  • Homogeneous reactions
  • Grit channel or sedimentation tanks

Effluent, Qout, Cao

Influent, Qin, Cai

Q, Ca

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Plug Flow reactor

  • Continuous flow.
  • No variation with time (at a given space), but with space/position (at a given time).
  • With partial/complete recycling can mimic a CSTR
  • More efficient than a CSTR of same dimensions
  • Conservative dye (no reaction): [Influent]=[effluent]
  • 0 order reaction: removal rate constant, [reactant] decreases uniformly along length.
  • 1st order reaction: removal rate decreases along the reactor length, [reactant] decreases exponentially

Theoretically Ideal as longitudinal mixing is always there.

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Plug Flow Reactor

Reaction kinetics and concentration graphs for

      • Conservative tracer
      • 0 order reaction
      • 1st order reaction

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CSTR (continuous-stirred tank reactor)

  • The reactant is instantaneously dispersed in the reactor and is completely mixed.
  • Contents are continuously and uniformly redistributed.
  • Continuous flow and L:B~1
  • Homogeneous reaction
  • Concentration within reactor is same at all points
  • Effluent concentration is same as that inside reactor
  • No spatial (in space, given time) or temporal (in time, given space/position) variation (At steady state).

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CSTR

  • Conservative tracer: [influent]=[effluent]
  • Zero order reaction: same as Plug-flow, for same detention time and conditions
  • 1st order reaction: concentration same everywhere in reactor and is less than PFR.
    • Since, removal rate is function of concentration, CSTR is less efficient than PFR for 1st and higher orders.

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CSTR

Reaction kinetics and concentration graphs for

      • Conservative tracer
      • 0 order reaction
      • 1st order reaction

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CSTR vs. PFR

  • CSTR and PFR have same efficiency for conservative tracer and 0 order reaction.

  • PFR is more efficient than a CSTR for 1st and higher reaction orders.

  • PFR will act as a CSTR if sufficient recycling of the reactants is done.

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Arbitrary Flow Reactor

  • Plug-flow reactor designed with flow dispersion (intermixing).
  • Non-ideal reactor, intermediate between Plug-flow and CSTR
  • Not used in Wastewater treatment, since Biological processes are not designed with intermediate mixing.

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Fluidized Bed Reactor

  • Filled packing material expands and gets fluidized when influent wastewater moves upwards.
  • Air is also introduced along with influent flow at inlet.

  • Used in aerobic or anaerobic biological oxidation.
  • Also for sludge treatment and removal of dissolved gases.

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Packed Bed Reactor

  • Filled inert packing material for biomass growth is kept packed (or fixed).
  • Flow may be upward or downward
  • Packing material: slag, rock or ceramic
  • Can be made anaerobic, by completely filling closed reactor with media (UASB)

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Sequencing Batch Reactor

  • SBR is an activated sludge process and works on fill-and-draw principle.
  • Reactions for aeration, waste conversion and effluent clarification occur in same reactor, in time-sequence.
    • Steps:
        • Anoxic fill: reactor is filled with sewage up to desired volume
        • React: aeration & mixing for designated time period
        • Settle: clarification or sedimentation of biomass
        • Decant: clarified effluent is withdrawn to separate the sludge
        • Idle:

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Process Flow Sheet

  • Sequence of processes
    • (general) Order of appearance in STP
    • Already shown at the beginning of the unit

  • Summary of process function
    • What does the process do?
      • E.g., skimming tank (oil and grease removal), BOD/Solids/Bacteria removal (secondary trt.)
      • See the Table (slide#05)

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Primary Treatment

  • Screens
  • Oil and Grease removal
  • Grit Chamber
  • Primary Sedimentation Tank (PST)

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Screening

  • Removal of floating matter (pieces of clothes, woods, paper, etc.) by bars spaced (generally) at an angle
  • Protects pumps and other following units from debris
  • Coarse (or racks, spacing>50 mm) and Medium screens (6-40 mm bar spacing)
  • Fine screens not generally used with sewage
  • Bar screens: bars arranged on a rectangular steel/RCC frame at designed spacing and inclined at 30-60°
  • Collected debris is cleaned by manual or mechanical rakes.
  • Screen cleaning frequency is governed by head loss through screens.
  • Screenings (material collected) is disposed by incineration or composting.

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Coarse screen

Mechanical Fine Bar screen

Skimming Tanks

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Skimming Tank

  • Oil/grease removal unit, placed before sedimentation
  • Oil/grease forms scum on sedimentation tank and prevents biological activity in secondary treatment units
  • Compressed air blown from bottom causes the grease to coagulate and congeal (solidify) and rises to surface from where it is removed.
  • Skimming (removed oil/grease) is disposed off by burning
  • Hot weather may prevent coagulation of oil,
    • Provide oil/grease trap near source, before sewers
    • Oil/grease floats on top, outlet is near the middle or bottom of chamber.
    • Periodic cleaning of trap.

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Grit Chamber

  • Grit: Inorganics solids (e.g., pebbles, sand, egg shells, glass, metal fragments, ) and largers/heavier organics (bone chips, seeds, coffee/tea grounds, etc.)
    • Size> 0.2 mm, Specific gravity~ 2.65
    • Inorganic and/or putresciable (undergoes putrefaction)
  • Need:
    • Grit constituents are abrasive; causes accelerated wear on pumps and sludge handling equipments.
    • Absorbs grease and may solidify on pumps, sumps, clarifiers
    • Non-biodegradable (inorganics) occupy and waste space in sludge digestors.
  • Type I (gravity) sedimentation,
  • Enlarged channel area for reduced velocity & grit settling, grit removed by mechanical scrapper.
  • Grit disposed by landfilling and incineration

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Grit Chamber

  • Quantity:
    • 0.004-0.037 m3/1000 m3 (separate sewage system)
    • 0.004-0.18 m3/1000 m3 (combined sewage system)
  • Constant horizontal velocity (flow-through) of 0.3 m/s
    • 25% velocity increase: grit washout
    • 25% velocity decrease: retention of non-target organics
  • Velocity controlled by velocity control section, proportioning flow/sutro weir at effluent end or parabolic shaped channel

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Grit Chamber

  • Horizontal flow type:
    • Horizontal flow with constant velocity,

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Grit Chamber: Parshall Flume

  • Parshall Flumes added at the end of Parabolic (or V-shaped) grit chamber.
  • Has negligible head loss, provides smooth hydraulic flow and prevents solid deposition.

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Aerated Grit Chamber

    • Consists of spiral flow aeration tank, spiral velocity is controlled by dimensions/shape of chamber and air quantity
    • Also aerates anaerobic sewage
    • Detention period: 3 min (typical), 2-5 min (range)

2 chambered aerated grit chamber

single chambered aerated grit chamber

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Vortex type grit chamber

  • Cylindrical tank, flow enters tangentially creating vortex flow pattern,
  • centrifugal (flotation of organics, lighter particles) and gravitational (grit settling) forces causes grit separation
  • Detention time = 20-30 sec
  • Central turbine maintains flow velocity

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Grit Chamber: Detritus Tank

    • Rectangular chambers, smaller flow velocity (0.09 m/s) and longer detention (3-4 min), organics and fine suspended solids also removed, rising air bubbles separates organics and can be returned to flow

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Primary Sedimentation

  • Follows the screens, grit chamber and skimming units.
  • Removes suspended organic particles
  • Typically Type II settling occurs, without the application of coagulants
    • Sludge particles are sticky in nature and flocculate naturally
    • Flocculated particles settle down by gravity.
  • Sometimes, may also be clubbed with ASP process
    • Part of return sludge may be fed back to PST

    • May also be combined with skimming, which can be done at surface of sewage using scum removal mechanism

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PST

  • Rectangular or circular made of RCC
  • Long narrow rectangular tanks with horizontal flow or circular tanks with radial or spiral flow
  • Long detention period decreases flow velocity causing sedimentation of suspended organics, which are removed from sludge hopper situated at base of PST.
  • Clean effluent is collected using effluent weirs
  • Efficiency: 60-65% suspended solids & 30-35% BOD removal
  • Removal efficiency is function of overflow rate

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PST: Design criteria

  • Detention Time: 1.5-2.5 h; typical: 2 h
  • Overflow rate (m3/m2.d): average: 32-48, peak flow: 80-120
  • Weir loading rate (m3/m2.d): 125-500
  • Dimensions, m:
    • Rectangular: Length: 15-90, Depth: 3-5, width: 3-24
    • Circular: depth: 3-5, diameter: 3.6-60

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Rectangular PST

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Circular PST

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Sedimentation

  • Particles with S.G.>1 settle down when flow velocity reduces/turbulence is retarded.
  • Gravity or chemical-aided (coagulation-flocculation).
  • Settling tank/sedimentation tank/sedimentation basin/clarifier: Rectangular or circular

  • Gravity/Plain/Type-1 sedimentation
    • Specific Gravity > 1.
    • Sedimentation by gravity alone.

    • Discrete particles: size/shape/S.G. constant with time
    • Flocculent particles: properties change due to aggregation..

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Sedimentation theory

  • Flow velocity: slower velocity, better settling.
  • Flow/water Viscosity: low viscosity (at high temperature), better settling
  • Size, shape & specific gravity:
    • Higher specific gravity, better settling
    • Small sized particles settle slowly.

Stoke’s Law

Vs= (g/18). (G-1). (d2/ ) d< 0.1mm

Vs: settling velocity (m/s) for spherical particle (dia, d, in m)

G: specific gravity of particle

v: kinematic viscosity (m2/sec)

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Settling velocity

Vs = 1.8 {gd(G-1)}1/2 d> 1 mm

Vs = 418 (G-1)d (3T+70)/100

0.1 mm < d < 1 mm

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Circular Clarifier

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Schematic: Circular Clarifier

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Schematics: Rectangular Clarifier

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Plain Sedimentation (Type-I)

  • Flow velocity control by extended detention period.
    • Use of a long tank, (large area)…

  • Sludge continuously removed by mechanical scrapper.

  • Mainly horizontal flow type.

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Sedimentation (Type-I)

  • Rectangular Tank
      • Equal velocity at all points on each vertical line
  • Circular Tank
      • Uniform radial flow with decreasing velocity towards periphery.
  • Particle removal is independent of tank depth.

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Design Concept

  • Overflow Rate/Surface Overflow rate/Surface Loading:
      • Design velocity: theoretical time for which the particle stays in the tank.
      • Settling Velocity (Vs) vs. Loading Rate (Vo) determines the particle removal.
      • Units: m3/d/m2
      • Discharge per unit surface area.
      • Q/As
      • Typical Rates: 12-18 m3/d/m2

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Settling Column Analysis (Discrete Particles)

  • To determine the theoretical settling/removal efficiency of a given suspension.
  • Column of 2 m height is used.

  • Samples withdrawn regularly.

  • Theoretical % of particles removed
    • (100-X) + ʃ(Vs/V0).100.dX
    • X: fraction with Vs < V0

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PST: Issues

  • Short-circuiting:
    • Portion of flow escapes the tank before designed detention period.
    • Causes: local disturbances at inlet and outlet.
    • Prevented by using long-narrow channels, properly designed inlet and outlets.

  • Coagulant-aided sedimentation
    • Increases cost, obsolete/unnecessary since secondary processes are more efficient, skilled operation needed.
    • Not used in PSTs for STPs.

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PST Design

Q: A municipal wastewater treatment plant processes and average flow of 5000 m3/d, with peak flow up to 12500 m3/d. Design a primary clarifier assuming appropriate detention period and overflow rate.

Solution:

Assuming overflow rate= 35 m3/m2/d.

Surface area= 5000/35 m2 =143 m2

Circular tank: diameter = (4xarea/π)1/2 = 13.5 m

Assuming side wall depth of 3m,

tank volume = 143x4 m3

= 429 m3

Detention time = V/Q = 429/5000 d ~ 2 hrs.

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PST design: Numerical II

Q: Design a rectangular sedimentation tank for sewage treatment of a city, with a maximum daily water demand of 12 million lt. State the assumptions made.

Solution:

Assuming 80% of water supplied is converted to sewage.

Sewage volume = 12x0.8 = 9.6 million lt/day

Assuming overflow rate of 40,000 lt/m2/d,

Surface area = 9600000lt/40000 lt m2 = 240 m2

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PST Numerical II contd.

Assuming 30 m length, width = 8 m

Assuming depth = 3m, tank volume = 240x3 = 720 m3

Detention time = volume/discharge = 720/9600 d = 1.8 hrs

Provide a tank of 30 m x 8m x 3 m with a detention period of 1.8 hrs. (This does not include freeboard and space for sludge hopper at the base of PST)

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Settling column

  • Particles with Vs > V0 are removed 100%.
  • Particles with Vs < V0 are removed in ratio Vs/V0.

  • Steps:
      • Find particle size by sieve analysis.
      • Find settling velocity.
      • Do column analysis and prepare settling curve.
      • Use settling equation to find theoretical removal efficiency.