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Co-ordination Chemistry--- B.Sc.II
Ajara Mahavidyalaya, Ajara
Department of Chemistry
Dist. Kolhapur
Pin.-416505
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Coordination sphere includes---------------
*
2 points
non metals
metal ion
ligands
metal and ligands
[Co(NH3)6]3+ is----------spin complex
*
2 points
high
moderate
low
intermediate
As the electrons in [Fe(CN)6]3- are paired up, it is a ........ complex and is essentially a slightly paramagnetic due to a single unpaired electron.
*
2 points
low spin or spin-paired
high-spin or spin-paired
low spin or spin free
high spin or spin-free
Co3+ Ion-Excited state configuration on approach of NH3 ligand, leading to octahedral .............
*
2 points
d2sp3 hybridization
sp3d2 hybridization
sp3d hybridization
dsp3 hybridization
Valence bond theory is simple, conceptual and .......
*
2 points
qualitative
semi-qualitative
quantitative
logical
[Fe(CN)6]3 ion is---------
*
2 points
trigonal
inner orbital octahedral
outer orbital octahedral
tetrahedral
Primary valency is satisfied by--------------
*
2 points
neutral molecules
positive ions
negative ions
molecules
VBT was successfully applied to complexes by--------------
*
2 points
Linus Pauling
Alfred Werner
Sidgwick
Lewis
Auxiliary valency of cobalt in [Co(ONO)(NH3)5]SO4 is----------
*
2 points
7
5
6
2
Ligands are considered as----------
*
2 points
Charged species
Point charges
Point groups
Charged groups
Hybridisation in [Fe(CN)6]3- is...............
*
2 points
d2sp3
sp3d2
sp3d1
d1sp3
Secondary vanence of Co in [Co(NH3)4Cl2]+ is.............
*
2 points
6
4
2
0
CoCl3.6NH3 contains-------number of ionisable Cl- ions
*
2 points
three
two
four
one
Co-ordinate bond is...........
*
2 points
semi-polar
double bond
Vander Waals bond
weak bond
Double salt retains its identity only in the form of.......
*
2 points
Crystal lattice
aqueous solution
complex ion
coloured compound
Oxidation number of metal is designated by--------in complex name
*
2 points
arabic figures
natural numbers
roman figures
indian figures
Secondary valence of Cr in [Cr(NH3)4Cl2]+ is ...........
*
2 points
6
2
4
0
Secondary valency is satisfied by------------
*
2 points
neutral molecules
positive ions
negative ions
molecules
Concept of auxiliary valence was put forth by......
*
2 points
Alfred Werner
S.M.Jorgensen
Linus Pauling
Sidgwick
In low spin complexes magnetic moment is--------
*
2 points
not restricted
restricted
free
partly restricted, partly free
Every transition element is characterized by two types of valencies.......
*
2 points
primary and secondary
principal and primary
primary and ionizable
secondary and subsidiary
Coordinate bond is formed by---------------
*
2 points
sharing of electron pair
transfer of electron pair
donation of electron pair by only one atom
absence of electron
Complex salt contains--------------
*
2 points
group of ions
group of atoms
complex ion
molecules
IUPAC name of [Co(CN)6]3- is................
*
2 points
hexacynocobaltate (III) ion
hexacynocobalt (III)
Cobalthexacyno (III)
hexacynocobaltate (VI) ion
Coordination number of the central metal is--------
*
2 points
number of bonds formed by the ligand with metal
number of metal ions in complex
number of ions present in ionisation sphere
effective atomic number
In spin paired complexes almost all electrons are-------------
*
2 points
paired
unpaired
either paired or unpaired
free
When CN is 4, possible geometry will be-----------
*
2 points
either octahedral or trigonal
either tetrahedral or square planar
either trigonal or tetrahedral
pentagonal
The secondary of Al in [Al(OH)(H2O)5]SO4 is------
*
2 points
1
2
5
6
Valence bond theory was applied to complex by ........
*
2 points
Linus Pauling
Alfred Werner
Sidgwick
S.M.Jorgensen
Ligand is the -------species
*
2 points
acceptor
donor
acceptor as well as donor
repelling
secondary valency is directed towards-----------
*
2 points
fixed position in space
not fixed position in space
ligand
primary valency
Cu+2 Ion-Excited state configuration on approach of 4NH3 ligands, causing to .............
*
2 points
dsp3 hybridization
sp2d hybridization
sp3 hybridization
sp3d hybridization
CoCl3 4NH3 may be formulated as.............
*
2 points
[Co(NH3)4Cl2]Cl
[Co(NH3)3Cl3]NH3
[Co(NH3)4Cl3]
[(NH3)3Co(NH3)3]
As the electrons in [Co(NH3)6]3+ are paired up, it is a low spin or spin-paired octahedral complex and it is .....
*
2 points
diamagnetic complex
paramagnetic complex
antiferromagnetic complex
ferromagnetic complex
[Co(NH3)6]3+ is--------magnetic
*
2 points
para
dia
delta
ferro
Cu+2 Ion-Excited state configuration on approach of 4Cl- ligands, causing to .............
*
2 points
sp3 hybridization
sp2 d hybridization
dsp3 hybridization
sp3d hybridization
[CoF6]3- or K3[CoF6] is-----------spin complex
*
2 points
low
high
moderate
constant
Coordinate bond is formed when---------------
*
2 points
donor atom has atleast one lone pair of electron
acceptor atom has atleast one empty orbital
orbital containing lone pair of electron overlap appreciably with empty orbital of acceptor
ionic bond forms
[Ni(CN)4]2- is -------magnetic
*
2 points
dia
para
ferro
anti para
[Ni(Cl)4]2- ion is--------
*
2 points
square planar
tetrahedral
tetragonal
octahedral
Every metal possess fixed number of secondary valency which is called-----------number
*
2 points
effective atomic
coordination
transport
Avogadro's
A ligand having more than one donor atoms but links through only one atom at a time is called-------------------
*
2 points
unidentate
ambidentate
flexidentate
polydentate
Every metal have--------sphere of attraction
*
2 points
inner and coordinating
inner and outer
outer and ionisable
three
During formation of octahedral complex, when (n-1)d orbitals are involved in bonding, resultant complex will be-----------orbital complex
*
2 points
outer
inner
neither inner nor outer
upper
Valence bond theory is based on .........
*
2 points
concept of hybridisation
secondary valence
ligand orbital
crystal field splitting
Effective atomic number of Fe in K4{Fe(CN)6] is..........
*
2 points
36
26
24
28
Metal makes available-------orbitals equal to its CN for the bonding
*
2 points
vacant
half filled
completely filled
imaginary
Prefixes di, tri, tetra etc are used to indicate the number of------------
*
2 points
different
same
polydentate
coloured
Primary valency of Iron in K4[Fe(CN)6] is----------
*
2 points
+4
+2
+3
-4
Ni+2 Ion-Excited state configuration on approach of 4NH3 ligands, causing to .............
*
2 points
dsp3 hybridization
sp2d hybridization
sp3 hybridization
sp3d hybridization
Co3+ Ion-Excited state configuration on approach of F- ligands, leading to octahedral .............
*
2 points
sp3d2 hybridisation
d2sp3 hybridisation
sp3d hybridisation
dsp3 hybridisation
Ethylene diamine is------dentate ligand
*
2 points
tetra
tri
bi
mono
As F- is weak field ligand [FeF6]3- is.............complex
*
2 points
high spin
low spin
no spin
spin paired
Effective atomic number of Fe in [Fe(CN)6]-4 is .............
*
2 points
36
26
24
28
Coordination number of Co3+ in [Co(NH3)5Cl]Cl2 is------------
*
2 points
four
seven
six
five
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