LT 8.1-8.4 Practice Test
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1. Which of the following statements about gases is false?
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2. One significant difference between gases and liquids is that __________.
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3. Gaseous mixtures __________.
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4. A pressure of 1.00 atm is the same as a pressure of __________ of mm Hg.
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5. Which of the following equations shows an incorrect relationship between pressures given in terms of different units?
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6. Which statement about atmospheric pressure is false?
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7. A sample of gas (24.2 g) initially at 4.00 atm was compressed from 8.00 L to 2.00 L at constant temperature. After the compression, the gas pressure was __________ atm.
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8. A sample of a gas (5.0 mol) at 1.0 atm is expanded at constant temperature from 10 L to 15 L. The final pressure is __________ atm.
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9. A balloon originally had a volume of 4.39 L at 44 °C and a pressure of 729 torr. The balloon must be cooled to __________°C to reduce its volume to 3.78 L (at constant pressure).
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10. If 3.21 mol of a gas occupies 56.2 L at 44°C and 793 torr, 5.29 mol of this gas occupies __________ L under these conditions.
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11. A gas originally at 27°C and 1.00 atm pressure in a 3.9 L flask is cooled at constant pressure until the temperature is 11°C. The new volume of the gas is __________ L.
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12. If 50.75 g of a gas occupies 10.0 L at STP, 129.3 g of the gas will occupy __________ L at STP.
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13. A sample of He gas (2.35 mol) occupies 57.9 L at 300.0 K and 1.00 atm. The volume of this sample is __________ L at 423 K and 1.00 atm.
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14. A sample of H₂ gas (12.28 g) occupies 100.0 L at 400.0 K and 2.00 atm. A sample weighing 9.49 g occupies __________ L at 353 K and 2.00 atm.
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15. A sample of an ideal gas (3.00 L) in a closed container at 25.0°C and 76.0 torr is heated to 300 °C. The pressure of the gas at this temperature is __________ torr.
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16. A sample of a gas originally at 25°C and 1.00 atm pressure in a 2.5 L container is allowed to expand until the pressure is 0.85 atm and the temperature is 15°C. The final volume of the gas is __________ L.
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17. The reaction of 50 mL of Cl₂ gas with 50 mL of CH₄ gas via the equation shown below will produce a total of __________ mL of products if pressure and temperature are kept constant.
Cl₂(g) + CH₄(g) → HCl (g) + CH₃Cl (g)
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18. The reaction of 50 mL of N₂ gas with 150 mL of H₂ gas to form ammonia via the equation shown below will produce __________ mL of ammonia if pressure and temperature are kept constant.
N₂(g) + 3H₂(g) → 2NH₃(g)
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19. The reaction of 50 mL of Cl₂ gas with 50 mL of CH₄ gas via the equation shown below will produce a total of __________ mL of products if pressure and temperature are kept constant.
Cl₂(g) + CH₄(g) → HCl (g) + CH₃Cl (g)
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20. The first person to investigate the relationship between the pressure of a gas and its volume was __________.
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21. Of the following, __________ is a correct statement of Boyle's law.
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22. Of the following, __________ is a valid statement of Charles' law.
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23. Which one of the following is a valid statement of Avogadro's law?
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24. A fixed amount of gas at 25.0 °C occupies a volume of 10.0 L when the pressure is 667 torr. Use Boyle's law to calculate the pressure (torr) when the volume is reduced to 7.88 L at a constant temperature of 25.0°C.
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25. A fixed amount of gas at 25.0°C occupies a volume of 10.0 L when the pressure is 629 torr. Use Charles's law to calculate the volume (L) the gas will occupy when the temperature is increased to 121°C while maintaining the pressure at 629 torr.
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26. The amount of gas that occupies 60.82 L at 31°C and 367 mm Hg is __________ mol.
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27. The pressure of a sample of CH₄ gas (6.022 g) in a 30.0 L vessel at 402 K is __________ atm.
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28. At a temperature of __________ °C, 0.444 mol of CO gas occupies 11.8 L at 889 torr.
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29. The pressure exerted by 1.3 mol of gas in a 13 L flask at 22°C is __________ kPa.
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30. A 0.325 L flask filled with gas at 0.914 atm and 19°C contains __________ mol of gas.
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31. A gas in a 325 mL container has a pressure of 695 torr at 19°C. There are __________ mol of gas in the flask.
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32. A sample of gas (1.9 mol) is in a flask at 21 °C and 697 mm Hg. The flask is opened and more gas is added to the flask. The new pressure is 795 mm Hg and the temperature is now 26°C. There are now __________ mol of gas in the flask.
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33. A sample of gas (1.3 mol) occupies __________ L at 22°C and 2.5 atm.
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34. The volume of 0.65 mol of an ideal gas at 365 torr and 97°C is __________ L.
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35. The volume occupied by 1.5 mol of gas at 35°C and 2.0 atm pressure is __________ L.
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36. The mass of nitrogen dioxide contained in a 4.32 L vessel at 48°C and 141600 Pa is __________ g.
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37. The molar volume of a gas at STP is __________ L.
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38. How many moles of gas are there in a 45.0 L container at 25.0°C and 500.0 mm Hg?
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39. Standard temperature and pressure (STP), in the context of gases, refers to __________.
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40. The volume of 1.20 mol of gas at 61.3 kPa and 25.0°C is __________ L.
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41. Sodium bicarbonate is reacted (in a single replacement reaction) with concentrated hydrochloric acid at 37.0°C and 1.00 atm. The reaction of 6.00 kg of bicarbonate with excess hydrochloric acid under these conditions will produce __________ L of CO₂.
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42. The density of ammonia gas in a 4.32 L container at 837 torr and 45.0°C is __________ g/L.
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43. The density of N₂O at 1.53 atm and 45.2°C is __________ g/L.
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44. The molecular weight of a gas is __________ g/mol if 3.5 g of the gas occupies 2.1 L at STP.
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45. The molecular weight of a gas that has a density of 6.70 g/L at STP is __________ g/mol.
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46. The molecular weight of a gas that has a density of 7.10 g/L at 25.0°C and 1.00 atm pressure is __________ g/mol.
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47. The molecular weight of a gas that has a density of 5.75 g/L at STP is __________ g/mol.
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48. The density of chlorine (Cl₂) gas at 25°C and 60. kPa is __________ g/L.
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49. The volume of hydrogen gas at 38.0°C and 763 torr that can be produced by the reaction of 4.33 g of zinc with excess sulfuric acid is __________ L.
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50. The volume of HCl gas required to react with excess magnesium metal to produce 6.82 L of hydrogen gas at 2.19 atm and 35.0 °C is __________ L.
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51. The volume of fluorine gas required to react with 2.67 g of calcium bromide to form calcium fluoride and bromine at 41.0°C and 4.31 atm is __________ mL.
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52. What volume (mL) of sulfur dioxide can be produced by the complete reaction of 3.82 g of calcium sulfite with excess HCl (aq), when the final SO₂ pressure is 827 torr at 44.0°C?
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53. Automobile air bags use the decomposition of sodium azide as their source of gas for rapid inflation (shown below).  What mass (g) of NaN₃ is required to provide 40.0 L of N₂ at 25.0°C and 763 torr?
2NaN₃ (s) → 2Na (s) + 3N₂ (g).
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54. The Mond process produces pure nickel metal via the thermal decomposition of nickel tetracarbonyl (shown below).  What volume (L) of CO is formed from the complete decomposition of 444 g of Ni(CO)₄ at 752 torr and 22.0°C?
Ni(CO)₄ (l) → Ni (s) + 4CO (g).
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55. What volume (L) of NH₃ gas at STP is produced by the complete reaction of 7.5 g of H₂O according to the following reaction?
Mg₃N₂ (s) + 6H₂O (l) → 3Mg(OH)₂ (aq) + 2NH₃ (g)
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56. Ammonium nitrite undergoes thermal decomposition to produce only gases (see below).  What volume (L) of gas is produced by the decomposition of 35.0 g of NH₄NO₂ (s) at 525°C and 1.5 atm?
NH₄NO₂ (s) → N₂ (g) + 2H₂O (g)
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57. The thermal decomposition of potassium chlorate can be used to produce oxygen in the laboratory (see below).  What volume (L) of O₂ gas at 25°C and 1.00 atm pressure is produced by the decomposition of 7.5 g of KClO₃ (s)?
2KClO₃ (s) → 2KCl (s) + 3O₂ (g)
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58. The volume of a sample of gas (2.49 g) was 752 mL at 1.98 atm and 62°C. The gas is __________.
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59. The density of __________ is 0.900 g/L at STP.
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60. The density of NO₂ in a 3.50 L tank at 780.0 torr and 37.0°C is _________ g/L.
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61. The density (in g/L) of CO₂ at 1140 torr and 60.0°C is __________.
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62. Of the following gases, __________ has density of 2.104 g/L at 303 K and 1.31 atm.
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63. A 255 mL round-bottom flask is weighed and found to have a mass of 114.85 g. A few milliliters of an easily vaporized liquid are added to the flask and the flask is immersed in a boiling water bath. All of the liquid vaporizes at the boiling temperature of water, filling the flask with vapor. When all of the liquid has vaporized, the flask is removed from the bath, cooled, dried, and reweighed. The new mass of the flask and the condensed vapor is 115.23 g. Which of the following compounds could the liquid be? (Assume the ambient pressure is 1 atm.)
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64. A sample of an unknown volatile liquid was injected into a Dumas flask and heated until no visible traces of the liquid could be found. The flask and its contents were then rapidly cooled and reweighed The atmospheric pressure and temperature during the experiment were 0.976 atm and 18.0°C, respectively. The unknown volatile liquid was __________.
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65. The density of air at STP is 1.285 g/L. Which of the following cannot be used to fill a balloon that will float in air at STP?
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66. The density of nitric oxide (NO) gas at 1.21 atm and 54.1°C is __________ g/L.
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67. The density of krypton gas at 1.21 atm and 50.0°C is __________ g/L.
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68. The density of chlorine gas at 1.21 atm and 34.9°C is __________ g/L.
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69. A 1.44-g sample of an unknown pure gas occupies a volume of 0.335 L at a pressure of 1.00 atm and a temperature of 100.0°C. The unknown gas is __________.
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70. Calcium hydride (CaH₂) reacts with water to form hydrogen gas (see belwo).  How many grams of CaH₂ are needed to generate 48.0 L of H₂ gas at a pressure of 0.888 atm and a temperature of 32°C?
CaH₂ (s) + 2H₂O (l) → Ca(OH)₂ (aq) + 2H₂ (g)
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71. A vessel contained N₂, Ar, He, and Ne. The total pressure in the vessel was 987 torr. The partial pressures of nitrogen, argon, and helium were 44.0, 486, and 218 torr, respectively. The partial pressure of neon in the vessel was __________ torr.
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72. The pressure in a 12.2 L vessel that contains 2.34 g of carbon dioxide, 1.73 g of sulfur dioxide, and 3.33 g of argon, all at 42°C is __________ mm Hg.
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73. A sample of He gas (3.0 L) at 5.6 atm and 25°C was combined with 4.5 L of Ne gas at 3.6 atm and 25°C at constant temperature in a 9.0 L flask. The total pressure in the flask was __________ atm. Assume the initial pressure in the flask was 0.00 atm and the temperature upon mixing was 25°C.
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74. A sample of H₂ gas (2.0 L) at 3.5 atm was combined with 1.5 L of N₂ gas at 2.6 atm pressure at a constant temperature of 25°C into a 7.0 L flask. The total pressure in the flask is __________ atm. Assume the initial pressure in the flask was 0.00 atm and the temperature upon mixing was 25°C.
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75. In a gas mixture of He, Ne, and Ar with a total pressure of 8.40 atm, the mole fraction of Ar is __________ if the partial pressures of He and Ne are 1.50 and 2.00 atm, respectively.
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76. A gas mixture of Ne and Ar has a total pressure of 4.00 atm and contains 16.0 mol of gas. If the partial pressure of Ne is 2.75 atm, how many moles of Ar are in the mixture?
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77. A mixture of He and Ne at a total pressure of 0.95 atm is found to contain 0.32 mol of He and 0.56 mol of Ne. The partial pressure of Ne is __________ atm.
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78. A flask contains a mixture of He and Ne at a total pressure of 2.6 atm. There are 2.0 mol of He and 5.0 mol of Ne in the flask. The partial pressure of He is __________ atm.
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79. Sodium hydride reacts with excess water to produce aqueous sodium hydroxide and hydrogen gas (see below).  A sample of NaH weighing __________ g will produce 982 mL of gas at 28.0°C and 765 torr, when the hydrogen is collected over water. The vapor pressure of water at this temperature is 28 torr.
NaH (s) + H₂O (l) → NaOH (aq) + H₂ (g)
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80. SO₂ (5.00 g) and CO₂ (5.00 g) were placed in a 750.0 mL container at 50.0°C. The total pressure in the container was __________ atm.
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81. SO₂ (5.00 g) and CO₂ (5.00 g) are placed in a 750.0 mL container at 50.0°C. The partial pressure of SO₂ in the container was __________ atm.
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82. SO₂ (5.00 g) and CO₂ (5.00 g) were placed in a 750.0 mL container at 50.0°C. The partial pressure of CO₂ in the container was __________ atm.
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83. CO (5.00 g) and CO₂ (5.00 g) were placed in a 750.0 mL container at 50.0°C. The total pressure in the container was __________ atm.
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84. CO (5.00 g) and CO₂ (5.00 g) were placed in a 750.0 mL container at 50.0°C. The partial pressure of CO in the container was __________ atm.
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85. CO (5.00 g) and CO₂ (5.00 g) were placed in a 750.0 mL container at 50.0°C. The partial pressure of CO₂ in the container was __________ atm.
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86. 10.0 grams of argon and 20.0 grams of neon are placed in a 1200.0 ml container at 25.0°C. The partial pressure of neon is __________ atm.
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87. A mixture of Xe, Kr, and Ar has a total pressure of 6.70 atm. What is the mole fraction of Kr if the partial pressures of Xe and Ar are 1.60 atm and 2.80 atm, respectively.
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88. Zinc reacts with aqueous sulfuric acid to form hydrogen gas (see below).  In an experiment, 225 mL of wet H₂ is collected over water at 27 °C and a barometric pressure of 748 torr. How many grams of Zn have been consumed? The vapor pressure of water at 27°C is 26.74 torr.
Zn (s) + H₂SO₄ (aq) → ZnSO₄ (aq) + H₂ (g)
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89. Zinc reacts with aqueous sulfuric acid to form hydrogen gas (see below).  In an experiment, 201 mL of wet H⁶ is collected over water at 27°C and a barometric pressure of 733 torr. The vapor pressure of water at 27°C is 26.74 torr. The partial pressure of hydrogen in this experiment is __________ atm.
Zn (s) + H₂SO₄ (aq) → ZnSO₄ (aq) + H₂ (g)
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