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Chemistry 12th Test -2
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1, Which of the following transition metal oxides is not an insulator?
4 points
(a) MnO
(b) NiO
(c) VO
(d) Mn2O3
Clear selection
2, An example of body centered cube is
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4 points
(a) Sodium
(b) Magnesium
(c) Zinc
(d) Copper
3, The numbers of tetrahedral voids in the unit cell of a face centered cubic lattice of similar atoms is
4 points
(a) 4
(b) 6
(c) 8
(d) 10
(e) 12
Clear selection
4, Which of the following is a colligative property?
4 points
(a) osmotic pressure
(b) boiling point
(c) vapour pressure
(d) electrical conductivity
Clear selection
5, Which of the following solutions have highest freezing point?
4 points
(a) 0.1 M NaCl
(b) 0.1 M BaCl2
(c) 0.1 M Al2 (SO4)3
(d) 0.1 M urea.
Clear selection
6,Which of the following 0.1 M aqueous solutions will have the lowest freezing point?
4 points
(a) potassium sulphate
(b) sodium chloride
(c) urea
(d) glucose
Clear selection
7, The Standard electrode potentials for the half cell reactions are as followsZn ? Zn2+ + 2e– [E° = 0.41 V]Fe ? Fe2+ + 2e– [E° = 0.76 V]
4 points
(a) -0.35 V
(b) 0.35 V
(c) + 1.17 V
(d) -1.17 V
Clear selection
8, The standard reduction potentials of Cu2+/Cu and Cu2+/Cu+ are 0.337 and 0.153 respectively. The standard electrode potential of Cu+/Cu half cell is
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4 points
(a) 0.184 V
(b) 0.827 V
(c) 0.521V
(d) 0.490 V
9, The standard reduction potentials of X, Y, Z metals are 0.52, -3.03, -1.18 respectively. The order of reducing power of the corresponding metals is:
4 points
(a) Y > Z > X
(b) X > Y > Z
(c) Z > Y > X
(d) Z > X > Y
Clear selection
10, For a chemical reaction A → B, it is found that the rate of the reaction quardruples when the concentration of A is doubled. The rate expression for the reaction is, rate = k [A]n where the value of n is
4 points
(a) 1
(b) 2
(c) 0
(d) 3
Clear selection
11, On increasing the temperature of the reacting system by 10° the rate of reaction almost becomes double. The most appropriate reason for this is that
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4 points
(a) Activation energy decreases by increases of temperature
(b) The fraction of molecules having threshold energy increases
(c) Collision frequency increases
(d) The value of threshold energy decreases.
12, The half-life period of any first order reaction
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4 points
(a) is half the specific rate constant
(b) is always the same irrespective of the reaction
(c) is independent of initial concentration
(d) in directly proportional to initial concentration of reactants.
13, The nature of bonding forces in adsorption are
4 points
(a) purely physical such as Van der Waal’s forces
(b) purely chemical
(c) both chemical and physical
(d) sometimes physical and sometimes chemical.
Clear selection
14, The protective power of a lyophilic sol is
4 points
(a) defined by Hardy-Schulze rule
(b) proportional to the quantity of electrical charge on it
(c) measured in terms of gold number
(d) determined by the size of its colloidal particles.
Clear selection
15, Which one of the following is not applicable to chemisorption?
4 points
(a) Its heat of adsorption is high
(b) It takes place at high temperature
(c) It is reversible
(d) It forms mono-molerular layers.
Clear selection
16, In the equation 4 M + 8 CN– + 2H2O + O2 → 4 [M(CN)2]– + 4OH–, the metal M is
4 points
(a) Copper
(b) Iron
(c) Gold
(d) Zinc
Clear selection
17, Pyrolusite is a/an
4 points
(a) Oxide ore
(b) Sulphide ore
(c) Carbide ore
(d) not an ore.
Clear selection
18, The isoelectronic pair is
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4 points
(a) Cl2O, ICl2–
(b) ICl2– ClO2
(c) IF2+, I3–
(d) ClO2–, ClF2+
19, Which one of the following arrangements represents the correct order of electron gain enthalpy (with negative sign) of the given atomic species?
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4 points
(a) F < Cl < O < S
(b) S < O < Cl < F
(c) O < S < F < Cl
(d) Cl < F < S < 0
20, Which of the following isomers of phosphorus is thermodynamically most stable?
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4 points
(a) Red
(b) White
(c) Black
(d) Yellow
21, Which one of the following contains the maximum number of lone pair of electrons on the central atom?
*
4 points
(a) ClO3–
(b) XeF4
(c) SF4
(d) I3–
22, Among the following molecules:XeO3, XeOF4, XeF6, those containing same number of lone pairs on Xe are:
4 points
(a) (i) and (ii) only
(b) (i) and (iii) only
(c) (ii) and (iii) only
(d) (i), (ii) and (iii)
Clear selection
23, Oxidizing power of perhalates decreases in the order
4 points
(a) BrO4– > IO4– >ClO4–
(b) Cl04– > BrO4 > IO4–
(c) IO4– > BrO4– > ClO4–
(d) ClO4– > IO4– > BrO4–
Clear selection
24, There are no S-S bond in
4 points
(a) S2O42-
(b) S2O52
(c) S2O32-
(d) S2O72-
Clear selection
25, Among the tri halides of Nitrogen, which one is the least basic?
4 points
(a) NF3
(b) NCl3
(c) NBr3
(d) Nl3
Clear selection
26, Which of the following oxides is the most acidic?
4 points
(a) N2O5
(b) P2O5
(c) As2O5
(d) Sb2O5
Clear selection
27, Which transition metal can show highest oxidation state?
4 points
(a) Sc
(b) Ti
(c) Os
(d) Zn
Clear selection
28, In KMnO4 oxidation number of Mn is
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4 points
(a) +2
(b) + 4
(c) + 6
(d) + 7
29, When KMn04 acts as oxidising agent in alkaline medium, the oxidation number of Mn decreases by
*
4 points
(a) 1
(b) 2
(c) 3
(d) 5.
30, Ag+ ion is isoelectric with
4 points
(a) OP
(b) Cd2+
(c) Zn2+
(d) Pd2+
Clear selection
31, The transition element with lowest atomic number is
4 points
(a) Scandium
(b) Titanium
(c) Zinc
(d) Lanthanum.
Clear selection
32, Which of the following oxides is amphoteric in nature?
*
4 points
(a) NiO
(b) ZnO
(c) CoO
(d) FeO
33, Which of the following oxides in acidic in nature?
*
4 points
(a) CrO
(b) Cr2O3
(c) CrO3
(d) CrO2
34, The equivalent mass of K2Cr2O7, when it acts as oxidising agent in acidic medium, is equal to
4 points
(a) M
(b) M/2
(c) M/6
(d) M/5
Clear selection
35, Amongst Ni (CO)4, [Ni(CN)4]2- and NiCl42-
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4 points
(a) Ni(CO)4 and NiCl42- are diamagnetic and [Ni(CN)4]2- is paramagnetic
(b) NiCl42- arrd [Ni(CN)4]2- are diamagnetic and Ni(CO)4 is paramagnetic.
(c) Ni(CO)4 and [Ni(CN)4]2- are diamagnetic and [NiCl4]2- is paramagnetic.
(d) Ni(CO)4 is diamagnetic and [NiCl4]2- and [Ni(CN)4]2- are paramagnetic.
36, Which of the following coordination compounds can exhibit coordination iomerism?
*
4 points
(a) [Co(en)2Cl2]Br
(b) [CO(NH3)6], [Cr(CN)6]
(c) [Co(en)3]Cl3
(d) [CO(NH3)5NO2]Cl2
37, Which of the following compounds can exhibit linkage isomerism?
*
4 points
(a) [Co(en)3]Cl3
(b) [Co(en)2Cl2]Cl
(c) [Co(en)2NO2Cl]Br
(d) [Co(NH3)5Cl]Br2.
38, Which of the following ligands is a bidentate ligand?
*
4 points
(a) Py
(b) Bipy
(c) dien
(d) EDTA.
39, Which of the following ligands is a tridentate ligand?
*
4 points
(a) DMG
(b) Bipy
(c) acac
(d) dien.
40, In Ni (CO)4, the nickel atom is ……… hybridised
4 points
(a) sp²
(b) sp³
(c) dsp²
(d) sp³d.
Clear selection
41, Ziegler-Natta catalyst is TiCl3 dissolved in
4 points
(a) Triethylaluminium
(b) Ether
(c). Water
(d) Ammonia.
Clear selection
42, Which of the following are arranged in the decreasing order of dipole moment?
*
4 points
(a) CH3Cl, CH3Br, CH2F
(b) CH3Cl, CH3F, CH3Br
(c) CH3Br, CH3Cl, CH3F
(d) CH3Br, CH3F, CH3Cl
43, The reactivity order of halides for dehydrogenation is
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4 points
(a) RF > RCl > RBr > RI
(b) RI > RBr > RCl > RF
(c) RI > RCl > RBr > RF
(d) RF > RI > RBr > RCl
44, The correct order of boiling points for primary (1°), Secondary (2°) and Tertiery (3°) alcohols is
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4 points
(a) 1° > 2° > 3°
(b) 3° > 2° > 1°
(c) 2° > 1° > 3°
(d) 2° > 3° > 1°
45, The addition of HBr is easiest with
*
4 points
(a) CH2 = CHCl
(b) ClCH = CHCl
(c) CH3-CH = CH2
(d) (CH3)2C = CH2
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