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7. Reaction Kinetics
✨This Session is According to PMDC MDCAT.
✨According to Your Province Book.
✨Explanation is given for Answers.
💫For any query , You can Contact us.
~Dr.Abdul Rehman
* Indicates required question
1. Which of the following reactions are usually slow?
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1 point
Neutralization of acids and bases
Explosive reaction of 02 and H2
Organic substitution reaction
Photochemical reactions
2. By increasing the concentration of reactants the rate of reaction:
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Decrease
Increase
Remain constant
Not predicted
3. The increase in reaction rate as a result of increase in temperature from 10 k to 100 k is:
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512
614
400
112
4. The rate of reaction involving ions can be studied by:
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Spectrometric method
Dilatometric method
Optical rotation method
Electrical conductivity method
5. The specific rate constant of a chemical reaction is the rate of the reaction when the concentration of the reactants is:
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Less than unity
Greater than unity
Equal to unity
Equal to concentration of 2nd order reaction
6. The 2nd order reaction becomes 1st order when:
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one of the reactants is limiting
one of the reactants is in large excess
None of the reactants is in large excess
Both reactants in large
7. Hydrolysis of ethyl acetate into acetic acid and ethanol in the presence of mineral acid is:
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Fractional order reaction
Pseudo 1st order reaction
1st order reaction
2nd order reaction
8. For a reaction A+B___C rate is given by Rate = [A] [B] hence the order of reaction is :
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3
2
1
0
9. The half life period of zero order reaction is equal to:
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0.63/k
a/2k
1/ka
1.5/ka2
10. For which reaction half life is inversely proportional to the initial concentration of reactants:
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Zero order reaction
1 st order reaction
2 ND order reaction
3 Rd order reaction
11. Activation energy of a reaction:
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Includes the average kinetic energy of reactants
Is in addition to the average kinetic energy of reactants
Is in addition to the average kinetic energy of products
Required for the effective collisions
12. Ea appears as a potential energy hill between _____ for carrying out the reaction
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Among the reactants
Among the product s
Reactants and the products
none
13. If Ef and Er are the activation energy of forward and reverse reactions the reaction is Known to be exothermic then:
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Ef >Er
Ef >>>> Er
Ef < Er
Ef=Er
14. If the energy of the activated complex lies close to energy of reactants it means that reaction is:
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Slow
Exothermic
Endothermic
Exothermic and fast
15. In some reactions a product formed acts as a catalyst. this phenomenon is called:
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Negative catalysis
Positive catalysis
Activation of catalyst
Autocatalysis
16. What is the correct relation between rate and activation energy:
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Rate directly proportional to Ea
Rate = Ea
Rate inversely proportional to Ea
All of them
17. Concentrated sugar solution under goes hydrolysis into glucose and fructose by an enzyme ______.
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Zymase
Invertase
Maltase
none
18. Which of the following is correct about enzyme catalysts:
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These are in pure crystalline state
The activity of enzyme catalysts is inhibited by poison
Enzyme catalytic reaction have maximum rate at optimum Temperature
All of them
19. The reaction rate in forward direction decrease with the passage of
time because:
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conc. of reactants decrease
the order of reaction changes
conc . of products decrease
temperature of system changes
20. The influence of the temperature on reaction rate is predicted by:
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Free energy charge
wander Waals equation
Arrhenius equation
kinetic equation
21. For which change of temperature the rate of reaction becomes double:
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293 k
283 k
20°C
10°C
22. The unit of rate constant is same as that of rate of reaction in:
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First order reaction
zero order reaction
second order reaction
third order reaction
23. Rate of photochemical reactions donot change with the change in concentration of reactants what is the order of reaction:
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second order reaction
first order reaction
zero order reaction
third order reaction
24. If the reactants or products of a chemical reaction can absorb ultraviolet visible or infrared radiation then the rate of a chemical reaction can be measured by:
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Chemical method
Graphical method
Spectrometry
Differential method
25. The study of rates of chemical reactions and the factors that effect the rates of chemical reactions is Known as:
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Thermodynamics
Stoichiometry
Electrochemistry
Chemical Kinetics
26. For exothermic reversible reaction activation energy for forward direction depends upon:
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temperature
Nature of products
Nature of reactants
both A and B
27. If concentration time graph of a reactant indicate a constant half life then the order of reaction is :
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First
zero
second
half
28. For which of the following order of the reaction rate of reaction is inversely proportional to the concentration reaction?
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1
2
negative
zero
29. Glucose is converted to ethanol by the enzyme present in the yeast :
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urease
zymase
invertase
sucrase
30. The rate law of reaction is Rate =k [A]2 [B] on doubling the concentration of both A and B rate increases by:
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4
9
8
2
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