PRO SERIES 4 (DRY)

Safety Data Sheet - USA                                  

According to App. D , OSHA Hazard Communication Standard 29 CFR 1910.1200

Version 02

Date of issue: 10/18/2024

1a: Product Identifier - Item Codes & Names:

Cash Money Blue, White Matte, Satin Rutile

1b: Product Identifier - PRO series glazes

1c: Recommended Use - Intended for glaze production in the ceramic arts

1d: Manufacturer / Supplier - The Ceramic Shop LLC, 1200 Markley St. Norristown PA 19401 -

1-888-457-4236

1e: Emergency Phone Number - Contact Local Poison Control -

2a: Classification of substance or mixture -

Physical:                Not Classified    

Health:         H302, H319, H332, H334, Carcinogen Category 1A

Specific Target Organ Toxicity – Repeated Exposure Category 1

Environmental:         H400, H410

 2b: Symbols and Statements

Symbols -       GHS Pictogram:                              

Hazard Statement -  

H302 + H332 Harmful if swallowed or if inhaled.

H319 Causes serious eye irritation.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H373 - May cause damage to lungs through prolonged or repeated exposure by inhalation

H412 Harmful to aquatic life with long-lasting effects.

H410 Very toxic to aquatic life with long-lasting effects

Precautionary Statement -

P261 Avoid breathing dust.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood

P260 - Do not breathe dust

P285 - In case of inadequate ventilation wear respiratory protection

P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear eye protection/ face protection.

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel

unwell. Rinse mouth.

P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable

for breathing. Call a POISON CENTER/ doctor if you feel unwell.

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue

rinsing.

P337 + P313 If eye irritation persists: Get medical advice/ attention.

P391 Collect spillage.

P284 Wear respiratory protection.

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.

P308 + P313 IF exposed or concerned: Get medical advice/ attention.

P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.

P363 Wash contaminated clothing before reuse.

P501 Dispose of contents/ container to an approved waste disposal plant.

2c: Other Hazards:      NONE

3a: Ingredients - Trade secrets are claimed for the product/s. Only the ingredients listed below are notifiable.

3b: Common name

4a-c: Description of necessary measures-

Skin Contact - Wash thoroughly after handling - Read Section 2 for any specific precautions associated with the use of this product. In general most ceramic glazes, clays and special products will tend to have a drying effect on the skin and may cause some sensitivity to users with sensitive skin.

Eye Contact - Read Section 2 for any specific precautions associated with the use of this product. In general most ceramic and special products contain materials that may be abrasive to eyes. Keeping materials from contacting the eyes is prudent. If contact does occur, flush with clean water, do not rub.

Inhalation - Read Section 2 for any specific precautions associated with this product. In general, breathing any type of dust / mist can and may aggravate irritation of the throat and lungs.

Ingestion-  Read Section 2 for any specific precautions associated with the use of this product. Do Not Ingest.

Notes for the doctor: Treat symptomatically.

5a: Extinguishing Media - Use fire-extinguishing media suitable for the surrounding fire

5b: Specific Hazards Arrising from Material - None Know

5c: Special Protective Equipment - Use protective equipment appropriate for surrounding materials

6a: Personal Protections, Protective Equipment, Procedures -

Personal precautions: see Section 8.

6b: Methods and material for containment and cleaning up

Collect spillage for reclamation or absorb in vermiculite, dry sand or similar material

Reference to other sections For waste disposal, see Section 13. For personal protection, see Section 8.

7a. Precautions for safe handling

Usage precautions Read label before use. Do not eat, drink or smoke when using this product. Good personal hygiene procedures should be implemented. Wash hands and any other contaminated areas of the body with soap and water before leaving the work site.

7b. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original containers in a dry and cool place.

8a. Exposure Limits

Copper Carbonate

PEL: 1.0 [mg/m3], as Cu

ACGIH: no information available

TLV: 1.0 [mg/m3], as Cu

Cupric Oxide

PEL: TWA 0.1 mg/m3

ACGIH: no information available

TLV: no information available

Cobalt Oxide

PEL: No information available

ACGIH: No information available

TLV: 0.2 mg/m

Titanium dioxide

PEL: 15 mg/m³ (total dust)

ACGIH: 15 ug/L

TLV: 2.5 [mg/m3], respirable particulate matter (fine-scale particles) [0.2 mg/m3, respirable nanoscale particulates]

Zinc Oxide

PEL: TWA: 5 mg/m³

ACGIH: No information available

TLV: 2 mg/m³ (respirable particulate matter) [2001]

Quartz ( Crystalline Silica)

PEL: 50 µg/m3 for respirable crystalline

ACGIH: No information available

TLV: 0.025 mg/m3, as respirable particulate matter.

 Ingredient comments Only ingredients listed in Section 3 are notifiable for this product. If none are shown then all ingredients are exempt.

8b. Appropriate engineering controls

No specific ventilations requirements unless the “FAN” pictogram is shown above or specified in Section 2.

8c. Individual Protection Measures

Eye/face protection No specific eye protection required unless the "EYE PROTECTION” pictogram is shown above or specified in Section 2.

Hand protection No specific hand protection required unless the “HAND PROTECTION” pictogram is shown above or specified in Section 2.

Hygiene measures Using good personal hygiene practices is always appropriate. Keeping a clean work space, cleaning up properly when done, and not eating, drinking or smoking when using this product.

Respiratory protection No specific respiratory protection required unless the “RESPIRATOR” pictogram is shown above or specified in Section 2. Using the appropriate certified protection for the operation is important if required.

Information on basic physical and chemical properties

9a. Appearance: Colored powder.

9b. Odor: Almost odorless.

9c. Odor threshold: No information available.

9d: pH: not available

9e: Melting point: No information available.

9f: Initial boiling point and range: No information available.

9g: Flash point: No information available

.

9h. Evaporation rate: No information available.

9i: Flammability (solid, gas): No information available.

9j: Upper/lower flammability or explosive limits: No information available.

9k: Vapor pressure: No information available.

9l: Vapor Density: No information available.

9m: Relative density: Greater than 1.0

9n: Solubility(ies): Not applicable.

9o: Partition coefficient: No information available.

9p: Auto-ignition temperature: Not applicable.

9q: Decomposition Temperature: No information available.

9r: Viscosity: No information available.

10a: Reactivity: There are no known reactivity hazards associated with this product.

10b: Chemical stability: No particular stability concerns.

10c: Possibility of hazardous reactions: None known.

10d: Conditions to avoid: None known.

10e: Materials to avoid: None known.

10f: Hazardous decomposition products: None known.

11a: Information on the likely routes of exposure:

Toxicological effects Please read Section 2 thoroughly to understand the toxicological risks, (if any) and precautions for safe use (if any).

11b: Symptoms related to the physical, chemical, and toxicological characteristics

No data available

11c: Delayed and immediate effects and also chronic effects from short- and

long-term exposure

No data available

11d: Numerical measures of toxicity (such as acute toxicity estimates)

No data available

12a. Ecotoxicity: Please read Section 2 completely. If any environmental warnings such as; H411 or H412 are listed in Section 2, please use appropriate procedures when disposing of product and container. Do not put materials into waterways or sewers.

12b. Persistence and degradability: No data available.

12c. Bioaccumulative potential: No information available.

12d. Mobility in soil: Semi-mobile.

12e. Other adverse effects: None known

General information Dispose of waste product or used containers in accordance with local regulations When handling waste, the safety precautions applying to handling of the product should be considered

14a. UN Number:  Not applicable.

14b. UN proper shipping name: Not applicable.

14c. Transport hazard class(es): No transport warning sign required.

14d. Packing group: Not applicable.

14e. Environmental hazards: Environmentally Hazardous Substance Please refer to Section 2 for any environmental hazards associated with this product. If H411/H412 warnings are shown then please verify packaging and labeling requirements for larger volumes.

14f. Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code):

14g: Special precautions: not applicable.

SARA 302 Components

This material does not contain any components with a section 302 EHS TPQ.

SARA 313 Components

The following components are subject to reporting levels established by SARA Title III,

Section 313:

Copper Carbonate

CAS-No.

12069-69-1

Cobalt Oxide

CAS- No

1308-06-1

Cupric Oxide

CAS-No

13463-67-7

SARA 311/312 Hazards

Acute Health Hazard, Chronic Health Hazard ( see section 2)

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.( see section 2)

US State Regulations

California Proposition 65 Carcinogens and Reproductive Toxins

California Proposition 65: WARNING: Attention California residents: This product can expose you to - chemicals including cobalt oxide, which is known to the State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.

Right to know:

Revision date 10/29/2024

Revision 3

Supersedes date 5/01/2017

SDS No. 72

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use