kinetic energy for a given mole of a gas
but ρ= m/v
pv=
but from PV =RT
= =RT
or
kinetic energy of gram mole of the gas is given by
K.E =
thus
DENSITY OF AN IDEAL GAS
density of an ideal gas is the sum of the masS of individual molecules divided by the volume occupied by the gas.
PV=RT
n= m/M
PV=
note replace small letter p in the above equation with rho,ρ
derivation for the equations of gas law
THE PRESSURE OF AN IDEAL GAS THUS
PV=nRT
BOYLE’S LAW
boyle’s law state that at constant temperature , the volume of a gas is directly proportional to pressure.
pv=nRT, at constant temperature and for a mole of a gas RT =constant.
PV =constant , P1V1=P2V2 OR P1/P2=V2/V1
charle’s law
at constant pressure the volume of fixed mass of a gas is inversely proportional to its temperature.
PV=nRT
for a mole of a gas
AVOGAGROS LAW
when two gases combine they do so in a volume which bear a simple ratio to one another and to the volume of the product if gaseous provided temperature and pressure remain constant.
from PV=n RT
For a gas with pressue P, TEMPERATURE T, VOLUME V1 AND NUMBER OF MOLES N
for another gas at the same condition of volume of gas V2 and number of moles n2
IF V1=V2 THEN
THUS
n1=n2ρ
equal volume of all gases at same same temperature and pressure contain the same number of molecules.
Daltons law of partial of partial pressure
The total pressure of a given mixture of a gas is equal to the sum of the individual partial pressures.
from p=1/3 ρĆ2
for a gas with partial pressure p1=1/3 ρ1Ć12
with another with partial pressure p2 =1/3 ρ2Ć22
total pressure , P = p1 +p2
GRAHAM’S LAW OF DIFFUSION
the graham’s law of diffusion states that the rate of diffusion of a gas at constant temperature is inversely proportional to the square root of its density.
for a gas with density p1, mean velocity D1 and pressure P
and another gas of density p2,mean vel. D2