Material Safety Data Sheet
1. Chemical Product & Company Identification
Texican Crude & Hydrocarbons, LLC
500 Dallas Street
Suite 1150
Houston, TX 77079
Information: (713)650-6579
CHEMTREC: (800)424-9300
Product Name: Crude Condensate Date Prepared: 12-18-2012
Synonyms: Natural Gas Condensates, Petroleum Crude Oil Condensate Drips
Product Description: A complex combination of hydrocarbons containing carbon numbers in the range of C2-C20.
2. Composition & Information on Ingredients
Component | CAS # | Concentration ***** | Occupational Exposure Limits | Units | ||
OSHA* PEL | ACGIH* TLV | NIOSH** | ||||
Natural Gas Condensate | 64741-47-5 | <100 | NA | NA | NA | |
Hydrogen Sulfide | 7783-06-4 | 0.1-5 | 10 | 10 | 10 | PPM |
Benzene**** | 71-43-2 | <5 | 1 | 0.5 | 0.1 | PPM |
Toluene | 108-88-3 | 1-7 | 100 | 100 | 100 | PPM |
Ethyl Benzene | 100-41-4 | 1-3 | 100 | 20*** | 100 | PPM |
Xylenes | 1330-20-7 | 1-8 | 100 | 100*** | 100 | PPM |
Cyclohexane | 110-82-7 | 1-5 | 300 | 100 | 300 | PPM |
n-hexane | 110-54-3 | 2-4 | 500 | 50*** | 50 | PPM |
Note: All concentrations are % by weight unless ingredient is a gas. Gas concentrations are in % by volume.
Key: | * | = | 8-Hr. TWA unless otherwise specified. |
** | = | 10-Hr. TWA unless otherwise specified. | |
*** | = | ACGIH has established a Biological Exposure Index (BEI) for this | |
substance due to its carcinogenicity. | |||
N/A | = | Not Available | |
**** | = | Benzene specific regulations are promulgated in 29 CFR | |
1910.1028 | |||
***** | = | Crude oil, natural gas and natural gas condensate may contain | |
minor amounts of sulfur, nitrogen, and oxygen containing organic | |||
compounds. There is also the possibility of trace amounts of | |||
heavy metals such as mercury, arsenic, nickel, and vanadium. | |||
The composition may vary depending on the source of the crude. |
3. Hazard Identification
Carcinogenicity | NTP | IARC Monographs | OSHA Regulated |
Natural Gas Condensate | - | - | - |
Benzene* | Yes | Yes | Yes |
Toluene | No | Yes (3)*** | No |
Ethyl Benzene | No | Yes (2B)** | No |
* Benzene has been designated as a carcinogen by the National Toxicology Program (NTP), the International Agency for Research on Cancer (IARC), and the Occupational Safety and Health Administration (OSHA). Benzene may produce blood changes which include reduced platelets, reduced red blood cells, reduced white blood cells, a plastic anemia, and acute nonlymphocytic leukemia. Benzene has produced fetal death in laboratory animals and caused chromosome changes in humans and mutation changes in cells of other organisms. Ethylbenzene is classified as a possible carcinogen IARC 2B and an OSHA confirmed animal carcinogen with unknown relevance to humans.
** Possibly carcinogenic to humans.
*** Not classifiable as its carcinogenicity to humans.
Potential Health Effects From Overexposure
Acute Effects:
Eyes: Slight to moderate eye irritation, along with severe reddening and inflammation of the conjunctiva. May cause pain, blurred vision, redness, and superficial corneal turbidity.
Skin: Moderately irritating, causing redness, drying of skin, itching, cracking, and inflammation.
Inhalation: Toxic by inhalation. Irritating to mucous membranes and respiratory tract. Can act as simple asphyxiant. Overexposure may lead to headache, nausea, drowsiness, excitation, dizziness, incoordination, light-headedness, blurred vision, pulmonary edema, labored breathing, loss of appetite, central nervous system depression, leading to coma and respiratory arrest. Also, may contain hydrogen sulfide gas which may be harmful or fatal if inhaled.
Ingestion: May be mildly irritating to intestines. Aspiration hazard if vomiting occurs, which may cause inflammation and possible fluid accumulation in the lungs resulting in possible chemical pneumonia, severe lung damage and/or respiratory failure (death).
Chronic Effects: Components: Toluene
Carcinogenicity: Exposure of rats and mice to toluene at concentrations ranging from 120-1200 ppm for two years did not demonstrate evidence of carcinogenicity. Toluene has not been listed as a Category 3 agent by IARC.
Target Organs: Epidemiology studies suggest that chronic occupational overexposure to toluene may damage color vision. Subchronic and chronic inhalation studies with toluene produced kidney and liver damage, hearing loss and central nervous system (brain) damage in laboratory animals. Intentional misuse by deliberate inhalation of high concentrations of toluene has been shown to cause liver, kidney, and central nervous system damage, including hearing loss and visual disturbances.
Benzene:
Carcinogenicity: Benzene is an animal carcinogen and is known to produce acute myelogenous leukemia (a form of cancer) in humans. Benzene has been identified as a Group 1, known human carcinogen by IARC, the US National Toxicology Program and the US-Occupational Safety and Health Administration. Target Organs: Prolonged or repeated exposures to benzene vapors can cause damage to the blood and blood forming organs, including disorders like leukopenia, thrombocytopenia, and aplastic anemia.
Reproductive Toxicity: Some studies in occupationally exposed women have suggested benzene increased risk of miscarriage and stillbirth along with decreased birth weight and gestational age. The quantity of the effects detected in these studies was small, and ascertainment of exposure and outcome in some cases relied on self-reports, which may limit the reliability of these results.
Germ Cell Mutagenicity: Benzene exposure has resulted in chromosomal aberrations in human lymphocytes and animal bone marrow cells, and DNA damage in mammalian cells in vitro.
4. FIRST AID MEASURES
Eye Contact: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention.
Skin Contact: Remove contaminated shoes and clothing, and flush affected area(s) with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. If skin surface is not damaged, cleanse affected area(s) thoroughly by washing
with mild soap and water or a waterless hand cleaner. If irritation or redness develops, seek medical attention. Wash contaminated clothing before reuse.
Inhalation
(Breathing): Immediately move victim away from exposure and into fresh air in a position comfortable for breathing. If respiratory symptoms or other symptoms of exposure develop, seek immediate medical attention. If victim is not breathing, clear airway and immediately begin artificial respiration. If breathing difficulties develop, oxygen should be administered by qualified personnel. Seek immediate medical attention.
Ingestion
(Swallowing): Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. If victim is drowsy or unconscious and vomiting, place on the left side with the head down. If possible, do not leave victim unattended and observe closely for adequacy of breathing. Seek immediate medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: -51oF/-46oC)
Flammable Limits in Air, % by Volume: Lower: 1.1
Upper: 6.0
Auto-ignition Temperature: 590oF/310oC
NFPA 704 Hazard Class
Health: 2 Flammability: 4 Reactivity: 0
(0-Minimal, 1-Slight, 2-Moderate, 3-Serious, 4-Severe)
Unusual Fire & Explosion Hazards:
Extremely flammable. This material can be ignited by heat, sparks, flames, or other sources of ignition (e.g., static electricity, pilot lights, mechanical/electrical equipment, and electronic devices such as cell phones, computers, calculators, and pagers which have not been certified as intrinsically safe). Vapors may travel
considerable distances to a source of ignition where they can ignite, flash back, or
explode. May create vapor/air explosion hazard indoors, in confined spaces, outdoors, or in sewers. This product will float and can be reignited on surface water. Vapors are heavier than air and can accumulate in low areas. If container is not sufficiently cooled, it can rupture in the heat of a fire. Hazardous combustion/decomposition products, including hydrogen sulfide, may be released by this material when exposed to heat or fire. Use caution and wear approved protective clothing, and respiratory protection.
Extinguishing Media:
Dry chemical, carbon dioxide, or foam is recommended. Water spray is recommended to cool or protect exposed materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water on the same surface is to be avoided as water reduces the effectiveness of the foam. Water may be ineffective for extinguishment, unless used under favorable conditions by experienced fire fighters.
Fire Fighting Instructions:
For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. When the potential chemical hazard is unknown, in enclosed or confined spaces, an approved self-contained breathing apparatus should be worn. In addition, wear other appropriate approved protective equipment as conditions warrant.
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it can be done safely. Avoid spreading burning liquid with water used for cooling purposes.
Hazardous Combustion Products:
Combustion may yield smoke, carbon monoxide, and other products of incomplete combustion. Hydrogen sulfide and oxides of nitrogen and sulfur may also be formed.
6. ACCIDENTAL RELEASE Personal Precautions:
Extremely flammable. Release of liquid product may create a fire hazard and may
form an explosive atmosphere. Keep all sources of ignition and hot metal surfaces away from spill/release if safe to do so. The use of explosion-proof electrical equipment is recommended. Contains hydrogen sulfide gas. If the presence of potentially dangerous amounts of Hydrogen Sulfide around the spilled product is suspected, additional or special actions may be warranted, including access restrictions and use of protective equipment. Evacuate upwind and away from spill/release. Avoid direct contact with material. For large spillages, notify persons downwind, isolate immediate hazard area and keep unauthorized personnel out. Wear appropriate approved protective equipment including approved respiratory protection, as conditions warrant. Avoid low lying areas.
Environmental Precautions:
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and natural waterways. Use foam on spills to minimize vapors. Use water sparingly to minimize environmental contamination and reduce disposal requirements. If spill occurs on water notify appropriate authorities and advise shipping of any hazard. Spills into or upon navigable waters, the contiguous zone, or adjoining shorelines that cause a sheen or discoloration on the surface of the water, may require notification of the National Response Center (phone number 800-424-8802).
Methods for Containment and Clean-Up:
Notify relevant authorities in accordance with all applicable regulations. Immediate cleanup of any spill is recommended. Dike far ahead of spill for later recovery or disposal. Absorb spill with inert material such as sand or vermiculite, and place in suitable container for disposal. If spilled on water remove with appropriate
methods (e.g. skimming, booms or absorbents). In case of soil contamination, remove contaminated soil for remediation or disposal, in accordance with local regulations.
Recommended measures are based on the most likely spillage scenarios for this material; however, local conditions and regulations may influence or limit the choice of appropriate actions to be taken. All contaminated media used for the purpose of cleanup should be disposed of properly in accordance with all Federal, State, and Local regulations.
7. HANDLING & STORAGE
Store in tightly closed containers in a dry, cool place, away from sources of heat or ignition. Ground and bond all transfer and storage equipment to prevent static sparks and equip with self-closing valves, pressure vacuum bungs and flame arrestors. Empty containers may contain residue (liquid/vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, or other sources of ignition; they may explode and cause injury or death. Use spark-proof tools and explosion-proof equipment. Label as appropriate per Federal, State and Local regulations.
8. EXPOSURE CONTROL, PERSONAL PROTECTION
Ventilation: Provide adequate general and local ventilation using explosion-proof means: (1) to maintain airborne chemical concentrations below applicable exposure limits, (2) to prevent accumulation of flammable vapors and formation of explosive atmospheres, and (3) to prevent formation of oxygen deficient atmospheres, especially in confined spaces. [Note: this product may release gases or vapors that can displace oxygen in enclosed areas.]
Eye/Face Protection: The use of eye protection that meets or exceeds ANSI Z.87.1 is recommended to protect against potential eye contact, irritation, or injury. Eye protection should be non- or indirectly vented goggles. Depending on conditions of use, a face shield may be necessary. Remove contact lenses.
Skin/Hand Protection: The use of gloves impervious to the specific material handled is advised to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Depending on exposure and use conditions, additional protection may be necessary to prevent skin contact including use of items such as chemical resistant boots, aprons, arm covers, hoods,
coveralls, or encapsulated suits. Suggested protective materials: Nitrile or neoprene.
Respiratory Protection: A NIOSH approved, self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode should be used in situations of oxygen deficiency (oxygen content less than 19.5 percent), unknown exposure concentrations, or situations that are immediately dangerous to life or health (IDLH).
A respiratory protection program that meets or is equivalent to OSHA 29 CFR 1910.134 should be followed whenever workplace conditions warrant a respirator’s use.
Other Protective Equipment: Eye wash and quick-drench shower facilities should be available in the work area. Thoroughly clean shoes and wash contaminated clothing before reuse.
Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, or engineering professionals.
9. PHYSICAL & CHEMICAL PROPERTIES
Boiling Point/Range: -20 to 800oF/-29 to 427oC
Vapor Pressure: 5-15 psia (Reid VP) @ 100oF/37.8oC
% Solubility in H2O: Negligible
Specific Gravity (water = 1): 0.6-0.8 @ 60oF (15.6oC) Appearance: Amber to Dark Brown.
Physical State: Liquid
Melting Point: Not Applicable
Vapor Density (Air=1): 1
Evaporation Rate: 1 (Butyl Acetate = 1)
Odor: Petroleum like or rotten egg odor if hydrogen sulfide is present.
pH: Not Applicable
VOC Content (%): 50
Flash Point: -51oF/-46oC
Lower Explosive Limits (% in air): 1.1
Upper Explosive Limits (% in air): 6.0
Auto-ignition Temperature: 590oF/310oC
Note: Unless otherwise stated, values are determined at 20oC (68oF) and 760 mm Hg (1 atm). Data represents typical values and are not intended to be specifications.
10. STABILITY & REACTIVITY
Stability: Stable under normal ambient and anticipated conditions of use.
Conditions to Avoid: Avoid high temperatures and all sources of ignition. Prevent vapor accumulation.
Materials to Avoid (Incompatible Materials): Avoid contact with strong oxidizing agents and strong reducing agents.
Hazardous Decomposition Products: Not anticipated under normal conditions of use.
Hazardous Polymerization: Not known to occur.
11. TOXICOLOGICAL INFORMATION
Toxicological data does not exist for this mixture.
BENZENE: This product contains benzene, which can cause degeneration in blood forming bone marrow leading to anemia which may further degrade to leukemia, a type of cancer. Acute benzene poisoning causes central nervous system depression. Chronic exposure affects the hematopoietic system causing blood disorders including anemia and pancytopenia. Mutagenic and clastogenic in mammalian and non-mammalian test systems. Reproductive or developmental toxicant only at doses that are maternally toxic, based on tests with animals.
HYDROGEN SULFIDE: This product contains hydrogen sulfide, which may be fatal if inhaled. Inhalation of a single breath at a concentration of 1000 ppm (0.1%) may cause coma. Hydrogen sulfide is corrosive when moist. Skin contact may cause burns. There is a rapid loss of sense of smell on exposure to gas concentrations above 150 ppm, and this means that the extent of exposure may be underestimated. Perception threshold ranges from 0.5 ppt to 0.1 ppm. It is an irritant and asphyxiant.
12. ECOLOGICAL INFORMATION
Toxicity: Acute aquatic toxicity studies on samples of gasoline and naphtha streams show acute toxicity values greater than 1 mg/L and mostly in the range 1-
100 mg/L. These tests were carried out on water accommodated fractions, in closed systems to prevent evaporative loss. Results are consistent with the predicted aquatic toxicity of these substances based on their hydrocarbon composition. These substances should be regarded as toxic to aquatic organisms, with the potential to cause long term adverse effects in the aquatic environment. Classification: H411: Chronic Cat 2.
Persistence and Degradability: The hydrocarbons in this material are not readily biodegradable, but are regarded as inherently biodegradable since their hydrocarbon components can be degraded by microorganisms.
Bioaccumulative Potential: Log Kow values measured for the hydrocarbon components of this material range from 3 to greater than 6 and, therefore are regarded as having the potential to bioaccumulate. In practice, metabolic processes or physical properties may prevent this effect or limit bioavailability.
Mobility in Soil: Upon release to water, hydrocarbons will float on the surface and since they are sparingly soluble, the only significant loss is volatilization to air. In air, these hydrocarbons are photodegraded by reaction with hydroxyl radicals with half-lives varying from 6.5 days for benzene to 0.5 days for n-dodecane.
Other Adverse Effects: None anticipated.
13. DISPOSAL INFORMATION
Dispose of through a licensed waste disposal company. When discarded or disposed of, it “may” meet the criteria of a “characteristic” hazardous waste. This product could also contain benzene and could exhibit characteristics of toxicity as determined by the Toxicity Characteristic Leaching Procedure (TCLP). This material may become hazardous waste if mixed or contaminated with a hazardous waste or other substance(s). It is the responsibility of the user to determine if disposal material is hazardous according to federal, state, or local regulations and to follow those that are applicable.
Container contents should be completely used and containers should be emptied prior to discard. Container residues and rinseates could be considered to be hazardous wastes.
EPA Waste Number(s)
• D001 – Ignitability characteristic
• D018 – Toxicity characteristic (Benzene)
14. TRANSPORT INFORMATION
U.S. Department of Transportation (DOT)
Shipping Description: If vapor pressure is >300 kPa (43.5 psia) at
50oC (122oF) and H2S is >8.8 molar %
shipping description is:
UN3160, Liquefied gas, toxic, flammable, n.o.s., (Hydrogen sulfide, Liquefied petroleum gas), 2.3, (2.1), Inhalation Hazard Zone X
If vapor pressure is >300 kPa (43.5 psia) at
50oC (122oF) and H2S is <8.8 molar %
shipping description is:
UN1965, Hydrocarbon gas mixture, liquefied, n.o.s., 2.1
If vapor pressure is < = 300 kPa (43.5 psia) at 50oC (122oF) and H2S is <8.8 molar % shipping description is:
UN1267, Petroleum crude oil, 3, I or II [I if BP
<35oC (95oF); II if BP >35oC]
If vapor pressure is < = 300 kPa (43.5 psia) at 50oC (122oF) shipping description is: UN3295, Hydrocarbons, liquid n.o.s., 3, I, II or III [I if BP <35oC (95oF); II if BP >35oC, III if BP
>35oC]
Non-Bulk Package Marking: Must be consistent with shipping description, either:
Liquefied gas, toxic, flammable, n.o.s (Hydrogen sulfide, Liquefied petroleum gas), UN3160
or
Hydrocarbon gas mixture, liquefied, n.o.s., UN1965
or
Petroleum crude oil, UN1267
or
Hydrocarbons, liquid n.o.s., UN3295
Non-Bulk Package Labeling: For UN3160: Poison gas and Flammable gas
For UN1965: Flammable gas For UN1267: Flammable liquid For UN3295: Flammable liquid
Bulk Package/Placard Marking: For UN3160: Poison gas/3160 and
Flammable gas
For UN1965: Flammable gas/1965
For UN1267: Flammable/1267
For UN3295: Flammable liquid/3295
Packaging – References: For UN1360: None; 49 CFR 173.304; 173.314
& .315
For UN1965: 49 CFR: 173.306; 173.304;
173.314 & .315
For UN1267: 49 CFR 173.150; 173.201;
173.243 [PG I]
-or –
49 CFR 173.150; 173.202; 173.242 [PG II] (Exceptions; Non-bulk; Bulk)
For UN3295: 49 CFR: 173.150; 173.201,
.202 and .203; 173.242 [PG I] and 173.243
[PG II]
Hazardous Substance: The EPA’s Petroleum Exclusion applies to Section 2 and/or 15 components which are listed in 49 CFR 172.101, Table 1 to Appendix A.
Emergency Response Guide: UN3160 – 119; UN1965 – 115; UN1267 – 128;
UN3295 – 128
Note: Replace X in shipping description with:
D if Molar % H2S is from 8.8% to 14.8%
C if Molar % H2S is from 14.9% to 44.4% B if Molar % H2S if from 44.5% to 100.0% Container(s) greater than 5 liters (liquids) or
5 kilograms (solids), shipped by water mode and ALL bulk shipments may require the shipping description to contain the “Marine Pollutant” notation [49 CFR
172.203(I)] and the container(s) to display the [Marine Pollutant Mark] [49 CFR
172.322].
The following alternate shipping description order may be used until January 1, 2013:
Proper Shipping name, Hazard Class or Division, (Subsidiary Hazard if any), UN or NA number, Packing Group
be required for DOT compliance.
International Maritime Dangerous Goods (IMDG)
Shipping Description: If vapor pressure is >300 kPa (43.5 psia) at
50oC (122oF) and H2S is >8.8 molar %
shipping description is:
UN3160, Liquefied gas, toxic, flammable, n.o.s., (Hydrogen sulfide, Liquefied petroleum gas), 2.3, (2.1)
If vapor pressure is >300 kPa (43.5 psia) at
50oC (122oF) and H2S is <8.8 molar %
shipping description is:
UN1965, Hydrocarbon gas mixture, liquefied, n.o.s., (Hydrogen sulfide, Liquefied petroleum gas), 2.1
If vapor pressure is < = 300 kPa (43.5 psia) at 50oC (122oF) and H2S is <8.8 molar % shipping description is:
UN1267, Petroleum crude oil, 3, I or II [I if IBP
<35oC (95oF); II if IBP >35oC] (-46oC)
If vapor pressure is < = 300 kPa (43.5 psia) at 50oC (122oF) shipping description is: UN3295, Hydrocarbons, liquid n.o.s., 3, I, II or III [I if BP <35oC (95oF); II if BP >35oC; III if BP
>35oC] (-46oC)
Non-Bulk Package Marking: Must be consistent with shipping description, either:
Liquefied gas, toxic, flammable, n.o.s., (Hydrogen sulfide, Liquefied petroleum gas), UN3160
or
Hydrocarbon gas mixture, liquefied, n.o.s., (Hydrogen sulfide, Liquefied petroleum gas), UN1965
or
Petroleum crude oil, UN1267
or
Hydrocarbons, liquid n.o.s., UN3295
For UN1965: Flammable gas For UN1267: Flammable liquid For UN3295: Flammable liquid
Placards/Marking (Bulk): For UN3160: Toxic gas/3160 and Flammable gas
For UN1965: Flammable gas/1965
For UN1267: Flammable/1267
For UN3295: Flammable/3295
Packaging – Non-Bulk: For UN1360 & UN1965: P200
For UN1267: P001
For UN3295: P001
EMS: For UN3160 & UN1965: F-D, S-U
For UN1267: F-E, S-E
For UN3295: F-E, S-D
Note: If container(s) is greater than 5 liters (liquids) or 5 kilograms (solids), shipment may require the shipping description to contain the “Marine Pollutant” description [IMDG 5.4.1.4.3.5] and the container(s) to display the Marine Pollutant mark [IMDG
5.2.1.6]. U.S. DOT compliance requirements may apply. See 49 CFR 171.22, 23 & 25. If transported in bulk by marine vessel in international waters, product is being carried under the scope of MARPOL Annex
I.
International Civil Aviation Org./International Air Transport Assoc. (ICAO/IATA)
UN/ID #: UN3160 – Forbidden UN1965 or UN1267 or UN3295
Proper Shipping Name: For UN1965: Hydrocarbon gas mixture, liquefied, n.o.s. (Liquefied petroleum gas, Hydrogen sulfide)
For UN1267: Petroleum crude oil
For UN3295: Hydrocarbons, liquid n.o.s.
Hazard Class/Division: For UN1965: 2.1
For UN1267: 3
For UN3295: 3
Subsidiary Risk: None
Packing Group: For UN1965: None
For UN1267: I or II [Determined by IATA
3.3.2]
For UN3295: I or II [Determined by IATA
3.3.2]
Non-Bulk Package Marking: For UN1965: Hydrocarbon gas mixture, liquefied, n.o.s. (Liquefied petroleum gas, Hydrogen sulfide), UN1965
For UN1267: Petroleum crude oil, UN1267
For UN3295: Hydrocarbon, liquid n.o.s., UN3295
Labels: For UN1965: Flammable gas, Cargo Aircraft
Only
For UN1267: Flammable liquid
For UN3295: Flammable liquid
ERG Code: For UN1965: 10L or For UN1267: 3L
or
For UN3295: 1L or 5L
LTD. QTY Passenger Aircraft Cargo Aircraft Only
Packaging Instruction #: | UN1965 – Forbidden UN1267 – Forbidden – [PG I] Y341 – [PG II] UN3295 – Y305 – [PG II] 305 – [PG II] | UN1965 – Forbidden UN1267 – 351 – [PG I] 353 – [PG II] UN3295 – 305 – [PG II] | UN1965 – 200 UN1267 – 361 – [PG I] 364 – [PG II] UN3295 – 307 – [PG II] |
Max. Net Qty. Per Package: | UN1267 – None (PG I); 1L (PG II) UN3295 – None (PG II) | UN1267 – 1L – [PG I] 5L – [PG II] UN3295 – 5L – [PG II] | UN1965 – 150 kg UN1267 – 30 L – [PG I] 60 L – [PG II] UN3295 – 60L – [PG II] |
15. REGULATORY INFORMATION
CERCLA/SARA – Section 302 Extremely Hazardous Substances and TPQs (in pounds):
This material contains the following chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372:
Component | TPQ | EPCRA RQ |
Hydrogen Sulfide | 500 lb | 100 lb |
CERCLA/SARA – Section 311/312 (Title III Hazard Categories)
Acute Health: Yes Chronic Health: Yes Fire Hazard: Yes Pressure Hazard: No Reactive Hazard: No
CERCLA/SARA – Section 313 and 40 CFR 372:
This material contains the following chemicals subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR 372:
Component | Concentration | de minimis |
Xylenes | 1-8 | 1.0% |
Toluene | 1-7 | 1.0% |
Cyclohexane | 1-5 | 1.0% |
Benzene | <5 | 0.1% |
n-Hexane | 2-4 | 1.0% |
Ethyl Benzene | 1-3 | 0.1% |
EPA (CERCLA) Reportable Quantity (in pounds):
EPA’s Petroleum Exclusion applies to this material – (CERCLA 101(14)).
California Proposition 65:
Warning: This material may contain detectable quantities of the following chemicals, known to the State of California to cause cancer, birth defects or other reproductive harm, and which may be subject to the requirements of California Proposition 65 (CA Health and Safety Code Section 25249.5):
Component | Type of Toxicity |
Toluene | Developmental Toxicant Female Reproductive Toxicant |
Benzene | Cancer Developmental Toxicant Male Reproductive Toxicant |
Ethyl Benzene | Cancer |
International Hazard Classification:
GHS Classification:
H224 -- Flammable liquids -- Category 1
H304 -- Aspiration Hazard -- Category 1
H315 -- Skin corrosion/irritation -- Category 2
H332 -- Acute toxicity, Inhalation -- Category 4
H336 -- Specific target organ toxicity (single exposure) -- Category 3
H350 -- Carcinogenicity -- Category 1B
H411 -- Hazardous to the aquatic environment, chronic toxicity -- Category 2
National Chemical Inventories:
TSCA STATUS: All components are listed on the Inventory of Chemical
Substances and comply with TSCA.
16. OTHER INFORMATION
THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF THIS COMPANY'S KNOWLEDGE AND BELIEVED ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE IS MADE AS TO THE ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY THEMSELVES AS TO THE SUITABILITY AND COMPLETENESS OF SUCH INFORMATION FOR THEIR OWN PARTICULAR USE.