MATERIAL SAFETY DATA SHEET

1.        CHEMICAL PRODUCT & COMPANY IDENTIFICATION

Texican Crude & Hydrocarbons, LLC

One Allen Center        Information: (713) 650-6579

500 Dallas Street, Suite 1150        CHEMTREC:        (800) 424-9300

Houston, Texas 77002

Product Name: Liquefied Petroleum Gas (Y Grade)

Last Revision: 12/19/12

MSDS Number:        A0124.msd        Date Prepared: 12/19/12

Synonyms:        LPG, Y-Grade

Product Description: A complex mixture of hydrocarbons having

carbon numbers predominantly in the range

Of C3 through C7

2.        COMPOSITION & INFORMATION ON INGREDIENTS Occupational Exposure Limits*

OSHA        ACGIH

Product        CAS No.        Wt%        PEL        TLV        NIOSH++ Units

**Liquefied Petroleum

Gas        68476-86-8        100        1000        1000        1000        ppm

Components

Ethane

74-84-0

3-20%

None

None

None

Propane

74-98-6

35-55%

1000

1000

1000

ppm

Isobutane

72-28-5

7-25%

None

1000

800

ppm

n-Butane

106-97-8

8-25%

None

1000

800

ppm

IsoPentane

78-18-4

5-15%

None

600

None

ppm

n-Pentane

109-66-0

5-15%

1000

600

120(ceil

ng 610) ppm

Hexanes plus

110-54-3

10-50%

500

50

50

ppm

i

Key: N/A = Not Available.

*        = 8-Hr. TWA unless otherwise specified.

**        = Simple asphyxiant.

++        = 10-Hr. TWA unless otherwise specified.

3.        HAZARD IDENTIFICATION

Note:        This product has not been tested by Texican Crude &  Hydrocarbons, LLC to determine its specific health hazards. Therefore,        the information provided in this section includes        health hazard information on the product components.

Carcinogenicity:

NTP

IARC Monographs

OSHA

Regulated

Propane

No

No

No

Potential Health Effects From Overexposure

Acute Effects:

Eyes:                Eye  irritation, direct contact may cause burns or frostbite.

Skin:                Irritation, direct contact may cause burns or frostbite.

Inhalation:        Weakness,  headache, confusion, blurred vision, drowsiness,        suffocation,  nausea  and/or  other nervous system effects.  Continued exposure may result                in  dizziness,  slurred  speech,  flushed face,        unconsciousness,  or  convulsions.    High concentrations        may  affect  heart  and  cause respiratory depression.

Ingestion:     Not Applicable.

Chronic Effects:

None determined.

Additional Medical and Toxicological Information:

Liquefied Petroleum Gas will displace oxygen and is considered a simple asphyxiant.  (Note of Physicians) Due to increased risk of eliciting cardiac dysrhythmias, catecholamine drugs, such as epinephrine, should be used with special caution in situations of emergency life support.  Arrhythmias have been reported in animals exposed to high concentrations and given epinephrine. Medical providers are urged to contact a Regional Poison Control Center (1-800-222-1222).

4.  FIRST AID MEASURES

Eye Contact:   If liquid propane contacts the eye, immediately flush with large amounts of water for at least 15 minutes, including under the eyelids.  Speed and thoroughness        in  rising eyes are  important to avoid permanent injury.  Seek immediate medical attention.

Skin Contact:  If freezing of the skin has occurred, flush the affected area with large amounts of soapy tepid water for 15 to 20 minutes.  If freeze burns have

occurred,  loosely  apply  bulky,  dry,  sterile bandage to protect affected area.  Do not rub affected area.  Get immediate medical attention.

Inhalation:        Remove to fresh air.  If breathing has stopped, apply        artificial  respiration.    Get  immediate medical attention.

Ingestion:     None considered necessary.

5.  FIRE FIGHTING MEASURES

Flash Point: N/A (-58 to -306oF) Flammable Limits in Air, % by Volume:

Lower: 1.8

Upper: 9.5

Autoignition Temperature: >260oC

Extinguishing Media: Dry chemical, foam, or carbon dioxide. NFPA Hazard Ratings (liquefied petroleum gas):

Health: 1           Flammability: 4         reactivity: 0

General Hazard:

Gas may flow on the surface for a considerable distance, reach an ignition source, and flash back.  It can be a dangerous fire and explosion hazard when mixed with air.  Continue cooling containers with water after fire has been extinguished.  This product is heavier than air and will tend to accumulate in low- lying areas.

Fire Fighting Instructions:

Water may be ineffective on flames but should be used to keep fire-exposed containers cool.   Do not completely extinguish flames unless gas flow is shut off or an explosive gas-air mixture may form and ignite without warning.   Firefighters should  wear  self-contained  breathing  apparatus  and  full protective clothing.

6.  ACCIDENTAL RELEASE

Remove sources of heat or ignition including internal combustion engines and power tools.  Stop gas flow.  Ventilate the area. Keep people away.  Stay upwind of release and allow release to evaporate to atmosphere and warn people downwind of possible explosion.  This product is heavier than air and will tend to accumulate in low-lying areas. Avoid breathing the gas, where self-contained breathing apparatus if conditions warrant. Equipment used for cleanup must be explosion proof/intrinsically safe and suitable for flammable liquid and vapor.

7.  HANDLING & STORAGE

Store and use in a cool, dry, well ventilated area, away from direct sunlight and incompatible materials or sources of heat and  ignition.    No  smoking  in  areas  of  storage  or  use. Electrically bond and ground storage and transfer lines and equipment.   Transfer high-pressure liquid and gas in approved systems.   Keep away from oxidizing agents and cylinders of oxygen on chlorine.  Empty tanks may contain residue (gas).  Do not cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks or other sources of ignition; they may explode and cause injury or death.

8.  EXPOSURE CONTROL, PERSONAL PROTECTION

Eye Protection:     Remove  contact  lenses  and  wear  chemical safety         glasses,  safety  goggles  or  face shield                (with  safety  goggles  or  safety glasses)                        that  meet or exceed ANSI Z87.1 where contact with compressed gas/liquid may occur.

Skin Protection:    Wear   insulating  gloves  and  protective clothing        when contact with compressed gas may occur.

Inhalation:                        Use  approved  respiratory   protective equipment for cleaning large spills or upon entry into large tanks, vessels, and other designated        confined   spaces   or  in  any situation where airborne concentrations may exceed        occupational  exposure limits.    In situations where the airborne concentration of                oxygen  may  be  below  20.9%  approved supplied-air  respiratory protection should be worn.  Warning! Air-purifying respirators do        not protect workers in oxygen-deficient atmospheres.

Ventilation:

Provide

adequate

general        and        local

ventilation:

(1)        to

maintain        airborne

chemical concentrations below applicable exposure limits, (2) to prevent accumulation of  flammable  vapors  and  formation  of explosive atmospheres, and (3) to prevent formation of oxygen deficient atmospheres, especially in confined spaces.  [Note: this

product        can        displace        oxygen        in        enclosed areas.]

9.        PHYSICAL & CHEMICAL PROPERTIES

Boiling Point 760 mmHg: -40 to 126oF Vapor Pressure mmHg @ 20 C: N/A Solubility in H20: N/A

% Volatile by Volume: 100

Viscosity (method, temp): N/A Appearance: Colorless Gas

Specific Gravity:        0.37-0.7 (water = 1) Freezing Point:        -309oF

Melting Point: N/A

Vapor Density (Air=1):1.6-2.0

pH: N/A

Evaporation Rate: N/A Odor: Odorless

UEL:        1.8%

LEL:        9.5%

Flash Point:        -58o to -306oF

10.        STABILITY & REACTIVITY

Stability: Stable under normal conditions of use.

Hazardous Polymerization: Will not occur.

Conditions   to  Avoid/Incompatibilities:  Strong  acids  and oxidizing agents, heat, sparks, flame and build-up of static electricity.

Hazardous        Decomposition        Products:        Carbon        monoxide        and        carbon

dioxide.

11.        TOXICOLOGICAL INFORMATION

No data available.

12.        ECOLOGICAL INFORMATION

No data available.

13.        DISPOSAL INFORMATION

Dispose        through        a        licensed        waste        disposal        company.        Follow applicable federal, state and local waste disposal regulations.

14.        TRANSPORT INFORMATION

Liquefied petroleum gas, 2.1, UN1075.

15.        REGULATORY INFORMATION EPA SARA TITLE III

Section 302 EPCRA Extremely Hazardous Substances (EHS)

Product Component        CAS No.        Wt%        RQ, lb        TPQ, lb

None

Section 304 CERCLA Hazardous Substances

Product Component        CAS No.        Wt%        RQ, lb

None

Section 311/312 Hazard Categorization

Acute:

Chronic:

Fire:

Pressure:

Reactive:

X

X

X

Section 313 EPCRA Toxic Substances

Product Component        CAS No.        Wt.% None

Key:       RQ = Reportable Quantity

TPQ = Threshold Planning Quantity of EHS

CALIFORNIA PROPOSITION 65 WARNING

Chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm may be found in crude oil and petroleum products.   Although it is possible to sufficiently refine a crude oil or its end products to remove the potential for cancer, we are advising that one or more of the  listed  chemicals  may  be  present  in  some  detectable quantities.   Read and follow directions and use care when handling crude oil and petroleum products.

16.  OTHER INFORMATION

THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF THIS COMPANY'S KNOWLEDGE AND BELIEVED ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE IS MADE AS TO THE ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY THEMSELVES AS TO THE SUITABILITY AND COMPLETENESS OF SUCH INFORMATION FOR THEIR OWN PARTICULAR USE.

This is the end of MSDS A0124.msd